PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Synthesis and Characterization of a New Thiazole Schiff Base 5-Bromo-2-hydroxybenzylidene-2-aminobenzothiazole and Its Complexes with Co(II), Cu(II) and NiSaII)

Autorzy
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A new ligand 5-bromo-2-hydroxybenzylidene-2-aminobenzothiazole has been synthesized from 2-aminobenzothiazole and 5-bromosalicylaldehyde by condensation in ethanol. Metal complexes of the ligand were prepared from chloride salts of Co(II), Cu(II), and Ni(II) in ethanol. Characterization of the ligand and its complexes were carried out by microanalyses, magnetic susceptibility measurements, FT-IR, 13C, 1H NMR, and UV-Visible spectroscopy. It was suggested that two ligands with two water molecules coordinate to each metal atom by hydroxy oxygen and imino nitrogen to form high spin distorted octahedral complexes with Co(II), Ni(II) and Cu(II).
Słowa kluczowe
Rocznik
Strony
29--33
Opis fizyczny
Bibliogr. 24 poz., rys.
Twórcy
autor
  • Firat University, Faculty of Science and Art, Department of Chemistry, 23169 Elazig, Turkey
autor
  • Firat University, Faculty of Science and Art, Department of Chemistry, 23169 Elazig, Turkey
Bibliografia
  • 1. Eynde J.J.V. and Fromont D., Bull. Soc. Chim. Belg., 106, 393 (1997).
  • 2. Sitkowski J., Stefaniak L„ Dziembowska T., Grech E., Jagodzińska E. and Webb G.A J Molecular Structure, 381, 177(1996).
  • 3. Tanaka K, Nomura K., Oda H., Yoshida S. and Mitsuhashi K., J. Heterocyclic Chem., 28,907 (1991).
  • 4. Muir M.M., Gomez G.M., Cadiz M.E. and Muir J.A., Inorg. Chim. Acta, 168, 47 (1990).
  • 5. Castro R., Garcia-Vazquez J.A., Romero J. and Sousa A., Polyhedron, 12, 224! (1993).
  • 6. Buncel E. and Clement O., J. Chem. Soc. Perkin Trans., 2, 1333 (1995).
  • 7. Atakol O., PhD Thesis, Ankara University, (1986).
  • 8. Schrauzer G.N. and Kohnle J., Chem. Ber., 97, 3056 (1964).
  • 9. Akbar M. Ali and Livinstone S.E., Coord. Chem. Rev., 13, 101 (1974).
  • 10. Campbell M.J.M., Coord. Chem. Rev., IS, 279 (1975).
  • 11. Padhye S. and Kauffman G.B., Coord. Chem. Rev., 63, 127 (1985).
  • 12. Karlin K.D. and Zubieta J. (Editors), Biological and Inorganic Copper Chemistry Adenine Press NY (1983) . ’ ’
  • 13. Tsuruoka M. and Seikutsugaka I., Med. Biol., 10,296 (1947).
  • 14. Merchant J.R., Martysen G. and Venkatesh N.S., Indian J. Chem., 20B, 493 (1981).
  • 15. Maghraby M.A., and Hassan A.A., Indian J. Chem., 20B, 256 (1981).
  • 16. Chaaben I., Mohsen A., Omar M.E., Ashour F.A. and Mahron M.A., Sci. Pharm., 52, 51 (1984),
  • 17. Buristrov S.I. and Bobashko Z.A., USSR. Pat. No: 154861, (1964). (Chem. Abstr., 60, 5508c (1964).)
  • 18. Kapoor R.P., Rastogi M.K., Khanna R. and Garg C.P., Indian J. Chem., 23B, 390 (1984).
  • 19. Nakamura A., Konushi A. and Otsuka S., J. Chem. Soc. Dalton Trans., 488 (1979).
  • 20. Williams D.H, and Fleming I., Spectroscopic Methods in Organic Chemistry, 4th Edition, McGraw-Hill London, (1989).
  • 21. Drago R.S., Physical Methods for Chemists, Sounders College Publishing, NY, (1992).
  • 22. Gul A. and Bekaroglu O., J. Chem. Soc. Dalton Trans., 2537 (1983).
  • 23. West B.O ., J. Chem. Soc., 1374 (1962).
  • 24. Greenwood N.N. and Eamshaw A., Chemistry of the Elements, Pergamon Press, Oxford, (1984).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ1-0016-0055
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.