One-, Two- and Non-Coordinated Cr02- 4 Entity in the Nickel(II) Complexes. Structural and Spectroscopic Investigation

Pietraszko, A.; Bronowska, W.; Wojciechowska, A.; Staszak, Z.; Cieślak-Golonka, M.

Artykuł - szczegóły

Tytuł artykułu

One-, Two- and Non-Coordinated Cr02- 4 Entity in the Nickel(II) Complexes. Structural and Spectroscopic Investigation

Autorzy

Pietraszko A. , Bronowska W. , Wojciechowska A. , Staszak Z. , Cieślak-Golonka M.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

A systematic investigation of the chromate ion in [Ni(II)-(2,2_-bpy)-CrO4 2_ ] systems has been carried out. The effect of the Ni(II) ion and the organic ligand on the mode of the chromate position in the [Ni(bpy)3]CrO4_7.5H2O(1), [Ni(bpy)2(OCrO3)(H2O)]_5H2O(2) and catena-(ž-CrO4-O,O_)[Ni(bpy)(H2O)2]_2H2O (3) complexes has been shown. [Ni(bpy)3]CrO4_7.5H2O crystals (1) have a monoclinic symmetry with space group C2/c and 8 chemical units, forming a unit cell with a = 13.641(3) A, b = 22.939(5) A, c = 23.351(5) A and _ = 104.69(3) deg, whereas the [Ni(bpy)2(OCrO3)(H2O)]_5H2O crystals (2) have a monoclinic symmetry with space group P21/c and 4 chemical units per unit cell with a = 10.854(2) A, b = 22.665(5) A, c = 10.623(2) A and _ = 108.93(3) deg at room temperature. The chromate ion in 1 is not coordinated to the nickel(II) ion. The geometry around the Cr(VI) atom is pseudotetrahedral. Untypical for the chromate ion monodentate coordination has been found in the complex [Ni(bpy)2(OCrO3)(H2O)]_5H2O. The chromate position has been also elucidated from the digitally resolved IR spectra. The coordination of the chromate ion in 2 and 3 was also observed for the single crystal at 4K, in reflectance and solution electronic spectra through the appearance of a new transition at ca. 15000 cm-1. The full characterization of the chromophores present in the complexes: NiN6, NiN4O2, NiN2O4 and NiO6 have been obtained on the basis of the detailed analysis of the electronic spectra at 4K(Gaussian deconvolution followed by digital filtration).

Słowa kluczowe

crystal structure Ni(II) complexes chromate ion electronic spectra

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2002

Tom

Vol. 76 / nr 2-3

Strony

309--324

Opis fizyczny

Bibliogr. 60 poz., rys.

Twórcy

autor

Pietraszko A.

Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, 59-950 Wrocław, Poland

autor

Bronowska W.

Institute of Physics, Wrocław Univiersity of Technology

autor

Wojciechowska A.

Institute of lnorganic Chemistry and Metallurgy of Rare Elements, Wrocław University of Technology

autor

Staszak Z.

Faculty of Computer Science and Management, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Cieślak-Golonka M.

Institute of lnorganic Chemistry and Metallurgy of Rare Elements, Wrocław University of Technology

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0020-0033