Nickel(II)morpholinedithiocarbamate with Mixed P,P-Ligands

• Autorzy: Pastorek R. , Kameniček J. , Šindelář Z. , Žák Z.
• Języki publikacji: EN

Abstrakty

EN

Ni(II)morpholinedithiocarbamate complexes with P,P-ligands in the coordination sphere of composition [Ni(morphdtc)(P,P)]X and [Ni2(morphdtc)2X2(P,P)], resp. [(X = NCS-, ClO4 _, I-; P,P = 1,2-bis(diphenylphosphino)ethane (dppe), 1,4-bis(diphenylphosphino) butane (dppb), 1,6-bis(diphenylphosphino)hexane (dpph), 1,1_-bis(diphenylphosphino) ferrocene (dppf); morph = C4H8O; dtc = S2CN-)] have been isolated. These complexes have been characterized by elemental analysis, IR and UV-VIS spectroscopy, thermal analysis, magnetochemical and conductivity measurements. X-ray structural analysis of [Ni(morphdtc)(dppf)]ClO4_C2H5OH confirms the NiS2P2 chromophore with a slightly distorted square arrangement around central atom.

Słowa kluczowe

EN

dithiocarbamate nickel(II) complexes; X-ray structural analysis; synthesis; thermal decomposition

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 3
• Strony: 363--369
• Opis fizyczny: Bibliogr. 18 poz., rys.

Twórcy

autor

Pastorek R.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Kameniček J.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Šindelář Z.

• Department of Inorganic and Physical Chemistry, Palacký University, 771 47 Olomouc, Czech Republic

autor

Žák Z.

• Department of Inorganic Chemistry. Masaryk University, Kotlàřskà 2, 611 37 Brno, Czech Republic

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