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Purpose: The influence of melting method on the kinetics of nitrogen absorption by Fe-C-Mn filler metals has been analysed. The industrial heats of the Fe-C-Mn (SpG1) type welding filler metals were selected for own researches. Design/methodology/approach: The research of the nitrogen absorption kinetics was carried out in the levitation and TIG arc-melting conditions in the Ar+N₂ atmosphere. The conditions of experiments were made possibly close to those existing in a molten metal drop in the welding processes. Findings: Based on the models of nitrogen absorption during levitation and arc melting of Fe-C-Mn filler metals, the time-dependent changes of nitrogen content were determined as well as the mass transfer coefficients b and the rates of nitrogen absorption. Nitrogen absorption rate decreases along with the increase of oxygen content in the Fe-C-Mn filler metals arc-melted in the Ar+N₂ atmosphere. Research limitations/implications: Investigation of the Fe-C-Mn complex alloys with the specified amount of impurities makes the detailed analysis of the elementary stages of nitrogen dissolution more difficult, yet brings the experiment conditions closer to those occurring in the actual welding processes. Practical implications: Recognizing the mechanisms of nitrogen absorption under arc and non-arc melting to make possible the control of nitrogen level in the welds. Originality/value: Obtained results explain the influence of oxygen and melting conditions on kinetics of nitrogen dissolution in Fe-C-Mn alloys.
Wydawca
Rocznik
Tom
Strony
109--112
Opis fizyczny
Bibliogr. 16 poz.
Twórcy
autor
- Welding Department, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, andrzej.gruszczyk@polsl.pl
Bibliografia
- [1] R.D. Pehlke, Kinetics and thermodynamics of interaction between liquid metals and gases, Moscow, 1974 (in Russian).
- [2] R.J. Fruehan, L.J Martonik, The Rate of absorption of Nitrogen into Liquid Iron Containing Oxygen and Sulfur, Metallurgical Transactions B 11 (1980) 615-621.
- [3] R.J. Fruehan, L.J Martonik, The Rate of Absorption of Nitrogen into Fe-Cr and Fe-Cr-Ni Alloys, Metallurgical Transactions B 12 (1981) 379-384.
- [4] P.C. Glaws, R.J. Fruehan, The Kinetics of the Nitrogen Reaction with Liquid Iron-Sulfur Alloys, Metallurgical and Materials Transactions B 16 (1985) 551-559.
- [5] G.R. Belton, How Fast Can We Go? The Status of Our Knowledge on the Rates of Gas-Liquid Metal Reaction, Metallurgical and Materials Transactions B 24 (1993) 241-258.
- [6] N. Hirashima, R.T.C. Choo, I.M. Toguri, K. Mukai, The effect of Surface Movements on Nitrogen Mass Transfer in Liquid Iron, Metallurgical and Materials Transactions B 26 (1995) 971-980.
- [7] H. Ono, H. Fukagawa, K. Morita, N. Sano, Effects of O, Se and Te on the Rate of Nitrogen Dissolution in Molten Iron, Metallurgical and Materials Transactions B 27 (1996) 848-853.
- [8] C.J Allum, Nitrogen Absorption from Welding Arc, MIS Doc.II-A-799-90, (1990).
- [9] J.D. Katz, T.B King, The Kinetics of Nitrogen Absorption and Desorption from Plasma Arc by Molten Iron, Metallurgical Transactions B 20 (1989) 175-185.
- [10] K. Mundra, T. DebRoy, A General Model for Partitioning of Gases between a Metal and Its Plasma Environment, Metallurgical and Materials Transactions B 26 (1995) 149-157.
- [11] D.G. Howden, D.R. Milner, Hydrogen Absorption in Arc Melting, British Welding Journal 10 (1963) 304-316.
- [12] M. Uda, S. Ohno, Effect of Surface Active Elements on Nitrogen Content of Iron under Arc Melting, Transactions of National Research Institute for Metals NRIM 15 (1973) 20-28.
- [13] J.W. Hooijmans, G. den Ouden, The Influence of Oxygen on Nitrogen Absorption during Arc Melting of Iron, Welding Journal 71 (1992) 337-380.
- [14] J. Węgrzyn, R.L. Apps, Effect of Nitrogen on Fissuring in Mild Steel Weld Deposit, British Welding Journal 15 (1968) 532-540.
- [15] M.F. Sidorenko, Theory and Technology of Steel Arc Melting, Metallurgya, Moscow, 1985 (in Russian).
- [16] A. Gruszczyk, The Absorption of Nitrogen by Arc Melted Fe-C-Mn Filler Metals, Silesian Technical University Publishing, Gliwice, 1999 (in Polish).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL8-0028-0024