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Electrochemical sensor for measurement of volatile organic compounds employing square wave perturbation voltage

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The paper presents the results of investigation on a prototype sensor for measurement of benzaldehyde in air. Sensitivity and limit of quantification of the sensor were determined for different internal electrolytes using square wave voltammetry (SWV) as the detection technique. The working and counter electrodes were made of platinum. Ionic liquids 1-hexyl, 3-methylimidazolium chloride,1-hexyl, 3-methylimidazolium bis (trifluoromethanesulfonyl) imide and 1-butyl,3-methylimidazolium tricyanomethan constituted the internal electrolyte. A polydimethylsiloxane (PDMS) membrane separated the gaseous medium from the electrolyte.
Słowa kluczowe
Rocznik
Strony
637--649
Opis fizyczny
Bibliogr. 21 poz., rys., tab., wykr.
Twórcy
autor
  • Gdansk University of Technology, Chemical Faculty, 11/12 Narutowicza, 80-233 Gdansk, Poland, jg@chem.pg.gda.pl
Bibliografia
  • [1] Cocker, D.R., Mader, B.T., Kalberer, M., Flagan, R.C., Seinfeld, J.H. (2001). The effect of water on gasparticle partitioning of secondary organic aerosol. Atmospheric Environment, 35, 6073-6085.
  • [2] Watson, J.G., Chow, J.C., Fujita, E.M. (2001). Review of volatile organic compounds source apportionment by chemical mass balance. Atmospheric Environment, 35, 1567-1584.
  • [3] European Parliament Directive 2008/50/WE of 21 May 2008 on air quality and pure air for Europe.
  • [4] Freemantle, M. (2005). Membranes For Gas Separation. C&EN, 83, 49-57.
  • [5] Sakamoto, Y., Nagata, K., Yogo, K., Yamada, K. (2007). Preparation and CO2 separation properties of amine modified mesoporous silica membrane. Microporous and Mesoporous Materials, 101, 303-311.
  • [6] Cañizares, P., García-Gómez, J., Sáez, C., Rodrigo, M.A. (2003). Electrochemical oxidation of several chlorophenols on diamond electrodes Part I. Reaction mechanism. J. Appl. Electrochem., 33, 917-927.
  • [7] Toshihiko, M., Hiroshi, K. (2002). Electro-chemical Remediation of VOC Contaminated Water. Report of Obayashi Corporation Technical Research Institute, 65, 89-94.
  • [8] Villagran, C., Banks, C.E., Hardacre, Ch., Compton, R.G. (2004). Electroanalytical determination of trace chloride in room-temperature ionic liquids. Anal. Chem., 76, 1998-2003.
  • [9] Gębicki, J., Kloskowski, A., Chachulski, B. (2010). Electrochemical sensor for measurement of volatile organic compounds in air. Elektronika, 6, 66-69.
  • [10] Bond, A.M. (1980). Modern Polarographic Methods in Analytical Chemistry. New York: Marcel Dekker Inc.
  • [11] Earle, M.J., Seddon, K.R. (2000). Ionic liquids. Green solvents for the future. Pure Appl. Chem., 72 (7), 1391-1398.
  • [12] Buzzeo, M.C., Hardacre, C., Compton, R.G. (2004). Use of room temperature ionic liquids in gas sensor design. Anal. Chem., 76, 4583-4588.
  • [13] Wei, D., Ivaska, A. (2008). Applications of ionic liquids in electrochemical sensors. Anal. Chimica Acta, 607, 126-135.
  • [14] TGS 822, TGS 2201, Product Information, Figaro USA, Inc.
  • [15] Jasiński, G. (2008). Czujniki gazów toksycznych na bazie elektrolitów stałych modelowanie i optymalizacja konstrukcji. Ph.D. Thesis. Gdansk University of Technology. (in Polish)
  • [16] Kotarski, M., Smulko, J. (2009). Noise measurement setups for fluctuations enhanced gas sensing. Metrol. Meas. Syst., 16(4), 457-464.
  • [17] Cao, Q., Rogers, J.A. (2009). Ultrathin films of single-walled carbon nanotubes for electronics and sensors: a review of fundamental and applied aspects. Adv. Mater., 21, 29-53.
  • [18] Wu, F.H., Zhao, G.C., Wei, X.W. (2002). Electrocatalytic oxidation of nitric at multi-walled carbon nanotubes modifield electrode. Electrochem. Commun., 4, 690-694.
  • [19] www. ilthermo.nist.gov
  • [20] Osteryoung, J.G., Osteryoung, R.A., (1985). Square wave voltammetry. Anal.Chem., 57, 101-110.
  • [21] Cygański, A. (1991). Podstawy metod elektroanalitycznych. Warszawa: WNT. (in Polish)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSW1-0075-0011
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