Analyzing a Sequence of Reactions by the De Donder Equation

• Autorzy: Głowiński J. , Tylus W. , Hałat A.
• Języki publikacji: EN

Abstrakty

EN

In the kinetic analysis of the mechanism postulated simplified assumptions are often made. These assumptions are generally verified by comparing the simplified kinetic description with experimental data. In this study consideration is given to the idea of constructing a quantitative" measure for the "qualitative" assessment of the assumption (approximation), which makes it possible to examine its adequacy at an arbitrary moment of the reaction. The adopted measures are defined as criteria for steady-state and equilibrium (quasi-equilibrium) approximations.

Słowa kluczowe

EN

kinetics; steady-state aproximation; quasi-equilibrium; criteria; criteria of applicability

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2001
• Tom: Vol. 75, nr 1
• Strony: 105--114
• Opis fizyczny: Bibliogr. 16 poz., rys.

Twórcy

autor

Głowiński J.

• Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University of Technology, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Tylus W.

• Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University of Technology, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

autor

Hałat A.

• Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University of Technology, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland

Bibliografia

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