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The acidity constant of 1-hydroxy-2-(prop-2_-enyl)-4-(prop-2_-enyloxy)-9,10-anthraquinone in different methanol-water mixtures at 25_C has been determined spectrophotometrically. A linear reverse relationship is observed between the pKa and mole fraction of methanol in the solvent mixtures. The complexation reaction between the anthraquinone derivative used and Cu2+ ion has been studied in methanol solution at 25_C by a spectrophotometric technique. The stoichiometry of the resulting complex was found to be 1:1. The formation constant of the Cu2+-anthraquinone complex, evaluated from the computer fitting of the absorbance-mole ratio data at 5 different wavelengths, is log Kf = 4.59 _ 0.06.
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Tom
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1533--1541
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- Department of Chemistry, Razi University, Kermanshah, Iran
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bwmeta1.element.baztech-article-BUJ1-0019-0066