Effect of Cu addition on the GFA, structure and properties of Fe-Co-based alloy

• Autorzy: Lesz S. , Babilas R. , Madej M. , Nowosielski R.
• Języki publikacji: EN

Abstrakty

EN

Purpose: The aim of the paper was investigation of the effect of Cu addition on GFA (Glass Forming Ability), structure, magnetic and mechanical properties of amorphous Fe-Co-B-Si-Nb alloy. Design/methodology/approach: The following experimental techniques were used: differential thermal analysis (DTA), transmission electron microscopy (TEM) and X-ray diffraction (XRD) method, measurements of magnetic properties (VSM method), Vickers microhardness (HV). Findings: It was shown that when Cu is added to the Fe-Co-based alloy, increase of the GFA and change of the magnetic properties was obtained. Research limitations/implications: The results can give more details to understand the relationship between structure, magnetic and mechanical properties. Thus can be useful for practical application of these alloys. Practical implications: The (Fe36Co36B19Si5Nb4)100-xCux (x=0 and 0.6) metallic glasses due to their excellent soft magnetic properties have shown great industrial value for commercial application. Many products consisting of these kinds of metallic glasses have been widely used, for example anti-theft labels, precision sensor material, and high efficient magnetic transformers in electronic industry. Originality/value: The applied investigation methods are suitable to determine the changes of GFA and structure combined with magnetic and mechanical properties of (Fe36Co36B19Si5Nb4)100-xCux (x=0 and 0.6) metallic glasses

Słowa kluczowe

EN

amorphous materials; magnetic properties; DTA; XRD; TEM method; GFA; glass forming ability

PL

materiały amorficzne; właściwości magnetyczne; mikrotwardość; DTA; XRD; metoda TEM; GFA; zdolność tworzenia fazy szklistej

• Wydawca: International OCSCO World Press
• Czasopismo: Archives of Materials Science and Engineering
• Rocznik: 2012
• Tom: Vol. 55, nr 2
• Strony: 70--77
• Opis fizyczny: Bibliogr. 26 poz.

Twórcy

autor

Lesz S.

autor

Babilas R.

autor

Madej M.

autor

Nowosielski R.

• Institute of Engineering Materials and Biomaterials, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland,

Bibliografia

• [1] J. Torrens-Serra, P. Bruna, J. Rodriguez-Viejo, S. Roth, M.T. Clavaguera-Mora, Effect of minor additions on the glass forming ability and magnetic properties of Fe-Nb-B based metallic glasses, Intermetallics 18 (2010) 773-780.
• [2] H.J. Sun, L. Li, Y.Z. Fang, J.X. Si, B. L. Shen, Bulk glassy (Fe0.474Co0.474Nb0.052)100-x(B0.8Si0.2)x alloys prepared using commercial raw materials, Journal of Non-Crystalline Solids 358 (2012) 911-914.
• [3] M. Stoica, R. Li, A. R. Yavari, G. Vaughan, J. Eckert, N. Van Steenberge, D.R. Romera, Thermal stability and magntic properties of FeCoBSiNb bulk metallic glasses, Journal of Alloys and Compounds 504S (2010) S123-S128.
• [4] Y. Jia, S. Zeng, S. Shan, L. Zhang, C. Fan, B. Zhang, Z. Zhan, R. Liu, W. Wang, Effect of copper addition on the glass forming ability of a Fe-Co based alloy, Journal of Alloys and Compounds 440 (2007) 113-116.
• [5] A. Inoue, B.L. Shen, C.T. Chang, Fe- and Co-based bulk glossy alloys with ultrahigh strength of over 4000 MPa, Intermetallics 14 (2006) 936-944.
• [6] A. Inoue, B. Shen, A. Takeuchi, Fabrication, properties- and applications of bulk glassy alloys in late transition metal-based systems, Materials Science and Engineering A 441 (2006) 18-25.
• [7] B. Shen, A. Inoue, Superhigh strength and good soft-magnetic properties of (Fe,Co)-B-Si-Nb bulk glassy alloys with high glass-forming ability, Applied Physics Letters 85/21 (2004) 4911-4913.
• [8] S. Lesz, R. Babilas, M. Nabiałek, M. Szota, M. Dośpiał, R. Nowosielski, The characterization of structure, thermal stability and magnetic properties of Fe-Co-B-Si-Nb bulk amorphous and nanocrystalline alloys, Journal of Alloys and Compounds 509S (2011) 197-201.
• [9] S. Lesz, Preparation of Fe-Co-based bulk amorphous alloy from high purity and industrial raw materials, Archives of Materials Science and Engineering 48/2 (2011) 77-88.
• [10] S. Lesz, R. Nowosielski, Structure and physical properties of Fe-based metallic glasses with Ni and Co addition, Journal of Achievements in Materials and Manufacturing Engineering 48/2 (2011) 145-152.
• [11] A. Makino, X. Li, K. Yubuta, C. Chang, T. Kubota, A. Inoue, The effect of Cu on the plasticity of Fe-Si-B-P based bulk metallic glass, Scripta Materialia 60 (2009) 277-280.
• [12] Y.Y. Sun, M. Song, X.Z. Liao, Y.H. He, Mechanical properties of a FeCuSiB alloy with amorphous and/or crystalline structures, Journal of Alloys and Compounds 509 (2011) 6603-6608.
• [13] Y. Dong, A. Wang, Q. Man, B. Shen, (Co1-xFex)68B21.9Si5.1Nb5 bulk glassy alloys with high glass-forming ability, excellent soft-magnetic properties and superhigh fracture strength, Intermetallics 23 (2012) 63- 67.
• [14] S. Lesz, Z. Stoklosa, R. Nowosielski, Influence of copper addition on properties of (Fe36Co36B19Si5Nb4)100-xCux metallic glasses, Archives of Materials Science and Engineering 38/1 (2009) 12-18.
• [15] R. Nowosielski, R. Babilas, P. Ochin, Z. Stokłosa, Thermal and magnetic properties of selected Fe-based metallic glasses, Archives of Materials Science and Engineering 30/1 (2008) 13-16.
• [16] R. Babilas, S. Griner, P. Sakiewicz, R. Nowosielski, Structure, thermal and magnetic properties of (Fe72B20Si4Nb4)100-xYx (x = 0,3) metallic glasses, Journal of Achievements in Materials and Manufacturing Engineering 44/2 (2011) 140-147.
• [17] R. Babilas, R. Nowosielski, Iron-based bulk amorphous alloys, Archives of Materials Science and Engineering, 44/1 (2010) 5-27.
• [18] R. Nowosielski, R. Babilas, Structure and magnetic properties of Fe36Co36B19Si5Nb4 bulk metallic glasses, Journal of Achievements in Materials and Manufacturing Engineering 30/2 (2008) 135-140.
• [19] R. Nowosielski, R. Babilas, Glass-forming ability analysis of selected Fe-based bulk amorphous alloys, Journal of Achievements in Materials and Manufacturing Engineering 42 (2010) 66-72.
• [20] B. Shen, C. Chang, A. Inoue, Formation, ductile deformation behavior and soft - magnetic properties of (Fe, Co, Ni)-B-Si-Nb bulk glassy alloys, Intermetallics 15 (2007) 9-16.
• [21] C. Suryanarayana, A. Inoue, Bulk metallic glasses, CRC Press Taylor & Francis Group Boca Raton, London, New York, 2011.
• [22] R. Babilas, M. Kądziołka-Gaweł, R. Nowosielski, Structure studies of Fe-based metallic glasses by Mössbauer spectroscopy method, Journal of Achievements in Materials and Manufacturing Engineering 45/1 (2011) 7-12.
• [23] P. Kwapuliński, J. Rasek, Z. Stokłosa, G. Badura, B. Kostrubiec, G. Haneczok, Magnetic and mechanical properties In FeXSiB (X=Cu,Zr,Co) amorphous alloys, Archives of Materials Science and Engineering 31/1 (2008) 25-28.
• [24] Ł. Madej, Z. Stokłosa, A. Chrobak, P. Kwapuliński, J. Rasek, G. Haneczok, Magnetic properties of Fe76X2Si8B14 (X=Al, Cr, Mo) amorphous alloys Archives of Materials Science and Engineering 34/1 (2008) 9-13.
• [25] W.J. Boettinger, U.R. Kattner, K.-W. Moon, J.H. Perepezko, DTA and heat-flux DSC measurements of alloy melting and freezing, National Institute of Standards and Technology Special Publication 960-15 (2006).
• [26] PN - EN ISO 6507 - 1:2007.
• [27] W.S. Sun, T. Kulik, X.B. Liang, J. Ferenc, Thermal stability and magnetic properties of Co-Fe-Hf-Ti-Mo-B bulk metallic glass, Intermetallics 14 (2006) 1066-1068.
• [28] W.H. Wang, Roles of minor additions in formation and properties of bulk metallic glasses, Progress in Materials Science 52 (2007) 540-596.