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Studying of polyoxadiazole with Si atom in the backbone

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Języki publikacji
EN
Abstrakty
EN
Purpose: The aim of this paper is to show properties of spin-coated thin films of new polymer having silicon atom in the backbone. This amorphous polymer has appeared to be applied as active films in organic devices (as OLED). Design/methodology/approach: Thin films of 4-(diphenyl(4-(4-(5-(p-tolyoxy)phenyl)-1,3,4-oxadiazol-2-yl)phenyloamino)methyl)-phenyl)silyl)-1-methylbenzamide (Oxad–Si-B) were obtained by spin-coating method. The methodology of preparing was changing of technological parameters such as solution concentration and spinning rate V. The films were deposited with five spinning rates. Findings: Such technological parameters as spinning rate and solution concentration has appeared to influence optical properties of thin films. These parameters were found to influence surface morphology and UV-Vis absorption spectra of thin films. Research limitations/implications: The optical properties of obtained films will allow further researches of this polymer. Its optical properties allow carrying of electrical measurements, which will be carried out in the nearest time. Practical implications: The value of Oxad-Si (B) energy gap suggests its luminescent properties and applications of this material as active film in optoelectronic devices. Originality/value: The goal of this paper is to show optical properties of thin films prepared with most optimal technology conditions.
Rocznik
Strony
77--84
Opis fizyczny
Bibliogr. 15 poz.
Twórcy
autor
autor
autor
autor
autor
autor
  • Division of Materials Processing Technology, Management and Computer Techniques in Materials Science, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, bhajduk@cchp-pan.zabrze.pl
Bibliografia
  • [1] A. Talaie, Y.K. Lee, J. Jang, D.J. Choo, S.M. Park, J.Y. Lee, S.H. Park, G. Huh, T. Taguchi, E. Maeder, Smart polymers with light emission ability: millennium products for intelligent displays for navigation in the transportation industry, International Journal of Materials and Product Technology 19/3-4 (2003) 304-313.
  • [2] A. Kubono, N. Okui, Polymer thin films prepared by vapour deposition, Progress Polymer Science 19 (1994) 389-438.
  • [3] J. Mc. Elvain, S. Tatsuura, F. Wudl, A.J. Heeger, Linear and nonlinear optical spectra of polyazomethines fabricated by chemical vapour deposition, Synthetic Metals 95/2 (1998) 101-105.
  • [4] M.S. Weaver, D.D.C. Bradley, Organic electroluminescence devices fabricated with chemical vapour deposited polyazomethine films, Synthetic Metals 83 (1996) 61-66.
  • [5] B. Hajduk, J. Weszka, J. Jurusik, Influence of LCVD technological parameters on properties of polyazomethine thin films, Journal of Achievements in Materials and Manufacturing Engineering 36/1 (2009) 41-48.
  • [6] B. Hajduk, J. Weszka, B. Jarząbek, J. Jurusik, M. Domański, Physical properties of polazomethine thin films doped with iodine, Journal of Achievements in Materials and Manufacturing Engineering 24/2 (2007) 67-70.
  • [7] A. Freydank, S. Janietz, B. Schulz Synthesis and elecktro-chemical behavior of amphihilic 1,3,4 -oxadiazole derivatives, Journal of Elektroanalitycal Chemistry 456 (1998) 61-69.
  • [8] E. Hamciuc, M. Bruma, T. Köpnick, Y. Kaminorz, B. Schulz, Synthesis and study of new silicon-containing polyoxadiazoles, Polymer 42 (2001) 1809-1815.
  • [9] M. Bruma, T. Köpnick, Silicon-containing polyoxadiazoles-synthesis and perspectives, Advances in Colloid and Interface Science 116 (2005) 277-290.
  • [10]B. Hajduk, J. Weszka, V. Cozan, B. Kaczmarczyk, B. Jarząbek, M. Domański, Optical properties of polyazomethine with oxygen atom in the backbone, Archives of Materials Science and Engineering32/2 (2008) 85-88.
  • [11]L. Marin, V. Cozan, M. Bruma, V.C. Grigoras, Synthesis and thermal behaviour of new poly(azomethine-ether), European Polymer Journal 42 (2006) 1173-1182.
  • [12]F. Queirolo, M. Alessandri, A. Sassela, Influence of roughness and grain dimension on the optical functions of polycrystalline silicon films, Thin Solid Films 313-314 (1998) 243-247.
  • [13]F. Taylor, Spin coating: An Overview, Metal Finishing 99/1 (2001) 16-21.
  • [14]M. Deepa, T.K. Saxena, D.P Singh, K.N. Sood, S.A. Agnihotry, Spin coated versus dip coated electrochromic tungsten oxide films: Structure, morphology, optical and electrochemical properties, Electrochimica Acta 51 (2006) 1974-1989.
  • [15]J. Weszka, L.A. Dobrzański, P. Jarka, J. Jurusik, B. Hajduk, M. Bruma, J. Konieczny, D. Małkowski, Studying of spin-coated oxad-Si propertiesm, Journal of Achievements in Materials and Manufacturing Engineering 22/2 (2009) 505-511.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL7-0048-0020
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