The Microcrystals of BEDT-TTF and BEDO-TTF Polyiodides Forming the Conducting Networks within Polymer Film surface and Their Transformations

• Autorzy: Tracz A.
• Języki publikacji: EN

Abstrakty

EN

New results on morphology and structure of microcrystals of bis-(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) and bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF or BO) polyiodide salts formed within surface layers of polymer films by a two step reticulate doping technique and their transformations are discussed. The architecture of the microcrystalline conducting network was studied by STM and AFM. X-ray diffraction studies of microcrystals of ET salts in polymer matrix and structure-properties relationships are discussed. The thermal transformation of microcrystals of _-ET2I3 in polymer matrix to _-ET2I3 was followed in situ by X-ray diffraction and a new example of the transformation of microcrystals of BO salt in polymer matrix by annealing is shown.

Słowa kluczowe

EN

organic superconductors; BEDT_TTF; BEDO-TTF; AFM; X-ray diffraction; conductive polymer composition

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 2-3
• Strony: 457--470
• Opis fizyczny: Bibliogr. 49 poz., rys.

Twórcy

autor

Tracz A.

• Center of Molecular and Macromolecular Studies Polish Academy of Sciences, Sienkiewicza 112, 90-363 Łódź, Poland

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