Non-Symmetrical Nickel(II)dithiocarbamates with NiS2P2-Chromophore

• Autorzy: Pastorek R. , Kámeniček J. , Husárek J. , Pavliček M. , Šindelár Z. , Žak Z.
• Języki publikacji: EN

Abstrakty

EN

Non-symmetrically substituted Ni(II)dithiocarbamate complexes with NiS2P2 chromophore of composition [Ni(bziprdtc)(PPh3)2]X, [Ni(bziprdtc)(PPh3)2]BPh4_3H2O (bziprdtc- = benzylisopropyldithiocarbamate, PPh3 = triphenylphosphine, BPh4 _ = tetraphenylborate, X = ClO4 _ , PF6 _ ), [Ni(cetdtc)(PPh3)2]X, [Ni(cetdtc)(PPh3)2]PF6, [Ni(cetdtc)(PBut3)2]X (cetdtc- = cyclohexylethyldithiocarbamate, PBut3 = tributylphosphine, X = ClO4 _ , BPh4 _ ) have been isolated. These complexes have been characterized by elemental analysis, IR and UV-VIS spectroscopy, thermal analysis, magnetochemical and conductivity measurements. X-ray structural analysis of [Ni(bziprdtc)(PPh3)2]ClO4_0.5H2O confirms the NiS2P2 chromophore with a slightly distorted square arrangement around the central atom.

Słowa kluczowe

EN

non-symmmetrical dithiocarbamate nickel(II) complexes; synthesis; physico-chemical study; X-ray structural analysis

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 11
• Strony: 1545--1551
• Opis fizyczny: Bibliogr. 16 poz., rys.

Twórcy

autor

Pastorek R.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Kámeniček J.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Husárek J.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Pavliček M.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Šindelár Z.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Žak Z.

• Department of Inorganic Chemistry, Masaryk University, Kotldfskd 2, 611 37 Brno, Czech Republic

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