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Corrosion resistance of high-manganese austenitic steels

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The aim of the paper is to compare the corrosion resistance of two new-developed high-manganese austenitic steels in 1N H2SO4 and 3.5% NaCl solutions. Design/methodology/approach: The steels used for the investigation were thermo-mechanically rolled and then solution heat-treated from a temperature of 850°C. Corrosion resistance of investigated steels was examined using the immersion test. The specimens were weighed and dipped in the prepared solutions for 100 h. After the test, the percentage weight loss was calculated. The metallographic investigations of corrosion damages included light and scanning electron microscope observations both in the polished and etched states. Findings: It was found that after the thermo-mechanical processing one steel is characterized by an austenitic structure with numerous annealing twins, whereas in the second steel ε and α' martensite plates in an austenitic matrix were observed. According to the results of the immersion tests it was found that the examined steels exhibit a comparable corrosion resistance. They show very poor corrosion resistance in H2SO4 solution and low corrosion resistance in NaCl medium. The weight loss in chloride solution is much lower, what is explained by different corrosion mechanisms. In both the solutions, the intensive general corrosion and corrosion pitting were observed. In acidic medium they are created in a way of hydrogen depolarization and in NaCl in the way of oxygen depolarization. Research limitations/implications: To investigate in more detail the corrosion behaviour of high-manganese austenitic steels, the investigations should include polarization tests and an analysis of corrosion products. Practical implications: The obtained results can be used to search for the appropriate way of improving the corrosion resistance of high-manganese steels with a single-phase austenitic structure as well as the austenite structure containing ε and α' martensite. Originality/value: The corrosion resistance of two types of advanced high-strength high-manganese austenitic steels with different initial structures was compared in acidic and chloride solutions.
Rocznik
Strony
77--84
Opis fizyczny
Bibliogr. 25 poz.
Twórcy
autor
  • Division of Constructional and Special Materials, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, adam.grajcar@polsl.pl
Bibliografia
  • [1] D. Matlock, Microstructural aspects of advanced high strength sheet steels, Report of Advanced High Strength Steels Workshop, Arlington, Virginia, 2006, 1-25.
  • [2] R. Kuziak, R. Kawalla, S. Waengler, Advanced high strength steels for automotive industry, Archives of Civil and Mechanical Engineering 8/2 (2008) 103-117.
  • [3] J. Adamczyk, A. Grajcar, Heat treatment and mechanical properties of low-carbon steel with dual-phase microstructure, Journal of Achievements in Materials and Manufacturing Engineering 22/1 (2007) 13-20.
  • [4] A. Grajcar, Hot-working in the γ+α region of TRIP-aided microalloyed steel, Archives of Materials Science and Engineering 28/12 (2007) 743-750.
  • [5] B. Wietbrock, M. Bambach, S. Seuren, G. Hirt, Homogenization strategy and material characterization of high-manganese TRIP and TWIP steels, Materials Science Forum 638-642 (2010) 3134-3139.
  • [6] J.A. Jimenez, G. Frommeyer, Microstructure and texture evolution in a high manganese austenitic steel during tensile test, Materials Science Forum 638-642 (2010) 3272-3277.
  • [7] G. Frommeyer, U. Brüx, P. Neumann, Supra-ductile and high-strength manganese-TRIP/TWIP steels for high energy absorption purposes, ISIJ International 43 (2003) 438-446.
  • [8] O. Grässel, L. Krüger, G. Frommeyer, L.W. Meyer, High strength Fe-Mn-(Al, Si) TRIP/TWIP steels development – properties – application, International Journal of Plasticity 16 (2000) 1391-1409.
  • [9] S. Allain S, J-P. Chateau, D. Dahmoun, O. Bouaziz, Modeling of mechanical twinning in a high manganese content austenitic steel, Materials Science and Engineering A 387-389 (2004) 272-277.
  • [10] B.X. Huang, X.D. Wang, Y.H. Rong, L. Wang, L. Jin, Mechanical behaviour and martensitic transformation of an Fe-Mn-Si-Al-Nb alloy, Materials Science and Engineering A 438-440 (2006) 306-313.
  • [11] T. Bator, Z. Muskalski, S. Wiewiórowska, J.W. Pilarczyk, Influence of the heat treatment on the mechanical properties and structure of TWIP steel in wires, Archives of Materials Science and Engineering 28/6 (2007) 337-340.
  • [12] L.A. Dobrzański, A. Grajcar, W. Borek, Influence of hot-working conditions on a structure of high-manganese austenitic steels, Journal of Achievements in Materials and Manufacturing Engineering 29/2 (2008) 139-142.
  • [13] A. Grajcar, M. Opiela, G. Fojt-Dymara, The influence of hot-working conditions on a structure of high-manganese steel, Archives of Civil and Mechanical Engineering 9/3 (2009) 49-58.
  • [14] L.A. Dobrzański, A. Grajcar, W. Borek, Hot-working behaviour of high-manganese austenitic steels, Journal of Achievements in Materials and Manufacturing Engineering 31/1 (2008) 7-14.
  • [15] L.A. Dobrzański, A. Grajcar, W. Borek, Microstructure evolution and phase composition of high-manganese austenitic steels, Journal of Achievements in Materials and Manufacturing Engineering 31/2 (2008) 218-225.
  • [16] Y.S. Zhang, X.M. Zhu, Electrochemical polarization and passive film analysis of austenitic Fe-Mn-Al steels in aqueous solutions, Corrosion Science 41 (1999) 1817-1833.
  • [17] M.B. Kannan, R.K.S. Raman, S. Khoddam, Comparative studies on the corrosion properties of a Fe-Mn-Al-Si steel and an interstitial-free steel, Corrosion Science 50 (2008) 2879-2884.
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  • [20] C.J. Altstetter, A.P. Bentley, J.W. Fourine, A.N. Kirkbridge, Processing and properties of Fe-Mn-Al alloys, Materials Science and Engineering A82 (1986) 13-25.
  • [21] H.J. Cleary, N.D. Greene, Corrosion properties of iron and steel, Corrosion Science 7 (1967) 821-831.
  • [22] A.S. Hamada, L.P. Karjalainen, M.A. El-Zeky, Effect of anodic passivation on the corrosion behaviour of Fe-Mn-Al steels in 3.5%NaCl, Proceedings of the 9th International Symposium “Passivation of Metals and Semiconductors and the Properties of Thin Oxide Layers”, Paris, 2005, 77-82.
  • [23] M. Opiela, A. Grajcar, W. Krukiewicz, Corrosion behaviour of Fe-Mn-Si-Al austenitic steel in chloride solution, Journal of Achievements in Materials and Manufacturing Engineering 33/2 (2009) 159-165.
  • [24] S. Prowans, Physical metallurgy, PWN, Warsaw, 1988 (in Polish).
  • [25] R.A. Cottis, Stress corrosion cracking, Corrosion and Protection Centre, UMIST, Teddington, 1982.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL7-0045-0068
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