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Tytuł artykułu

Relaxor properties of Ba1-xNaxTi1-xNbxO3 at low temperatures

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Wybrane pełne teksty z tego czasopisma
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Języki publikacji
EN
Abstrakty
EN
Purpose: The purpose of this paper is to investigate ferroelectric relaxor behavior of polycrystalline solid solutions of Ba1-xNaxTi1-xNbxO3 (for x = 0.3 and x = 0.4) at low temperatures (113 K - 473 K). Design/methodology/approach: The dielectric spectroscopy method has been applied to measure dielectric and electric parameters within the frequencies from 20 Hz to 1 MHz. Findings: Temperature dependences of real (ε') and imaginary (ε'') parts of dielectric permittivity confirm relaxor type of polarization behavior for both investigated materials. Experimental findings are in good agreement with data published in literature. Diffused phase transition of relaxor character is analysed in the terms of departure from Curie-Weiss rule. A dependence of the temperature related to the maximum of dielectric permittivity on the frequency has activated character. Different thermal activation energies found for the investigated materials may be related to their different microstructures. Research limitations/implications: Further investigations should be carried on in a broaden frequency range (up to 1.8 GHz) in order to establish an influence of network dynamics on ferroelectric-paraelectric phase transition. Originality/value: Relaxor behaviour in polycrystalline solid solution of Ba1-xNaxTi1-xNbxO3 (for x = 0.3 and x = 0.4) is described.
Rocznik
Strony
23--26
Opis fizyczny
Bibliogr. 15 poz.
Twórcy
autor
  • Institute of Physics, Pedagogical University, ul. Podchorążych 2, 30-084 Kraków, Poland, wbak@ap.krakow.pl
Bibliografia
  • [1] F. Bahri, H. Khemakhem, M. Gargouri, A. Simon, R. Von der Muhll, J. Ravez, Dielectric and Raman studies on the solid solution (1-x)BaTiO3/xNaNbO3 ceramics, Solid State Sciences 5 (2003) 1445-1450.
  • [2] C. Kajtoch, Long range electrical ordering in BaTiO3 – BaSnO3 solid solution, Scientific Press WSP, Cracow, 1998 (in Polish).
  • [3] R. Skulski, The diffusion of the phase transitions in the selected groups of ferroelectrics and relaxsors, Silesian University Press, Katowice, 1999, (in Polish).
  • [4] L.E. Cross, Relaxor ferroelectrics: An overview, Ferroelectrics 151 (1994) 305-320.
  • [5] A. Buchacz, Influence of piezoelectric on characteristics of vibrating mechatronical system, Journal of Achievements in Materials and Manufacturing Engineering 17 (2006) 229-232.
  • [6] A. Buchacz, A. Wróbel, Piezoelectric layer modelling by equivalent circuit and graph method, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 299-302.
  • [7] Landolt-Boernstein, New Series 3, Vol. 3, Springer-Verlag, Berlin-Heidelberg-New York, 1969.
  • [8] C. Kuś, W. Bąk, W.S. Ptak, W. Śmiga, Antiferroelectricparaelectric phase transformation in nonstoichiometric NaNbO3, Ferroelectrics 81 (1988) 277-280.
  • [9] H. Abdelkefi, H. Khemakhem, G. Velu, J.C. Carru, R. Von der Muhll, Dielectric properties of ferroelectric ceramics derived from the system BaTiO3 – NaNbO3 – based solid solutions, Solid State Sciences 6 (2004) 1347-1351.
  • [10] H. Khemakhem, A. Simon, R. Von der Muhll, J. Ravez, Relaxor or classical ferroelectric behaviour with composition Ba1-xNaxTi1-xNbxO3, Journal of Physics: Condensed Matter 12 (2000) 5951-5959.
  • [11] J. Ravez, A. Simon, Non-stoichiometric perovskites derived from BaTiO3 with a ferroelectric relaxor behaviour, Physica Status Solidi (a) 178 (2000) 793-797.
  • [12] W. Bąk, C. Kajtoch, F. Starzyk, Dielectric properties of BaTi1-xSnxO3 solid solution, Materials Science and Engineering B100 (2003) 9-12.
  • [13] W. Bąk, F. Starzyk, C. Kajtoch, E. Nogas-Ćwikiel, Elevated temperature induced dispersion phenomena in Ba1-xNaxTi1-xNbxO3, Archives of Materials Science and Engineering 29/1 (2008) 5-9.
  • [14] C. Kajtoch, W. Bąk, F. Starzyk, M. Gabryś, Study of phase transition specific in polycrystalline Pb(Cd1/3Nb1/3)O3, Archives of Materials Science and Engineering 29/1 (2008) 20-23.
  • [15] F. Starzyk, W. Bąk, C. Kajtoch, M. Gabryś, Influence of electric field DC-component on AC-response of ferroelectric powder, Archives of Materials Science and Engineering 29/1 (2008) 36-39.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BSL7-0033-0026
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