Models of Biomacromolecules and Other Useful Structures Based on the Poly(alkylene phosphate) Chains

• Autorzy: Penczek W. , Pretula J. , Kałużyński K.
• Języki publikacji: EN

Abstrakty

EN

Poly(alkylene phosphate) backbones are at the basis of two important classes of biomacromolecules, nucleic and teichoic acids. Both are known to strongly bind metal cations; teichoic acids interact specifically with Ca2+ and Mg2+ cations transporting these cations in the biological milieu. This review describes the work of this laboratory directed towards synthesis of the backbones interaction with cations and some applications in nonbiological systems, although related to the ability to interact with cations. Thus, poly(alkylene phosphates) are described as liquid membranes and in the form of block copolymers as regulating crystal growth by interacting with cations rich surface. Moreover, poly(alkylene phosphates) function as strong acids: cationation of polyaniline (doping) leading to the intermolecular complex, in which poly(pentamethylene phosphate) specifically recognize the distance between the nitrogen atoms in polyaniline.

Słowa kluczowe

EN

poly(alkylene phosphates); biomimicking polymers; liquid membranes; polyaniline; crystal growth modifiers

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 8
• Strony: 1171--1181
• Opis fizyczny: Bibliogr. 31 poz., rys.

Twórcy

autor

Penczek W.

• Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Lódź, Sienkiewicza 112, Poland

autor

Pretula J.

• Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Lódź, Sienkiewicza 112, Poland

autor

Kałużyński K.

• Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Lódź, Sienkiewicza 112, Poland

Bibliografia

• 1.Munson R.S. and Glaser L., Biology of Carbohydrates, Ed. V. Ginsburg, Wiley, NY 1981, vol. 1, p. 91.
• 2.Naumowa I.B., Usp. Sovrem. Biol., 75, 357 (1973).
• 3.Heptinstall S., Archibald A.R. and Baddiley J., Nature, 225, 519 (1970).
• 4.Hughes A.H., Hancock I.C. and Baddiley J., Biochem. J., 132, 83 (1973).
• 5.Baddiley J., Hancock J.C. and Sherwood P.M.A., Nature, 243, 43 (1973).
• 6.Kałużyński K., Libiszowski J. and Penczek S., Macromol., 9, 365 (1976).
• 7.Libiszowski J., Kałużyński K. and Penczek S,,J. Polym. Sci. Polym. Chem. Ed., 16, 1275 (1978).
• 8.Kłosiński P. and Penczek S., Macromol., 16, 316 (1983).
• 9.Penczek S. and Kłosiński P., Models of Biopolymers by Ring-Opening Polymerization, Ed. S. Penczek, CRC Press, Inc., 1990, chapter 4, pp 291-378.
• 10.Sosnowski S., Libiszowski J., Slomkowski S. and Penczek S., Makromol. Chem. Rapid Commun., 5, 239 (1984).
• 11.Westheimer H., Acc. Chem. Res.,70, 1 (1968).
• 12.Pretula J. and Penczek S., Makromol. Chem., Rapid Commun., 9, 731 (1988).
• 13.Pretula J. Kałużyński K., Szymański R. and Penczek S., J. Polym. Sci. Part A: Polym. Chem., 37, 1365 (1999).
• 14.Nifanteev E.E., Chimia Gidrofosforilnych Soedin., Nauka: Moskva, 1983.
• 15.Vogt W. and Balasubramanian S., Makromol. Chem., 163, 111 (1973).
• 16.Penczek S. and Pretula J., Macromol., 26, 2228 (1993).
• 17.Pretula J. and Penczek S., Makromol. Chem., 191, 671 (1990).
• 18.Pretula J., Kałużyński K., Szymański R. and Penczek S., Macromol., 30, 8172 (1997).
• 19.Szymański R. and Penczek S., Makromol. Chem., 194, 1645 (1993).
• 20.Wodzki R. and Kłosiński P., Makromol. Chem., 191, 921 (1990).
• 21.Wodzki R. and Kałużyński K, Makromol. Chem., 190, 107 (1989).
• 22.Narębska A., Wodzki R. and Wyszyńska A., Makromol. Chem., 190, 1501 (1989).
• 23.Ramachandran V.S., Malhotra V.M., Jolicoeur C. and Spiratos N., Superplasticizers: Properties and Applications in Concrete, Ed. Minister of Public Works and .Government Services, Canada, 1998, chapter 7, pp 193-221.
• 24.Sedlak M., Antonietti M. and Colfen H., Makromol. Chem. Phys., 199, 247 (1998).
• 25.Marentette J.M., Norwig J., Stoeckelmann E., Meyer W.H. and Wegner G., Adv. Mater., 8, 9 (1997).
• 26.Kałużyński K., Pretula J., Lapienis G., Basko M., Bartczak Z., Dworak A. and Penczek S., J. Polym. Sci., submitted.
• 27.Ginder J.M. and Epstein A.J., Phys. Rev. Lett., 64, 1184 (1990).
• 28.Ginder J.M. and Epstein A.J., Phys. Rev. Lett., B41, 674 (1990).
• 29.Kulszewicz-Bajer I., Pretula J. and Pron A., J. Chem. Soc., Chem. Commun., 642 (1994).
• 30.Kulszewicz-Bajer I., Sobczak J., Hasik M. and Pretula J., Polymer, 37, 25 (1996).
• 31.Pretula J., Doctoral Thesis, Center of Molecular and Macromolecular Studies, Polish Academy of Sciences, Lodz, 1999.