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Cementy Sorela i pokrewne. Cz.1: Cement Solera, znany także jako cement oksychlorkowomagnezowy

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EN
Sorel and related cements. Part 1: Sorel cement, also known as magnesium oxychloride cement (MOC)
Języki publikacji
PL
Abstrakty
PL
Cement Sorela, znany także jako oksychlorkowy cement magnezowy, był długo stosowany jako specjalny rodzaj cementu do wykonywania podłóg i jako materiał wiążący do płyt wełniano-drzewnych. Znane są także inne liczne zastosowania, w których wykorzystuje się obojętne wypełniacze i pigmenty barwiące, a które obejmują wytwarzanie sztucznych kamieni, podłóg bezspoinowych, sztucznych kości słoniowych (jako kul bilardowych), łączenie szkła z metalem i jako dekoracyjne tynki wewnętrzne i stiuki zewnętrzne zawierające kruszywo skalne. Opisano złożoną chemię procesu hydratacji cementu Sorela obejmującą szereg reakcji rozpuszczania i strącania, powodujących wiązanie, wraz ze specjalnymi odmianami tego cementu do cementowania otworów wiertniczych. Rozważono także możliwość wykonywania pojemników na odpady toksyczne. Wydaje się, że w przyszłości zostaną opracowane normy europejskie na cementy Sorela. Ważne znaczenie ma także określenie bezpiecznego stosowania cementów Sorela.
EN
Sorel cement (also known as magnesium oxychloride cement) has long been used as a special type of cement in flooring and as a binder for wood-wool slabs. There are numerous other applications, which may involve neutral fillers and coloured pigments, including artificial stone manufacture, jointless floors, artificial ivory (as in billiard balls), cementing glass with metal, and in decorative interior plasters and exterior stuccos with embedded stone aggregate. The complex hydration chemistry of Sorel cement for instigating binding by a series of dissolution and precipitation reactions is described along with that of variants of this cement for specialist well cementing downhole. The possibility for encapsulating toxic waste is also considered. European standardisation is likely to arise in the future for Sorel cement. It is important to clarify where Sorel cement can be safely employed and where it is inappropriate to use.
Czasopismo
Rocznik
Strony
297--316
Opis fizyczny
Bibliogr. 56 poz.
Twórcy
autor
  • Materials Chemistry Centre, UCL. London WC1H 0AJ, UK
Bibliografia
  • 1. S. Sorel: Procédé pour la formation d'un ciment très-solide par I'action d'un chlorure sur l'oxyde de zinc. Comptes Rendus hebdomadaires des Séances de l'Académie des Sciences, Paris 41. 784-785 (1855).
  • 2. S. Sorel: Sur un nouveau ciment magnésien. Comptes Rendus hebdomadaires des Séances de l'Académie des Sciences, Paris 65, 102-104 (1867).
  • 3. W. Hinz: Silicat-Lexikon. VEB Akademie-Verlag, Berlin (1985).
  • 4. Heidelberg Cement (website, 2005).
  • 5. F.M. Lea: The Chemistry of Cement and Concrete, 3rd Edition, p. 17. Edward Arnold (Publishers) Ltd., London (1970).
  • 6. A.D. Wilson and J.W. Nicholson: Acid-Base Cements: Their Biomedical and Industrial Applications. Cambridge University Press, Cambridge (1993).
  • 7. British Standards Institution: BS 776: Part 2: 1972. Specification for Materials for Magnesium Oxychloride (Magnesite) Fiooring. Part 2. Metric units. BSI, London (1972).
  • 8. W.O. Robinson and W.H. Waggaman: Basic magnesium chlorides. Journal of Physical Chemistry 13, 673-678 (1909).
  • 9. C.R. Bury and E.R.H. Davies: System magnesium oxide-magnesium chloride-water. Journal of the Chemical Society (London) 2008-2015 (1932).
  • 10. L. Walter-Lévy and P.M. deWolff: Contribution a l'étude du ciment Sorel. Comptes Rendus hebdomadaires des Séances de l'Académie des Sciences, Paris 222, 1077-1079 (1949).
  • 11. P.M. deWolff and L. Walter-Lévy: Structures et formulaires des constituants du ciment Sorel. Comptes Rendus hebdomadaires des Séances de l'Académie des Sciences, Paris 229, 1232-1234 (1949).
  • 12. L. Walter-Lévy and Y. Bianco: Action de magnésium sur une solution de chlorure de magnésium à 100°. Comptes rendus hebdomadaires des Séances de l'Académie des Sciences, Paris 232. 730-732 (1951).
  • 13. E.S. Newman, J.V. Gilfrich and L.S. Wells: Heat generation in the setting of magnesium oxychloride cements. Journal of Research of the National Bureau of Standards 49 (6), 377-383 (1952).
  • 14. P.M. deWolff and L. Walter-Lévy:Crystal structure of Mg2(OH)3(CI,Br)4H2O. Acta Crystallographica 6 (1), 140-144 (1953).
  • 15. Y. Bianco: Chlorures et bromures basigues de magnesium. Annales de Chimie (Paris), 3 (3), 370-404 (1958).
  • 16. L. Walter-Lévy: Chlorocarbonate neutre de magnésium. Comptes rendus hebdomadaires des Séances de l'Académie des Sciences, Paris 205. 1405-1407(1937).
  • 17. L. Walter-Lévy: Contribution de l'étude des halogenocarbonates de magnésium. Comptes Rendus hebdomadaires des Séances de l'Académie des Sciences, Paris 206, 1898-2000 (1938).
  • 18. T. Demediuk, W.F. Cole and H.V. Hueber: Studies on magnesium and calcium oxychlorides. Australian Journal of Chemistry 8, 215-233 (1955).
  • 19. W.F. Cole and T. Demediuk: X-ray, thermal and dehydration studies on magnesium oxychlorides. Australian Journal of Chemistry 8, 234-251 (1955).
  • 20. T. Demediuk and W.F. Cole: A study of magnesium oxysulphates. Australian Journal of Chemistry 1Q, 287-294 (1957).
  • 21. C.A. Sorrell and C.R. Armstrong: Reactions and equilibria in magnesium oxychloride cements. Journal of the American Ceramic Society 59 (1/2), 51-54(1976).
  • 22. L. Urwongse and C.A. Sorrell: The system MgO-MgCI2-H2O at 23°C. Journal of the American Ceramic Society 63. (9/10), 501-504 (1980).
  • 23. B. Tooper and L. Cartz: Structure and formation of magnesium oxychloride Sorel cements. Nature (London) 211, 64-65 (1966).
  • 24. V. Rogic and B. Matkovic: Phases in magnesium oxychloride cement (in Serbo-Croat). Cement (Zagreb) 16 (2), 61-69 (1972).
  • 25. B. Matkovic and J.F. Young: Microstructure of magnesium oxychloride cements. Nature Physical Science 246. 79-80 (1973).
  • 26. B. Matkovic, S. Popovic, V. Rogic, T. Zunic and J.F. Young: Reaction products in magnesium oxychloride cement pastes. System MgO-MgCI2-H2O. Journal of the American Ceramic Society 60. (11/12), 504-507 (1977).
  • 27. B.l. Smirnov, E.S. Solov'eva and E.E. Segalova: Chemical reaction of magnesium oxide with magnesium chloride solutions of various concentrations (in Russian). Zhurnal Priklandnoi Khimii 40 (3), 505-515 (1967).
  • 28. E.S. Solov'eva, B.l. Smirnov, E.E. Segalova and P.A. Rehbinder: Physicochemical features of hardening of magnesium oxychloride cement. Kinetics of formation of disperse hardening structures on interaction of magnesium oxide with magnesium chloride in aqueous medium (in Russian). Kolloidny Zhurnal 30 (5), 754-760 (1968).
  • 29. B.l. Smirnov, E.S. Solov'eva, E.E. Segalova and P.A. Rehbinder: Physicochemical features of hardening of magnesium oxychloride cement. Effect of the crystallisation conditions of magnesium oxychlorides on the kinetics of formation of dispersed hardening structures (in Russian). Kolloidny Zhurnal 31 (3), 440-445 (1969).
  • 30. J.J. Beaudoin and V.S. Ramachandran: Strength development in magnesium oxychloride cement. Cement and Concrete Research 5 (6), 617-630(1975).
  • 31. P.J. Sereda, R.F. Feldman and V.S. Ramachandran: Structure formation and development in hardened cement pastes, Sub-Theme Vl-1, 7th International Congress on the Chemistry of Cement, Paris, 1980. Editions Septima, Paris (1980).
  • 32. V.S. Ramachandran, R.F. Feldman and J.J. Beaudoin: 'Concrete Science - Treatise on Current Research'. Heyden & Son Ltd, London (1981).
  • 33. J.J. Beaudoin, V.S. Ramachandran and R.F. Feldman: Impregnation of magnesium oxychloride cement with sulphur. Ceramic Bulletin 56. 424-427(1977).
  • 34. J. Bensted: Special cements, in 'Lea's Chemistry of Cement and Concrete', 4th Edition. (Editor: P.C. Hewlett), pp. 779-835. Arnold Publishers, London (1998).
  • 35. J. Bensted: Cement science - Is it simple?/Czy nauka o cemencie jest nauką prostą? Cement-Wapno-Beton 6/68. No.1, 6-19 (2001).
  • 36. W. Kurdowski, C.M. George and F.P. Sorrentino: Special cements. 8th International Congress on the Chemistry of Cement, Rio de Janeiro, 22-27 September 1986. Volume 1, Theme 3, Sub-Theme 3.3 - Special cements. Calcium aluminate and non-silicate cements, pp. 292-318. FINEP, Rio de Janeiro (1986).
  • 37. D. Ménétrier-Sorrentino, P. Barretand S. Saqout: lnvestigations on the system MgO - MgCI2 - H2O and hydration of Sorel cement. 8lh International Congress on the Chemistry of Cement, Rio de Janeiro, 22-27 September 1986. Volume 4, Theme 3, Sub-Theme 3.3, Communications, pp. 339-343. FINEP, Rio de Janeiro (1986).
  • 38. D. Ménétrier-Sorrentino: Rapport DGRST, Matériaux P.079, 81 P 0630: Recherche du contrôle de la tenue aux intempéries d'un matériau composite fibres de verre - Ciment à l'oxychlorure de magnésium (1984).
  • 39. P. Maravelaki and G. Moraitou: Sorel's cement mortars - Decay susceptibility and effect on Pentelic marble. Cement and Concrete Research 29, 1929-1935(1999).
  • 40. C. Zhang and D. Deng: Research on the water resistance of magnesium oxychloride cement and its improvement (in Chinese). Gui Suan Yan Xue Bao 23 (6), 673-679 (1995).
  • 41. C. Zhang and D. Deng: Research on evaluation indexes of the water resistance of magnesium oxychloride cement (in Chinese). Xin Xing Jian Zhu Cai Liao 22 (2), 11-14 (1995).
  • 42. D. Deng and C. Zhang: The formation mechanism of the hydrate phases in magnesium oxychloride cement. Cement and Concrete Research 29. 1365-1371 (1999).
  • 43. D. Deng: The mechanism for soluble phosphates to improve the water resistance of magnesium oxychloride cement. Cement and Concrete Research 33, 1311-1317 (2003).
  • 44. F.C. Harper: L’effet de la température de calcination sur les propriétés de l'oxyde de magnésium prepare au départ de carbonate basique de magnésium. Comptes Rendus du 27éme Congrés International de la Chimie Industielle (Bruxelles) Vol. III, 45-48 (1954).
  • 45. F.C. Harper: Effect of calcination temperature on the properties of magnesium oxides for use in magnesium oxychloride cements. Journal of Applied Chemistry 17, 5-10 (1967).
  • 46. J. Bensted: A review of novel cements with potential for use in oilwell cementing. Royal Society of Chemistry Special Publication 67. 38-56 (1988).
  • 47. l.G. Vereshchaka, E.V. Kondrashchenko, A.S. Seryakov, S.G. Mihailenko, N.N. Kruglitskii and M.V. Grozev: Experiment involving magnesia oilwell cement (in Russian). Tsement (St. Petersburg) No.10, 10-11 (1984).
  • 48. H. Barthel: Composition and process for strengthening and sealing geological formations and strata in mining and deep drilling. U.S. Patent 3,816,148(1974).
  • 49. K.-H. Arens and M. Akstinat: Verbesserung der Ringraumzementation in teifen und übertiefen Bohrungen. Teil 2: Tiefbohrzemente und Additive. Bundesministerium für Forschung und Technologie (BMFT), Forschungsbericht BMFT-FB-T 82-112: Technologische Forschung und Entwicklung- Nichtnukleare Energietechnik. Fachinformationszentrum Energie-Physik-Mathematik GmbH, Karlsruhe (1982).
  • 50. R.E. Sweatman and W.C. Scoggins: Acid-soluble magnesia cement: new applications in completion and workover operations. 63rd Annual Technical Conference and Exhibition of the Society of Petroleum Engineers, Houston, Texas, 2-5 October 1988. SPE Paper 18031, pp. 137-152. Society of Petroleum Engineers, Richardson, Texas (1988).
  • 51. J. Bensted: Nuovi cementi: Cementi Sorel e cementi chimici affini./ Novel cements: Sorel and related chemical cements. II Cemento 86, 217-228(1989).
  • 52. S. Macakova, M.T. Hepworth, N. Pliesokova, J. Hatala and F. Siska: Immobilisation of heavy metals from MSW (municipal solid waste) incineration ash via use of Sorel cement. Journal of Solid Waste Technology and Management 24, No.1 (February 1997).
  • 53. M. Nehdi and A.A. Khan: Cementitious composites containing recycled tyre rubber - an overview of engineering properties and potential applications. Cement, Concrete and Aggregates 23, No.1 (June 2001).
  • 54. J. Bensted: Cementy wiertnicze. Cześć 3. Plastyczne mieszanki cementu wiertniczego o zwiększonej trwałości długookresowej./Oilwell cements. Part 3. Ductile oilwell cement compositions for better long term durability. Cement-Wapno-Beton 10/72. 13-32 (2005).
  • 55. J. Bensted: Scientific aspects of high alumina cement./Naukowe aspekty cementów glinowych. Cement-Wapno-Beton 9/71. 109-133 (2004).
  • 56. W. Kurdowski and F. Sorrentino: Special cements, in ‘Structure and Performance of Cements', 1St Edition, (Editor: P. Barnes), pp. 471-554. Applied Science Publishers, London and New York (1983).
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Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BTB2-0030-0078
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