The Synthesis and Characterization of 1,2-dihydroxyimino-3,6-di-aza-8,9-O-iso-butylidene Nonane and Its Complexes with Ni(II), Cu(II), Zn(II) and Cd(II)

Canpolat, E.; Kaya, M.; Görgülü, A. O.

Artykuł - szczegóły

Tytuł artykułu

The Synthesis and Characterization of 1,2-dihydroxyimino-3,6-di-aza-8,9-O-iso-butylidene Nonane and Its Complexes with Ni(II), Cu(II), Zn(II) and Cd(II)

Autorzy

Canpolat E. , Kaya M. , Görgülü A. O.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

1,2-Dihydroxyimino-3,6-di-aza-8,9-O-iso-butylidene nonane (H2L) was synthesized starting from 1,2-O-iso-butylidene-4-aza-6-amino hexane (RNH2) and antichloroglyoxime. Ni(II) and Cu(II) complexes ofH2L have a metal:ligand ratio of 1:2 and the ligand coordinates through two N atoms, as do most of the vic-dioximes. However, Zn(II) and Cd(II) complexes of H2L have a metal:ligand ratio of 1:1 and one chloride ion and one water molecule are also coordinated to the metal ion. Structures of the ligand and its transition- metal complexes are proposed, according to elemental analyses, IR, 13C and 1H NMR spectra, magnetic susceptibility measurements and thermogravimetric analyses (TGA).

Słowa kluczowe

vic-dioxime Ni(II) Cu(II) Zn(II) Cd(II) complexes

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2002

Tom

Vol. 76 / nr 5

Strony

687--694

Opis fizyczny

Bibliogr. 37 poz., rys.

Twórcy

autor

Canpolat E.

Firat University, Faculty of Art and Science, Department of Chemistry, 23119 Elazig, Turkey

autor

Kaya M.

Firat University, Faculty of Art and Science, Department of Chemistry, 23119 Elazig, Turkey

autor

Görgülü A. O.

Firat University, Faculty of Art and Science, Department of Chemistry, 23119 Elazig, Turkey

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0020-0075