Transformations of 2-Alkoxy-6-chloro- and 6-Alkoxy-2-chloro-7-methylpurines Under the Action of Methyl Iodide

Kowalska, A.; Maślankiewicz, A.

Artykuł - szczegóły

Tytuł artykułu

Transformations of 2-Alkoxy-6-chloro- and 6-Alkoxy-2-chloro-7-methylpurines Under the Action of Methyl Iodide

Autorzy

Kowalska A. , Maślankiewicz A.

Identyfikatory

Warianty tytułu

Języki publikacji

Abstrakty

2-Alkoxy-6-chloro-7-methylpurines 3 were prepared by 6-chloro-dealkoxylation of 2,6-dialkoxy-7-methylpurines 4. Reactions of alkoxy-chloro-7-methylpurines 2 and 3 with methyl iodide led as N-9 methylation and as N-3 methylation to give N-methyl purinium salts 9 and 11 from purine 2 or 6 and 7 from purine 3. The formation of purinium salts was accompanied by 6-iodo-dechlorination leading from 3 to 6-iodopurinium salt 5 and by alkyl iodide elimination leading to hypoxanthine 10.

Słowa kluczowe

7,9-dialkylpurinium salts chloropurines dialkoxypurines

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Polish Journal of Chemistry

Rocznik

2001

Tom

Vol. 75, nr 9

Strony

1327--1332

Opis fizyczny

Bibliogr. 21 poz., rys.

Twórcy

autor

Kowalska A.

Department of Organic Chemistry, Silesian School of Medicine, Jagiellońska 4, 41-200 Sosnowiec, Poland

autor

Maślankiewicz A.

Department of Organic Chemistry, Silesian School of Medicine, Jagiellońska 4, 41-200 Sosnowiec, Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUJ1-0019-0041