Angular Overlap Treatment of cis-Dichlorobis(1,10-phenanthroline)chromium(III) Chloride Dihydrate in Aqueous Solution

• Autorzy: Kurzak K. , Biernacki K.
• Języki publikacji: EN

Abstrakty

EN

Low-symmetry mixed-ligands cis-[CrCl2(phen)2]Cl complex (phen = 1,10-phenanthroline) has been characterized spectroscopically. Electronic spectrum of aqueous solution of this complex has been measured at room temperature and interpreted using the angular overlap model (AOM), and assuming C2v symmetry. All the experimental transition energies are derived from Gaussian analysis of the solution spectrum. The calculations of the ligand-field parameters take into account all the transitions, which are required in the ligand-field theory (except those energetically higher than the range of the measured spectrum).

Słowa kluczowe

EN

angular overlap model; electronic spectra; chromium(III) complexes; 1,10-phenanthroline; molecular structure; low symetry

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 4
• Strony: 503--509
• Opis fizyczny: Bibliogr. 20 poz., rys.

Twórcy

autor

Kurzak K.

• Department of Chemistry, University of Podlasie, ul. 3-go Maja 54, PL-08110 Siedlce, Poland

autor

Biernacki K.

• Department of Chemistry, University of Podlasie, ul. 3-go Maja 54, PL-08110 Siedlce, Poland

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