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Tytuł artykułu
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Abstrakty
In the kinetic analysis of the mechanism postulated simplified assumptions are often made. These assumptions are generally verified by comparing the simplified kinetic description with experimental data. In this study consideration is given to the idea of constructing a quantitative" measure for the "qualitative" assessment of the assumption (approximation), which makes it possible to examine its adequacy at an arbitrary moment of the reaction. The adopted measures are defined as criteria for steady-state and equilibrium (quasi-equilibrium) approximations.
Wydawca
Czasopismo
Rocznik
Tom
Strony
105--114
Opis fizyczny
Bibliogr. 16 poz., rys.
Twórcy
autor
- Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University of Technology, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
autor
- Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University of Technology, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
autor
- Institute of Inorganic Technology and Mineral Fertilizers, Wroclaw University of Technology, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
Bibliografia
- 1. Benson S.W., J. Chem, Phys., 20, 1605 (1952).
- 2. Rice O.K., J. Phys. Chem.,64, ¡851 (1960).
- 3. Giddings J.C. and Shin H.K., Trans. Farad. Soc., 57, 468 (1961).
- 4. Shin H.,J. Chem. Phys., 39,2937(1963).
- 5. Bowen J.R., Acrivos A. and Oppenheim A.K., Chem. Eng. Sci., 18, 177 (1963).
- 6. Farrow L.A. and Edelson D., Inter. J. Chem. Kinet., 6, 787 (1974).
- 7. Boudart M. and Djega-Mariadassou G., Kinetics of Heterogeneous Catalytic Reactions, Princeton University Press, Princeton, N.Y. 1984, p. 79.
- 8. Holstein W.L. and Boudart M., J. Phys. Chem. B, 101, 9991 (1997).
- 9. Boudart M., Ind. Eng. Chem. Fundamentals, 25, 70 (1986).
- 10. Dumesic J.A., J. Catal., 185, 496 (1999).
- 11. Boudart M., Microkinetics, in: Handbook of Heterogeneous Catalysis, VCH Weinheim 1997, vol. 3, p. 963 and p. 965.
- 12. Atkins P.W., Physical Chemistry, Oxford University Press., Oxford 1990, p. 802.
- 13. Laidler K.J., J. Chem. Edu., 65, 250 (1998).
- 14. Kondratev W.N., Konstanty skorosti gazofaznykh reakcii, Nauka, Moskva 1972, p. 67, p. 79, p. 243.
- 15. Benson S.W. and Axworthy A.E., J. Chem. Phys,, 26, 1718 (1957).
- 16. Głowiński J. and Tylus W., Polish J. Technol., 1,4(1999).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0016-0064