One-, Two- and Non-Coordinated Cr02- 4 Entity in the Nickel(II) Complexes. Structural and Spectroscopic Investigation

• Autorzy: Pietraszko A. , Bronowska W. , Wojciechowska A. , Staszak Z. , Cieślak-Golonka M.
• Języki publikacji: EN

Abstrakty

EN

A systematic investigation of the chromate ion in [Ni(II)-(2,2_-bpy)-CrO4 2_ ] systems has been carried out. The effect of the Ni(II) ion and the organic ligand on the mode of the chromate position in the [Ni(bpy)3]CrO4_7.5H2O(1), [Ni(bpy)2(OCrO3)(H2O)]_5H2O(2) and catena-(ž-CrO4-O,O_)[Ni(bpy)(H2O)2]_2H2O (3) complexes has been shown. [Ni(bpy)3]CrO4_7.5H2O crystals (1) have a monoclinic symmetry with space group C2/c and 8 chemical units, forming a unit cell with a = 13.641(3) A, b = 22.939(5) A, c = 23.351(5) A and _ = 104.69(3) deg, whereas the [Ni(bpy)2(OCrO3)(H2O)]_5H2O crystals (2) have a monoclinic symmetry with space group P21/c and 4 chemical units per unit cell with a = 10.854(2) A, b = 22.665(5) A, c = 10.623(2) A and _ = 108.93(3) deg at room temperature. The chromate ion in 1 is not coordinated to the nickel(II) ion. The geometry around the Cr(VI) atom is pseudotetrahedral. Untypical for the chromate ion monodentate coordination has been found in the complex [Ni(bpy)2(OCrO3)(H2O)]_5H2O. The chromate position has been also elucidated from the digitally resolved IR spectra. The coordination of the chromate ion in 2 and 3 was also observed for the single crystal at 4K, in reflectance and solution electronic spectra through the appearance of a new transition at ca. 15000 cm-1. The full characterization of the chromophores present in the complexes: NiN6, NiN4O2, NiN2O4 and NiO6 have been obtained on the basis of the detailed analysis of the electronic spectra at 4K(Gaussian deconvolution followed by digital filtration).

Słowa kluczowe

EN

crystal structure; Ni(II) complexes; chromate ion; electronic spectra

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2002
• Tom: Vol. 76 / nr 2-3
• Strony: 309--324
• Opis fizyczny: Bibliogr. 60 poz., rys.

Twórcy

autor

Pietraszko A.

• Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, 59-950 Wrocław, Poland

autor

Bronowska W.

• Institute of Physics, Wrocław Univiersity of Technology

autor

Wojciechowska A.

• Institute of lnorganic Chemistry and Metallurgy of Rare Elements, Wrocław University of Technology

autor

Staszak Z.

• Faculty of Computer Science and Management, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Cieślak-Golonka M.

• Institute of lnorganic Chemistry and Metallurgy of Rare Elements, Wrocław University of Technology

Bibliografia

• 1.Zhitkovich A., Voikun V. and Costa M., Carcinogenesis 16, 907 (1995).
• 2.Cieślak-Golonka M, Polyhedron Report, 15, 3667 (1996).
• 3.Stearns D.E. and Wetterhahn K.E., NATO ASI 1997 Series 26,15 and the references therein.
• 4.Perez-Benito J.R and AriasC, J. Phys. Chem.,A102, 5837 (1998).
• 5.Codd R. and Lay P.A., J. Am. Chem. Soc, 121, 7864 (1999).
• 6.Szyba K.,Cieślak-Golonka M. and Gąsiorowski K., BioMetals, 5,157 (1992).
• 7.Gąsiorowski K., Szyba K., Woźniak D.,Cieślak-Golonka M. and Rzepka-Materny M.,BioMetals, U, 175 (1998), and the references therein.
• 8.Stanica N., Stager C.V., Cimpoesu M. and Andruh M., Polyhedron, 17,1787 (1998).
• 9.Shi J.M., CuiJ.Z., Liao D.Z., MiaoM.M., Liu Y.J.,Jiang Z.H. and Wang G.L., PolishJ. Chem., 72,643 (1998).
• 10.Gamovskii A.D., Burlov A.S., Gamovskii DA., Vasilchenko I.S, Antsichkina A.S., Sadikov G.G., SousaA., Garcia-VazquezJ.A., Romero J., Duran M.L., Sousa-Pedrares A. and Gomez C., Polyhedron, 18, 863 (1999).
• 11. Gosmini C, Lasry S., Nedelec J.Y. and Perichon J., Tetrahedron, 54,1289 (1998).
• 12.Hayashi Y, Mano H. and Uehara A., Chem. Lett., 899 (1998).
• 13.Zeki Y.S., Nedim M.M., Nuras T. and Yasar G., Acta Chem. Scand., 52, 694 (1998).
• 14.Ye B.H., Chen X.M., Xue G.Q. and Ji L.N., J. Chem. Soc., Dalton Trans., 2827 (1998).
• 15.Plater M.J., Foreman M.R.SU., Coronado E., Gomez-Garcia C.J. and Slawin A.M.Z., J. Chem. Soc, Dalton Trans., 4209 (1999).
• 16.Pavlishchuk W.W., Kalaida A.W. and Goreshnik E.A., Koord. Khim., 25, 542 (1999) (inRussian).
• 17.Molina-Svendsen H.,Bojesen G. and McKenzie Ch.J., Inorg. Chem., 37,1981 (1998).
• 18.YeB.H., Xue F., Xue G.Q.,Ji L.N. and Mak T.C.W., Polyhedron, 18,1785 (1999).
• 19.Repka A.,Cieślak-Golonka M., Surga W. and Żurowski K., Thermochim. Acta, 313,9 (1998).
• 20.SheldrickG.M., SHELXL-97, Programs for the Solution and the Refinement of Crystal Structures from Dififraction Data. University of Gottingen, 1997.
• 21.Bierman G. and Ziegler H., Anal. Chem., 58, 536 (1986).
• 22.Myrczek J., Spectr. Lett., 23,1027 (1990).
• 23.Cieślak-Golonka M.,Rączko M. and Staszak Z., Polyhedron, 11, 2549 (1992).
• 24.Wojciechowska A., Staszak Z., Pietraszko A., Bronowska W. and Cieślak-Golonka M.,Poyhedron, 21, 2063 (2001).
• 25.Slavič I.A., Nucl. Instr. Meth, 134,285 (1976).
• 26.Bartecki A. and Staszak Z., Comp. Enh. Spectr., 2,129 (1984).
• 27.Miernik D., Arkowska A., Grażyńska E. and Staszak Z., Spectr. Lett., 24,371 (1991).
• 28.Perumareddi J.R., J. Phys. Chem., 76, 3401 (1972).
• 29.Merriam J.S. and Perumareddi J.R., J. Phys. Chem., 79,142 (1975).
• 30.Wada A., Sakebe N. and Tanaka L, ActaCryst, B32, 1121 (1976).
• 31.Xu Y, Xu J.Q., Zhang K.L., Zhang Y and You X.Z., Chem. Commun., 153 (2000).
• 32.Oshio H., Kikuchi T., Kikuchi K. and Ito T., Mol. Cryst. Liq. Cryst., 305, 23 (1997).
• 33.Oshio H., Okamoto H., Kikuchi T. and Ito X., Inorg. Chem., 36, 3201 (1997).
• 34.Harel M.,Knobler C.and McCullough J.D., Inorg. Chem, 8, 11 (1969).
• 35.Bensch W., Seferiadis N. and Oswald H.R.,Inorg. Chem. Acta, 126,113 (1987).
• 36.Oshio H., Kikuchi T. and Ito X., Inorg. Chem., 35,4938 (1996).
• 37.Choi K.Y., Park J.R. and Suh I.H., Polyhedron, 18, 497 (1998).
• 38.Choi K.Y, Suh I.H. and Kim D.W., Inorg. Chim. Acta, 293,100 (1999).
• 39.Gatehouse B.M. and Guddat L.W., Acta Cryst.,C43,1445 (1987).
• 40.Drtleke S., Wieghardt K.,Nuber B., Weiss J., Fleischhauer H.P., Gehring S. and Hasse W.,J. Am. Che m.Soc, 111, 8622 (1989).
• 41.Benetollo F., Bombieri G., Gilli R, Harlow P.M., Polo A. and Vallarino L.M.,Polyhedron, 14, 2255 (1995).
• 42.(a)Bruggemann R.C. and Xhewalt U., Z NaturforschB, 49,1531 (1994); (b) Allen J.L., Shapley P.A. and Wilson S.R., Organometallics, 13, 3749 (1994); (c)Bueno I., ParadaC, Garcia O., Puebla G.E., Monge A. andRuiz-ValeroC,J. Chem. Soc, Dalton Trans., 1911 (1988).
• 43.Leppa-aho J., ActaCryst., C50, 663 (1994).
• 44.Xedenac J.C. and Philippot E.,ActaCryst, B30, 2286 (1974).
• 45.Liu Z.M.,Jiang Z.H., Liao D.Z. and Wang G.L., Polyhedron, 10,101 (1991).
• 46.Rodriguez-Martin Y, Gonzalez-Platas J. And Ruiz-Perez C, Acta Cryst, C55,1087 (1999).
• 47.Nakamoto K., Infrared and Ramana Spectra of lnorganic and Coordination Compounds, A Wiley-Interscience Pub. John Wiley & Sons, Inc, 5th ed. 1997.
• 48.HathawayB.J., in: Compreh. Coord. Chem., Pergamon Press, Oxford 1987, Vol. 2.
• 49.Cieślak-Golonka M., Coord. Chem. Rev., 109, 223 (1991), and the references therein.
• 50.Gili P. and Lorenzo-Luis P.A., Coord. Chem. Rev., 193-195, 747 (1999), and the references therein.
• 51.Lever A.B.P.,Inorganic Electronic Spectroscopy, Elsevier Press: NY, 2nd ed. 1984.
• 52.Palmer R.A. and Piper X.S., Inorg. Chem., 5, 864 (1966).
• 53.Bunel S., GilL., Morąga E. and Bobadilla H., Inorg. Chim. Acta, 4:3,415 (1970).
• 54.Bronowska W,Pietraszko A., Daszkiewicz M., Staszak Z.,Cieślak-Golonka M. and Wojciechowska A., submitted to Polyhedron.
• 55.Solomon E.I. and Ballhausen C., J. Mol. Phys., 29, 279 (1975).
• 56.(a)Dingle R. and Palmer R.A., Theor. Chim. Acta, 6,249 (1966). (b)Zompa L.J., Inorg. Chem., 17,2531
• (1978). (c)Hart S.M.,Boeyens J.C.A. andHancockR.D.,Inorg. Chem., 22,982 (1983). (d)Martin L.L., Martin R.L., Murray K.S. and Sargeson A.M.,Inorg. Chem., 29,1387 (1990). (e) Stranger R., Wallis S.C., Gahan L.R.,Kennard C.H. and Byriel K.A.,J. Chem. Soc., Dalt. Trans., 297 (1992). (f) Stranger R., McMahon K.L., Gahan L.R.,Bruce J.I. and Hambley T.W., Inorg. Chem., 36, 3466 (1997).
• 57.Stawińska J., Staszak Z.,Jezierska J.,Cieślak-Golonka M.and Daszkiewic zM., Polish J. Chem., 74,291 (2000).
• 58.TłaczałaT., Cieślak-Golonka M., Bartecki A. and Rączko M., Appl Spectr., 47,1704 (1993).
• 59.(a)Miskowski V., Gray B.H. and Ballhausen C.J.,Mol. Phys., 28,729 (1974), and the references therein. (b) Hog J.H.,Ballhausen C.J. and Solomon E.I., Mol. Phys., 32, 807 (1976).
• 60.(a)JohnsonL.W. and McGlynn S.P., Chem. Phys. Lett., 7,618 (1970). (b)Robbins D.J. and Day R, Mol. Phys., 34, 893 (1972)