Synthesis and Characterization of Three Novel Ferromagnetic Copper(II) Binuclear Complexes Bridged by Phthalato

• Autorzy: Ma S. , Zhang L. Z.
• Języki publikacji: EN

Abstrakty

EN

Three novel copper(II) binuclear complexes with phthalate dianion as bridging ligand have been obtained, namely [Cu2(phth)(L)4](ClO4)2, where phth denotes the phthalate dianion and L represents 1,10-phenanthroline (abbreviated as phen), 2,2_-bipyridine (bpy) or 4,4_-dimethyl-2,2_-bipyridine (Me2bpy). Meanwhile, the IR, electronic spectra, ESR spectra and the temperature-dependent magnetic susceptibility of the three complexes were analyzed. The results of the magnetic analyses show a weak ferromagnetic coupling between the paramagnetic ions in all complexes studied.

Słowa kluczowe

EN

phthalate dianion bridge; copper(II)-copper(II) binuclear complex; ferromagnetic interaction

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 11
• Strony: 1537--1543
• Opis fizyczny: Bibliogr. 13 poz., rys.

Twórcy

autor

Ma S.

• Department of Pharmaceutical Engineering, Tianjin University of Commerce, Tianjin, 300134, P.R. of China

autor

Zhang L. Z.

• Department of Pharmaceutical Engineering, Tianjin University of Commerce, Tianjin, 300134, P.R. of China

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