Deposition and Characterization by Surface Plastmon Resonance of Langmuir-Blodgett Monolayers of Three Macrocyclic Conjugated Tetrapyrrole Compounds Exposed to Chlorine Gas

• Autorzy: Honeybourne C. L. , Portus D. , Ratcliffe N.M. , Richardson T. , Ashwell G.J.
• Języki publikacji: EN

Abstrakty

EN

Surface plasmon resonance (SPR) and quartz crystal microbalance (QCM) studies are described for tetrakis-tert-butylphthalocyanatoCu(II) and two new tetrakis-5,10,15,20- (substituted phenyl)-21H,23H-porphines. The Langmuir isotherms of the porphines, coupled with the layer thickness and contact area of the LB monolayers, show that these two compounds are not forming regular monolayer LB films, but are exhibiting extensive clumping on the subphase and on the substrates. The optical spectra and SPR of the porphine films did not exhibit noteworthy sensitivity to chlorine. In contrast the phthalocyanine gave good quality monolayers, which showed promise for sensing chlorine in the 1-10 ppm range.

Słowa kluczowe

EN

surface plasmon resonance; quartz crystal microbalance; Langmuir-Blodgett films; porphines

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 2-3
• Strony: 367--376
• Opis fizyczny: Bibliogr. 30 poz., rys.

Twórcy

autor

Honeybourne C. L.

• The Nanomaterials Group, Cranfield University, Cranfield MK43 0AL, UK

autor

Portus D.

• The Nanomaterials Group, Cranfield University, Cranfield MK43 0AL, UK

autor

Ratcliffe N.M.

• Faculty of Applied Sciences, UWE(Bristol), Bristol BS161QY, UK

autor

Richardson T.

• Department of Physics, University of Sheffleld, Sheffleld S3 7RH, UK

autor

Ashwell G.J.

• The Nanomaterials Group, Cranfield University, Cranfield MK43 0AL, UK

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