Development and validation of a selective method for the determination of chrysene using silver-enhanced room-temperature phosphorimetry

• Autorzy: da Cunha A. L. M. C. , Ziolli R. L. , Aucelio R. Q.
• Języki publikacji: EN

Abstrakty

EN

A factorial design was applied for the development of a solid surface room-temperature phosphorimetric method aiming the selective determination of chrysene. Data analysis was made using statistical experimental analysis (testing the significance of the factors using the analysis of variation, F-test and t-test), graphic method (Pareto´s chart) and the evaluation of the interactions among all variables. This procedure was used in order to guarantee high accuracy of results and minimization of the time spent for optimization. As the result, the experimental conditions using a selective phosphorescence inducer (silver) and a substrate surface modifier allowed the determination of chrysene in the presence of pyrene. The method allowed the detection of effective masses of chrysene in the ng range. Method validation is presented including a recovery and "t" tests using a Standard Reference Material.

Słowa kluczowe

EN

factorial design; validation; solid surface room-temperature phosphorimetry (SSRTP); chrysene; uncertainty

• Wydawca: Komitet Metrologii i Aparatury Naukowej PAN
• Czasopismo: Metrology and Measurement Systems
• Rocznik: 2007
• Tom: Vol. 14, nr 1
• Strony: 125--135
• Opis fizyczny: Bibliogr. 12 poz., rys., wykr.

Twórcy

autor

da Cunha A. L. M. C.

autor

Ziolli R. L.

autor

Aucelio R. Q.

• Pontifícia Universidade Católica do Rio de Janeiro (PUC-RJ), Chemistry Department, Brazil,

Bibliografia

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• 8. ANVISA, Guide to Quality in Analytical Chemistry, vol. 1, Brazil, 2004.
• 9. INMETRO, Orientations about method’s validation in chemistry test, DOG CGCRE-008, 2003.
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• 12. CITAC/EURACHEM, Quantifying Uncertainty Analytical Measurement, 2000.