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Non-metallic inclusions in high manganese austenitic alloys

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The aim of the paper is to identify the type, fraction and chemical composition of non-metallic inclusions modified by rare-earth elements in an advanced group of high-manganese austenitic C-Mn-Si-Al-type steels with Nb and Ti microadditions. Design/methodology/approach: The heats of 3 high-Mn steels of a various content of Si, Al and Ti were melted in a vacuum induction furnace and a modification of non-metallic inclusions was carried out by the mischmetal in the amount of 0.87 g or 1.74 g per 1 kg of steel. Evaluation of the metallurgical purity of steels with non-metallic inclusions was done basing on determination their fraction, type, size and morphology. Stereological parameters of the inclusions were assessed by the use of automatic image analyzer cooperating with light microscope. EDS method was used to assess the chemical composition of non-metallic inclusions. Findings: It was found that the steels are characterized by high metallurgical purity connected to low concentrations of phosphorus and gases at a slightly higher sulphur content, introduced to a melt together with electrolytic manganese. The steels contain fine sulfide inclusions with a mean size from 21 to 25 ěm2 in a majority and their fraction equals from 0.047 to 0.09%, depending on sulphur content. MnS, carbonitrides of the (Ti,Nb)(C,N) type and complex carbosulfides containing Mn, Ti and Nb were identified in steels. The beneficial influence in decreasing a fraction of non-metallic inclusions and their susceptibility to elongate in a rolling direction has a higher addition of mischmetal and titanium microaddition. A modification of the chemical composition of non-metallic inclusions by Ce, La and Nd proceeds in an external zone of inclusions. Research limitations/implications: Further investigations relating the type and morphology of non-metallic inclusions to mechanical properties of sheets at various sections according to the rolling direction are needed. Practical implications: The knowledge of the type and morphology of non-metallic inclusions forming in high-Mn alloys and the effectiveness of their modification has a significant meaning for metallurgical and steel making technologies. Originality/value: A problem of the identification of non-metallic inclusions modified by REE and titanium is a new topic in studies on the metallurgical purity of advanced high-strength high-manganese steels.
Rocznik
Strony
21--30
Opis fizyczny
Bibliogr. 17 poz.
Twórcy
autor
autor
autor
  • Division of Constructional and Special Materials, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, adam.grajcar@polsl.pl
Bibliografia
  • [1] A.K. Lis, B. Gajda, Modelling of the DP and TRIP microstructure in the CMnAlSi automotive steel, Journal of Achievements in Materials and Manufacturing Engineering 15 (2006) 127-134.
  • [2] A. Grajcar, R. Kuziak, W. Zalecki, Designing of cooling conditions for Si-Al microalloyed TRIP steel on the basis of DCCT diagrams, Journal of Achievements in Materials and Manufacturing Engineering 45/2 (2011) 115-124.
  • [3] R. Kuziak, R. Kawalla, S. Waengler, Advanced high strength steels for automotive industry, Archives of Civil and Mechanical Engineering 8/2 (2008) 103-117.
  • [4] G. Frommeyer, U. Brüx, P. Neumann, Supra-ductile and high-strength manganese-TRIP/TWIP steels for high energy absorption purposes, ISIJ International 43 (2003) 438-446.
  • [5] S. Allain, J.P. Chateau, O. Bouaziz, S. Migot, N. Guelton, Correlations between the calculated stacking fault energy and the plasticity mechanisms in Fe-Mn-C alloys, Materials Science and Engineering A 387-389 (2004) 158-162.
  • [6] A. Grajcar, M. Opiela, G. Fojt-Dymara, The influence of hot-working conditions on a structure of high-manganese steel, Archives of Civil and Mechanical Engineering 9 (2009) 49-58.
  • [7] L.A. Dobrzański, A. Grajcar, W. Borek, Microstructure evolution of high-manganese steel during the thermo-mechanical processing, Archives of Materials Science and Engineering 37/2 (2009) 69-76.
  • [8] L.A. Dobrzański, W. Borek, Processes forming the micro-structure evolution of high-manganese austenitic steel in hot-working conditions, Journal of Achievements in Materials and Manufacturing Engineering 37/2 (2009) 397-407.
  • [9] L.A. Dobrzański, W. Borek, Hot-working of advanced high-manganese austenitic steels, Journal of Achievements in Materials and Manufacturing Engineering 43/2 (2010) 507- 526.
  • [10] L.A. Dobrzański, W. Borek, Hot deformation and recrystallization of advanced high-manganese austenitic TWIP steels, Journal of Achievements in Materials and Manufacturing Engineering 46/1 (2011) 71-78.
  • [11] A. Grajcar, S. Kołodziej, W. Krukiewicz, Corrosion resistance of high-manganese austenitic steels, Archives of Materials Science and Engineering 41/2 (2010) 77-84.
  • [12] G. Gigacher, W. Krieger, P.R. Scheller, C. Thomser, Non-metallic inclusions in high-manganese-alloy steels, Steel Research International 76/9 (2005) 644-649.
  • [13]T. Gladman, The Physical Metallurgy of Microalloyed Steels, University Press, Cambridge, 1997.
  • [14] J. Adamczyk, Development of the microalloyed construc-tional steels, Journal of Achievements in Materials and Manufacturing Engineering 14 (2006) 9-20.
  • [15] W. Ozgowicz, M. Opiela, A. Grajcar, E. Kalinowska-Ozgowicz, W. Krukiewicz, Metallurgical products of microalloy constructional steels, Journal of Achievements in Materials and Manufacturing Engineering 44/1 (2011) 7-34.
  • [16] K. Bolanowski, Influence of rare-earth elements on the structure and properties of steel, Metallurgical News 7-8 (2004) 323-325 (in Polish).
  • [17] A. Grajcar, Modification of non-metallic inclusions by rare-earth elements in low-alloyed C-Mn-Si-Al-type steels, Ores and Metals 55/3 (2010) 143-152 (in Polish).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL8-0045-0017
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