Application of Bromotrimethylsilane and Trialkyl Phosphites for Convenient and Effective Synthesis of Aminophoshonic Acids and Corresponding Monoalkyl and Dialkyl Esters

• Autorzy: Boduszek B.
• Języki publikacji: EN

Abstrakty

EN

Application of bromotrimethylsilane (Br-TMS) in a mixture with trialkyl phosphite for synthesis of various aminophosphonic acids and esters was investigated. It was found, that appropriate mixtures of Br-TMS and trimethyl phosphite or triethyl phosphite were effective reagents for phosphorylation of various aldimines, obtained from aromatic and heteroaromatic aldehydes. Products of these reactions were corresponding aminophosphonic acids, or corresponding dialkyl or monoalkyl esters, respectively.

Słowa kluczowe

EN

trimethyl phosophite; bromotrimethylsilane; silylation; aminophosphonic acids; monomethyl esters of aminophosphonic acids; dimethyl esters of aminophosphonic acids

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 5
• Strony: 663--672

Twórcy

autor

Boduszek B.

• Institute of Organic Chemistry, Biochemistry and Biotechnology, Wrocław University of Technology, 50-370 Wrocław, Poland,

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