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Ductilization of Ni3Al by alloying with boron and zirconium

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The investigation of Ni₃AlBZr alloys was carried out to determine the influence of small zirconium and boron additions on the microstructure and mechanical properties, particularly with respect to room-temperature, and different strain rate conditions. Design/methodology/approach: Additions of both boron 0.26 at.% and zirconium from 0.3 to 1.5 at.% results in higher strength than exhibited by unalloyed Ni3Al. The sequence of structural changes of Ni3Al-based alloy has been correlated with mechanical properties, determined in uniaxial compression tests. Two ranges of work hardening have been identified on the stress-strain curves of these alloys. It was found that the first range of deformation corresponds to the intergranular slip system operating within individual grains, while the second one is connected with transgranular slip. Findings: Structural observations of A and B alloys showed that zirconium addition causes a decrease of the average grain size. On the mechanical properties of investigated alloys the increasing yield stress and hardness were observed in enlarging zirconium additions. However, the enlarged addition of zirconium causes a decrease of extension. Addition to an intermetallics compound Ni₃Al of such elements as boron (0.26 at.%) and zirconium (0.3 - 1.5 at.%) can be accepted as optimum from susceptibility to plastic deformation point of view. Research limitations/implications: The main limits for application of the polycrystalline Ni3Al phases is a poor strength and creep properties at high temperatures. The improvement of mechanical proprieties of Ni₃Al phase required small addition of suitable alloying elements. Practical implications: The results of investigations as well as the conclusions may be used for improvement of alloys processing based on Ni₃Al intermetallics compound. In well-considered peculiarity selection of alloyed additions and also processing parameters it is possible to steer in a limited range of mechanical properties of these alloys. Originality/value: The results of investigations expand knowledge about processing of the alloys based on Ni₃Al phase, and in consequence, to apply it in many branches of industry.
Rocznik
Strony
69--74
Opis fizyczny
Bibliogr. 14 poz.
Twórcy
autor
autor
  • Institute of Technology, Pedagogical University, ul. Podchorążych 2, 30-084 Kraków, Poland, phyjek@up.krakow.pl
Bibliografia
  • [1] K. Aoki, O. Izumi, Improvement in room temperature ductility of the L12 type intermetallic compound Ni₃Al by boron addition, Journal of Japan Institute of Metals 43 (1979) 1190-1196.
  • [2] C.T. Liu, C.L. White, J.A. Horton, Effect of boron on grain-boundaries in Ni₃Al, Acta Metallurgica 33 (1985) 213-229.
  • [3] C.T. Liu, V.K. Sikka, Nickel aluminides for structural use, Journal of Metals 38 (1986) 19-21.
  • [4] J. H. Schneibel, G. F. Peterson, C. T. Liu, Creep behaviour of a polycrystalline nickel aluminide: Ni-23.5at% Al-0.5at% Hf-0.2at%B, Journal of Materials Research 1 (1986) 68-72.
  • [5] S.E. Hus, N.S. Hsu, C.H. Tong, C.Y. Ma, S.Y. Lee, Mechanical properties of Ni₃Al(B) alloys at high temperature, In High Temperature Ordered Intermetallic Alloys II,eds. N. S. Stoloff, C. C. Koch, C. T. Liu and O. Izumi, Materials Research Society 81 (1987) 507-512.
  • [6] J. Adamiec,Ni₃Al alloy's properties related to high-temperature brittleness, Archives of Materials Science and Engineering 28/6 (2007) 333-336.
  • [7] S.A. Sajjadi, S.M. Zebarjad, Effect of temperature on tensile fracture mechanisms of a Ni-base superalloy, Archives of Materials Science and Engineering 28/1 (2007) 34-40.
  • [8] A. Nowotnik, Mechanical and structural aspects of high temperature deformation in Ni alloy, Journal of Achievements in Materials and Manufacturing Engineering 26/2 (2008) 143-146.
  • [9] P. Hyjek, PhD Thesis, Intermetallic alloys based on the Ni₃AlMe (Me = B, Cr, Ti, Zr) phase for high temperature structural applications, AGH University of Science and Technology-Krakow, 2008 (in Polish).
  • [10] E.P. George, C.T. Liu, D.P. Pope, Environmental embrittlement: The major cause of room-temperature brittleness in polycrystalline Ni₃Al, Scripta Metallurgica 27 (1992) 365-370.
  • [11] Y.F. Lia, J.T. Guo, L.Z. Zhou, H.Q. Ye, Effect of recrystallization on room-temperature mechanical properties of Zr-doped Ni3Al alloy, Materials Letters 58 (2004) 1853- 1856.
  • [12] A. Chiba, S. Hanada, S. Watanabe, Microstructure and Ductility of Zr and Hf doped Ni₃Al, Proceedings of the 3rd Japan International SAMPE Symposium, 1993, 1181-1186.
  • [13] T.H. Chuang, The mutual effects of boron, zirconium and aluminium on grain boundary segregation in Ni3Al intermetallic compounds, Materials Science and Engineering A141 (1991) 169-178.
  • [14] J.H. Hollomon, Tensile deformation, Transactions AIME Metal Technology 162 (1945) 268-290.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL8-0031-0019
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