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Purpose: In the technical Al alloys even small quantity of impurities - Fe and Mn - causes the formation of new phase components. Intermetallic particles form either on solidification or whilst the alloy is at a relatively high temperature in the solid state, e.g. during homogenization, solution treatment or recrystallization. The exact composition of the alloy and casting condition will directly influence the selection and volume fraction of intermetallic phases. The main objective of this study was to analyze the morphology and composition of complex microstructure of intermetallic phases in cast AlSi5Cu1Mg and AlCu4Ni2Mg2 aluminium alloys. Design/methodology/approach: In this study, several methods were used such as: optical light microscopy (LM), scanning (SEM) electron microscopy in combination with X-ray analysis (EDS) using polished sample, and X-ray diffraction (XRD) to identify intermetallics in cast AlSi5Cu1Mg and AlCu4Ni2Mg2 aluminum alloys. Findings: The results show that the microstructure of cast AlSi5Cu1Mg and AlCu4Ni2Mg2 aluminum alloys in T6 condition consisted a wide range of intermetallic phases. By using various instruments (LM, SEM, XRD) and techniques (imagine, EDS) following intermetallic phases were identified: Β-Al5FeSi, α-Al15(FeMn)3Si - in AlSi5Cu1Mg alloy and Al7Cu4Ni, Al12Cu23Ni, Al2CuMg, AlCuFeNi - in AlCu4Ni2Mg2 alloy. Research limitations/implications: In order to complete and confirm obtained results it is recommended to perform further analysis of the investigated aluminium alloys. Therefore it is planned to include in a next studies, microstructure analysis of the alloys by using transmission electron microscopy technique (TEM). Practical implications: Since the morphology, crystallography and chemical composition affect the intermetallic properties, what involves changes of alloy properties, from a practical point of view it is important to understand their formation conditions in order to control final constituents of the alloy microstructure. Originality/value: This paper proposes the best experimental techniques for analysis of the intermetallic phases occurring in the cast AlSi5Cu1Mg and AlCu4Ni2Mg2 aluminium alloys. This study has showed that the chemical phenol extraction method for the cast aluminium alloy is applicable.
Wydawca
Rocznik
Tom
Strony
69--28
Opis fizyczny
Bibliogr. 28 poz.
Twórcy
autor
- Department of Materials Science, Rzeszów University of Technology, ul. W. Pola 2, 35-959 Rzeszów, Poland, mrowka@prz.edu.pl
Bibliografia
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- [6]F. King, Aluminium and its alloys. John Willey & Sons, New York-Chichester-Brisbane-Toronto, 1987.
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- [9]J.W. Martin, Preciptation Hardening, Pergamon Press, Oxford, 1968.
- [10]I.J. Polmear, Light alloys. Metallurgy of the light metals. Arnold, London-New York-Sydney-Auckland, 1995.
- [11]L.A. Dobrzański, R. Maniara, M. Krupiński, J.H. Sokolowski, Microstructure and mechanical properties of AlSi9CuX alloys, Journal of Achievements in Materials and Manufacturing Engineering 24/2 (2007) 51-54.
- [12]M. Kciuk, S. Tkaczyk, Structure, mechanical properties and corrosion resistance of AlMg5 and AlMg1Si1 alloys, Journal of Achievements in Materials and Manufacturing Engineering 21/1 (2007) 39-42.
- [13]M. Takeda, A. Komatsu, M. Ohta, T. Shirai, T. Endo, The influence of Mn on precipitation behavior in Al-Cu, Scripta Materialia 39/9 (1998) 1295-1300.
- [14]M. Warmuzek, G. Mrówka, J. Sieniawski, Influence of the heat treatment on the precipitation of the intermetallic phases in comercial AlMn1FeSi alloy, Journal of Materials Processing Technology 157-158 (2004) 624-632.
- [15]S. Zajac, B. Bengtsson, C. Jönsson, Influence of cooling after homogenization and reheating to extrusion on extrudability and final properties of AA6063 and AA6082 alloys, Materials Science Forum 396-402 (2002) 399-404.
- [16]G. Mrówka-Nowotnik, J. Sieniawski, Influence of heat treatment on the microstructure and mechanical properties of 6005 and 6082 aluminium alloys Proceedings of the 14th Scientific International Conference „Achievements in Mechanical and Materials Engineering”, Gliwice-Wisła, 2005, 447-450.
- [17]G. Mrówka-Nowotnik, J. Sieniawski, M. Wierzbińska, Intermetallic phase particles in 6082 aluminium alloy, Archives of Materials Science and Engineering 28/2 (2007) 69-76. [18]G. Mrówka-Nowotnik, J. Sieniawski, M. Wierzbińska: Analysis of intermetallic particlesin AlSi1MgMn aluminium alloys, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 155-158.
- [19]M. Wierzbińska, G. Mrówka-Nowotnik, Identification of phase composition of AlSi5Cu2Mg aluminium alloy in T6 condition, Archives of Materials Science and Engineering 30/2 (2008) 85-88.
- [20]L.A. Dobrzański, R. Maniara, J.H. Sokolowski, The effect of cast Al-Si-Cu alloy solidification rate on alloy thermal characteristics, Journal of Achievements in Materials and Manufacturing Engineering 17 (2006) 217-220.
- [21]R.A. Siddiqui, H.A. Abdullah, K.R. Al.-Belushi, Influence of aging parameters on the mechanical properties of 6063 aluminium alloy, Journal of Materials Processing Technology 102 (2000) 234-240.
- [22]G. Sha, K. O’Reilly, B. Cantor, J. Worth, R. Hamerton, Growth related phase selection in a 6xxx series wrought Al alloy, Materials Science and Engineering A304-306 (2001) 612-616.
- [23]A.K. Gupta, D.J. Lloyd, S.A. Court, Precipitation hardening in Al-Mg-Si alloys with and without excess Si, Materials Science and Engineering A 316 (2001) 11-17.
- [24] M. Warmuzek, K. Rabczak, J. Sieniawski, The course of the peritectic transformation in the Al-rich Al–Fe–Mn–Si alloys, Journal of Materials Processing Technology 162-163 (2005) 422-428.
- [25] M. Warmuzek, J. Sieniawski, K. Wicher, G. Mrówka- Nowotnik, The study of distribution of the transition metals and Si during primary precipitation of the intermetallic phases in Al-Mn-Si alloys, Journal of Materials Processing Technology 175/1-3 (2006) 421-426.
- [26] J.A. Garcia-Hinojosa, C.R. Gonzalez, Y. Houbaert, Structure and properties of Al-7Si-Ni and Al-7Si-Cu cast alloys nonmodified and modified with Sr, Journal of Materials Processing Technology 143-144 (2003) 306-310.
- [27] M. Wierzbińska, J. Sieniawski, Effect of morphology of eutectic silicon crystals on mechanical properties and cleavage fracture toughness of AlSi5Cu1 alloy, Journal of Achievements in Materials and Manufacturing Engineering 14 (2006) 31-35.
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL9-0031-0009