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The International Committee forWeights and Measures (CIPM) has had a long-term aim of defining all of the base units in the terms of fundamental physical constants to eliminate any artifact on material dependencies. In 2005, in Recommendation 1, the CIPM approved preparative steps towards new definitions of the kilogram, the ampere, the Kelvin and the mole in terms of fundamental constants [1, 2]. The unit of temperature, the Kelvin, can be defined in terms of the SI unit of energy, the joule, by fixing the value of the Boltzmann constant k which is simply the proportionality constant between temperature T and thermal energy kT [3]. The new definition would be in line with modern science where nature is characterized by statistical thermodynamics, which implies the equivalence of energy and temperature as expressed by the Maxwell-Boltzmann equation. The Boltzmann constant k is not connected with the other fundamental constants, there are no alternatives to the linking of the Kelvin aside from the exact value of the constant k. In practice, no universal instrument for measuring energy exists while energy appears in different forms, e.g. temperature. Currently, several experiments are underway to determine k using primary thermometers of different types [3, 4]. From the point of view of practical thermometry it is necessary to determine what uncertainty in the measured value of k is needed to apply it as the temperature unit. It would be of the order in the present realization of the triple point of water: ≈ 1.8×10-7. At present its uncertainty is about one order of magnitude higher.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
227--234
Opis fizyczny
Bibliogr. 22 poz., tab.
Twórcy
autor
autor
- Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Wrocław, A.Szmyrka@int.pan.wroc.pl
Bibliografia
- 1. Recommendation 1 (CI-2005): Preparative Steps Towards New Definitions of the Kilogram, the Ampere, the Kelvin and the Mole in Terms of Fundamental Constants - CIPM, Sevres, 2005.
- 2. Becker P., De Bievre P., Fujii K., Glaeser M., Inglis B., Luebbig H., Mana G.: “Considerations on future redefinitions of the kilogram, the mole and the other units”, Metrologia, vol. 44, 2007, pp. 1-14.
- 3. Fischer J., Fellmuth B., Seidel J., Buck W.: “Towards a new definition of the Kelvin: Way to go”, Proc. of TEMPMEKO 2004, 9th International Symposium on Temperature and Thermal Measurements in Industry and Science, vol. 2, Zagreb-Croatia, 2005, pp. 13-19.
- 4. Fischer J., Gerasimow S., Hill K. D., Machin G., Moldover M. R., Pitre L., Steur P., Stock M., Tamura O., Ugur H., White D. R., Yang L., Zhang J.: “Preparative Steps Towards the New Definition of the Kelvin in Terms of the Boltzmann Constant”, Int. J. Thermophys., vol.28, 2007, pp. 1753-1765.
- 5. Preston - Thomas H.: “The International Temperature Scale of 1990 (ITS - 90)”, Metrologia, vol. 27, 1990, pp. 3-10.
- 6. Quinn T.: “Temperature scales and units and implications for practical thermometry of a possible redefinition of the Kelvin in terms of the Boltzmann constant”, 1. BIPM, Document CCT/05-26.
- 7. Renaot E., et all.: “Comparison of realizations of the triple-point of water; EUROMET project No. 549”, Proc. of TEMPMEKO 2004, 9th International Symposium on Temperature and Thermal Measurements in Industry and Science, vol. 2, Zagreb-Croatia, 2005, pp. 1009-1016.
- 8. Fellmuth B., Fischer J., Gaiser C., Buck W.: “Workshop of Methods for New Determinations of the Boltzmann Constant”, Working Document CCT/05-02 on the 23rd Meeting of the CCT, BIPM, Sevres 2005.
- 9. Mills I. M., Mohr P. J., Quinn T. J., Taylor B. N., Williams E. R.: “Redefinition of the kilogram, ampere, Kelvin and mole: a proposed approach to implementing CIPM recommendation 1 (CI-2005)”, Metrologia, vol. 43, 2006, pp. 227-246.
- 10. Preston - Thomas H., Blombergen P., Quinn T. J.: “Supplementary Information for the ITS-90”, BIPM, Sevres 1990.
- 11. CCT, Document “Mise en pratique for definition of the Kelvin”, BIPM, 2006, available at www.bipm.org.
- 12. Pavese F., Fellmuth B., Head D., Hermier Y., Peruzzi A., Szmyrka-Grzebyk A., Zanin L.: “MULTICELLS” the European Project on Cryogenic Temperature Fixed Points in Sealed Cells, Temperature, Its Measurement and Control in Science and Industry, vol. 7, American Institute of Physics, Melville, 2003, pp. 161-167.
- 13. Fellmuth B., Hermier Y., Pavese F., Szmyrka-Grzebyk A., Tew W.: “Special Problems when Realising the Triple Point of Hydrogen as a Defining Fixed Point of the ITS-90”, Proc. of 8th International Symposium on Temperature and Thermal Measurements in Industry and Science, TEMPMEKO’2001, pp. 403-410.
- 14. Fellmuth B.,Wolber L., Hermier Y., Pavese F., Steur P. P. M., Peroni I., Szmyrka-Grzebyk A., Lipinski L., Tew W. L., Nakano T., Sakurai H., Tamura O., Head D., Hill K. D., Steele A. G.: “Isotopic and other influences on the realisation of the triple point of hydrogen”, Metrologia, vol. 42, 2005, pp. 171-193.
- 15. Pavese F., Fellmuth B., Head D., Hermier Y., Sakurai H., Steele A. G., Szmyrka-Grzebyk A., Tew W. L.: “Proposal of amendement of the ITS-90 definition concerning the triple point of equlibrium hydrogen”, Document BIPM – CCT/01-07, 21 Meeting of the CCT, BIPM, Paris 2001.
- 16. Peruzzi A., Kerhof O., de Groot M.: “Isotope and Impurity Content in Water Triple-Point Cells Manufactured at Nmi VSL”, Intern. Journ. of Thermophysics, 2007, vol. 28, pp. 1931-40.
- 17. Tew W. L.: “Estimating the Triple-Point Isotope Effect and the Corresponding Uncertainties for Cryogenic Fixed Point”, Intern. Journ. of Thermophysics, 2008, vol. 29, pp. 67-81.
- 18. Pavese F., Fellmuth B., Hill K. D., Head D., Hermier Y., Lipinski L., Nakano T., Peruzzi A., Sakurai H., Smyrka-Grzebyk A., Steele A. G., Steur P. P. M., Tamura O., Tew W. L., Valkiers S., Wolber L.: “Progress Towards the Determination of the Relationship of the Triple-Point Temperature versus Isotopic Composition of Neon”, Intern. Journ. of Thermophysics, 2008, vol. 29, pp.57-66.
- 19. Lipinski L., Kowal A., Szmyrka-Grzebyk A., Manuszkiewicz H., Steur P. P. M., Pavese F.: “The triple point of nitrogen”, Metrologia, vol. 43, 2006, pp. 435-440.
- 20. Lipinski L., Kowal A., Szmyrka-Grzebyk A., Manuszkiewicz H., Steur P. P. M., Pavese F.: “The Transition of Nitrogen”, Intern. Journ. of Thermophysics, vol. 28, 2007, pp.1904-1912.
- 21. Szmyrka-Grzebyk A., Lipinski L., Manuszkiewicz, Kowal A.: “A National Temperature Standard between 13,8033 K and 273,16 K”, Proc. of the 2nd International Seminar and Workshop on Low Temperature Thermometry, Wroclaw 2003, pp.79-84.
- 22. Szmyrka-Grzebyk A., Lipinski L., Manuszkiewicz H., Kowal A.: “Cryogenic temperature standards in Poland”, Pribory, 2007, vol. 85 (7), pp. 16-19. (in Russian).
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Bibliografia
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