Synthesis and Stereochemistry of Mono and Bicyclic 1,2-Thiaphosphacyclanes

• Autorzy: Mastryukova T. , Odinets I. L. , Vinogradova N. M. , Lyssenko K. A. , Petrovskii P. V.
• Języki publikacji: EN

Abstrakty

EN

The facile synthetic route to 5- and 6-membered mono and bicyclic 3-cyano-2-oxo-1,2- thiaphosphacyclanes has been elaborated on the base of intramolecular S-alkylation in a series of mono- and bis-_-haloalkyl substituted thiophosphorylacetonitriles. The stereochemistry of the cyclic compounds was determined byNMRas well as X-ray diffraction. The diastereomeric transformations of 3-cyano-2-oxo-1,2-thiaphosphinanes and formation of conglomerates in the case of 6-cyano-2-oxa-10-thia-1-phosphabicyclo[4.4.0]decane- 1-oxide are discussed.

Słowa kluczowe

EN

S-alkylation; 3-cyano-2-oxo-1,2-thiaphospholane; 3-cyano-2-oxo-1,2-thiaphosphinane; 6-cyano-2-oxa-10-thia(oxa)-1-phosphabicyclo[4.4.0]decane-1-oxide

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 8
• Strony: 1103--1119
• Opis fizyczny: Bibliogr. 37 poz., rys.

Twórcy

autor

Mastryukova T.

• A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813 Moscow, GSP-1, Vavilova str.28, Russia

autor

Odinets I. L.

• A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813 Moscow, GSP-1, Vavilova str.28, Russia

autor

Vinogradova N. M.

• A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813 Moscow, GSP-1, Vavilova str.28, Russia

autor

Lyssenko K. A.

• A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813 Moscow, GSP-1, Vavilova str.28, Russia

autor

Petrovskii P. V.

• A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 117813 Moscow, GSP-1, Vavilova str.28, Russia

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