Dipole Moment, Molar Kerr Constant, Crystal and Molecular Structure of 3-Chloro-N-methyl-N-nitroaniline

• Autorzy: Prezhdo V. , Bykova A. S. , Głowiak T. , Prezhdo O. V. , Daszkiewicz Z. , Kyzioł J. B.
• Języki publikacji: EN

Abstrakty

EN

Dipole moment, molar Kerr constant, crystal and molecular structure of m- ClC6H4N(CH3)NO2 (or C7H7ClN2O2) are studied. Comparison the data obtained by dipole moment and molar Kerr constant measurement, X-ray crystallographic investigation and quantum-chemical calculation show that the molecule contains a planar NNO2 nitroamino group which is twisted around the N-Cphenyl bond by ca 61.4_ from the plane of the aromatic ring. The structural data are compared with the data for p- ClC6H4N(CH3)NO2 and the influence of the substituent on the structural parameters of the molecule is established.

Słowa kluczowe

EN

N-nitroamino group; N-methyl-N-nitro-chloranilines; crystal structure; dipole moment; molar Kerr constant; quantum chemical calculation

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 5
• Strony: 707--718
• Opis fizyczny: Bibliogr. 33 poz., rys.

Twórcy

autor

Prezhdo V.

autor

Bykova A. S.

autor

Głowiak T.

autor

Prezhdo O. V.

autor

Daszkiewicz Z.

autor

Kyzioł J. B.

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