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Abstrakty
Surface plasmon resonance (SPR) and quartz crystal microbalance (QCM) studies are described for tetrakis-tert-butylphthalocyanatoCu(II) and two new tetrakis-5,10,15,20- (substituted phenyl)-21H,23H-porphines. The Langmuir isotherms of the porphines, coupled with the layer thickness and contact area of the LB monolayers, show that these two compounds are not forming regular monolayer LB films, but are exhibiting extensive clumping on the subphase and on the substrates. The optical spectra and SPR of the porphine films did not exhibit noteworthy sensitivity to chlorine. In contrast the phthalocyanine gave good quality monolayers, which showed promise for sensing chlorine in the 1-10 ppm range.
Wydawca
Czasopismo
Rocznik
Tom
Strony
367--376
Opis fizyczny
Bibliogr. 30 poz., rys.
Twórcy
autor
- The Nanomaterials Group, Cranfield University, Cranfield MK43 0AL, UK
autor
- The Nanomaterials Group, Cranfield University, Cranfield MK43 0AL, UK
autor
- Faculty of Applied Sciences, UWE(Bristol), Bristol BS161QY, UK
autor
- Department of Physics, University of Sheffleld, Sheffleld S3 7RH, UK
autor
- The Nanomaterials Group, Cranfield University, Cranfield MK43 0AL, UK
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0020-0038