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Tytuł artykułu

CLSM and UV-VIS researches on polyoxadiazoles thin films

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The purpose of this paper was to analyse the surface morphology and optical properties of polyoxadiazoles thin films. Design/methodology/approach: A few different conducting polymers were dissolved in N-methyl-2-pyrrolid(in)one. Then the solutions were deposited on a glass substrate by spin coating method with a different spin rate. Changes in surface topography and optical properties were observed. A confocal laser scanning microscope CLSM Zeiss LSM 5 Exciter has been used. Photos have been taken from area of 120 x 120 microns. Findings: The analysis of images and spectra has confirmed that the quality of thin films depends upon the used polymers. It was also observed that the parameters of the spin coating method have significant effect on the morphology and the optical properties. The spin rate has got a strong impact on them. Research limitations/implications: The morphology and optical properties of polyoxadiazoles thin films has been described. This paper include description how the spin rate influence on the polymer thin films. In order to use a polymer thin film in photovoltaics or optoelectronics it must have a high internal transmission density. Further research of polymer thin films are recommended. Practical implications: The spin coating method allows to deposit a uniform thin films. It is important to know how the spin rate influence on the thin films properties. It is also important to find a new use for this group of material engineering in photovoltaic or optoelectronics devices. Originality/value: The good properties of thin films make them suitable for various applications. The value of this paper is defining the optimal parameters of spin-coating technology for polyoxadiazoles thin films. The results allow the choosing optimal parameters of the deposition process. Spin coating is a very good method to obtain thin films which are obligated to have the same thickness over the whole surface.
Rocznik
Strony
53--61
Opis fizyczny
Bibliogr. 20 poz.
Twórcy
autor
autor
autor
autor
  • Division of Materials Processing Technology, Management, and Computer Techniques in Materials Science, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, magdalena.szindler@polsl.pl
Bibliografia
  • [1] N. Drozdov, Photovoltaic cells for solar energy, Publisher University of Technology Lublin, Lublin, 2006.
  • [2] W. Torbicz, D. Pijanowska, Electroconductive polymers in electronics and analytical biochemical, Elektronika 6 (2009) 36-43.
  • [3] H. Shirakawa, Synthesis and characterization of highly conducting polyacetylene, Synthetic Metals 69 (1995) 3-8.
  • [4] J.A. Mikroyannidisa, M.M. Stylianakisa, M.S. Royc, P. Sureshb, G.D. Sharmab, Synthesis, photophysics of two new perylene bisimides and their photovoltaic performances in quasi solid state dye sensitized solar cells, Journal of Power Sources 194/2 (2009) 1171-1179.
  • [5] I. Gruin, Polymeric materials, PWN, Warsaw, 2003.
  • [6] A. Proń, Synthetics metals, Knowledge and Life 2 (2001).
  • [7] M. Bruma, T. Kopnick, Silicon-containing polyoxadiazoles - synthesis and perspectives, Advances in Colloid and Interface Science 116 (2005) 277-290.
  • [8] B. Schulz, Y. Kaminorz, L. Brehmer, New Aromatic Poly(l,3,4-oxadiazole)s for Light Emitting Diodes, Synthetics Metals 84/1 (1997) 449-450.
  • [9] E. Hamciuc, M. Bruma, T. Köpnick, Y. Kaminorz, B. Schulz, Synthesis and study of new silicon-containing polyoxadiazoles, Polymer 42 (2001) 1809-1815.
  • [10] B Hajduk, P Jarka, J Weszka, M Bruma, J Jurusik, M Chwastek, D Mańkowski, Studying of polyoxadiazole with Si atom in the backbone, Archives of Materials Science 42/2 (2010) 77-84.
  • [11] J. Weszka, L.A. Dobrzański, P. Jarka, J. Jurusik, B. Hajduk, M. Bruma, J. Konieczny, D. Mańkowski, Studying of spincoated oxad-Si properties, Journal of Achievements in Materials and Manufacturing Engineering 37/2 (2009) 505-511.
  • [12] J. Weszka, M. Szindler, A. Śliwa, B. Hajduk, J. Jurusik, Reconstruction of thin films polyazomethine based on microscopic images, Archives of Materials Science and Engineering 48/1 (2011) 40-48.
  • [13] J. Weszka, M.M. Szindler, M. Chwastek-Ogierman, M. Bruma, P. Jarka, B. Tomiczek, Surface morphology of thin films polyoxadiazoles, Journal of Achievements in Materials and Manufacturing Engineering 49/2 (2011) 224-232.
  • [14] L.A. Dobrzański, L.W. Żukowska, J. Mikuła, K. Gołombek, D. Pakuła, M. Pancielejko, Structure and mechanical properties of gradient PVD coatings, Journal of Materials Processing Technology 201 (2008) 310-314.
  • [15] L.A. Dobrzański, K. Lukaszkowicz, D. Pakuła, J. Mikuła,Corrosion resistance of multilayer and gradient coatings deposited by PVD and CVD techniques, Archives of Materials Science and Engineering 28/1 (2007) 12-18.
  • [16] L.A. Dobrzański, J. Mikuła, Structure and properties of PVD and CVD coated Al2O3+TiC mixed oxide tool ceramics for dry on high speed cutting processes, Journal of Materials Processing Technology 164-165 (2005) 822-831.
  • [17] K. Norrman, A. Ghanbari-Siahkali, N.B. Larsen, Studies of spin-coated polymer films, Annual Reports C 101 (2005) 174-201.
  • [18] G. Kalyuzhny, A. Vaskevich, G. Ashkenasy, A. Shanzer, I. Rubinstein, UV/Vis Spectroscopy of Metalloporphyrin and Metallophthalocyanine Monolayers Self-Assembled on Ultrathin Gold Films, Journal of Physical Chemistry B 104/34 (2000) 8238-8244.
  • [19] H. Förster, UV/VIS spectroscopy, Molecular Sieves - Science and Technology 4 (2004) 337-426.
  • [20] L.A. Dobrzański, M. Musztyfaga, A. Drygała, W. Kwaśny, P. Panek, Structure and electrical properties of screen printed contacts on silicon solar cells, Journal of Achievements in Materials and Manufacturing Engineering 45/2 (2011) 141-147.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL8-0050-0006
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