Electric properties of ice near solidification and melting temperature

• Autorzy: Rusiniak L.
• Języki publikacji: EN

Abstrakty

EN

The dielectric permittivity, conductivity and loss tangent of ice were measured for different thicknesses of the sample (0.1-4 mm). In this investigation, the measurement of thin samples can be treated as a laboratory test of surface proper-ties and that of thick samples as a test of bulk properties. The measurements were carried out from 3.5 to -13.5°C with descending and growing temperature. Two domain Debye resonances were observed. The one at low frequency is interpreted as being associated with transversal mode, and the other, at higher frequency, is associated with longitudinal mode of proton domain. The resonance frequencies depend on sample size and temperature. Temperature hysteresis of resonance frequencies was observed. As the temperature grows starting from low temperature, the resonance frequencies move towards each other and finally the two modes join to form one mode. The dielectric constant associated with transversal mode is higher than 104. The dielectric constant associated with longitudinal mode is about 102. The dipole dielectric constant vanishes after solidification. As the temperature grows, the di-pole dielectric constant grows too. Oscillation of dielectric permittivity and conductance for a small value of oscillator level was observed. The experimental data show that ice could be both a ferroelectric and a piezoelectric material.

Słowa kluczowe

EN

ice; dielectric permittivity; conductivity; loss tangent; ferroelectrics; piezoelectrics

• Wydawca: Instytut Geofizyki PAN
• Czasopismo: Acta Geophysica Polonica
• Rocznik: 2004
• Tom: Vol. 52, nr 3
• Strony: 363--380
• Opis fizyczny: Bibliogr. 38 poz.

Twórcy

autor

Rusiniak L.

• Institute of Geophysics, Polish Academy of Sciences, Księcia Janusza 64, 01-452 Warszawa

Bibliografia

• 1. Auty, R.P., and R.H. Cole, 1952, Dielectric properties of ice and solid D2O, J. Chem. Phys. 20, l 1309-1314.
• 2. Bishop, P.G., and J.W. Glen, 1969, Electrical polarization effects in pure and doped ice at Iow temperatures. In: "Physics of Ice", Proc. Intern. Symp. Munich, Plenum Press, New York, 492-501.
• 3. Bullemer, B., H. Engelhardt and N. Riehl, 1969, Protonie conduction ofice. Part I: High tem¬perature region. In: "Physics of Ice", Proc. Intern. Symp. Munich, Plenum Press, New York, 416-429.
• 4. Camp, P.R., 1966, Water and ice, The Encyclopedia of Chemistry, Reinhold Publ. Comp., New York, 1090-1091.
• 5. Camp, P.R., W. Kiszenick and D. Arnold, 1969, Electrical conduction in ice. In: "Physics of Ice", Proc. Intern. Symp. Munich, Plenum Press, New York, 450-470.
• 6. Cole, R.H., and O. Worz, 1969, Dielectric properties of ice 1. In: "Physics of Ice", Proc. Intern. Symp. Munich, Plenum Press, New York, 546-554.
• 7. Debye, P., 1945, Polar Molecules, Dover Publications, Dover, N.Y.
• 8. Dengel, O., U. Eckener, H. Plitz and N. Riehl, 1964, Ferroelectric behaviour of ice, Phys. Letters 9, 291-292.
• 9. Dengel, O., A. Riehl and A. Schleippmann, 1966, Messungen der dielektrizitatskontanten von reinem und NH4F-dotierem eis, Physik kondens. Materie 5, 83-88.
• 10. Engelhardt, H., and N. Riehl, 1965, Space-charge limited proton currents in ice, Physics Letters 14,20-21.
• 11. Fischer, S.F., and G.L. Hofacker, 1969, Theory of the mobility of structural defects in ice. In: "Physics of ice", Proc. Intern. Symp. Munich, Plenum Press, New York, 369-384.
• 12. Gelin, H., and R. Stubbs, 1965, Ice electrets, J. Chem. Phys. 42, 967-971.
• 13. Glen, J.W., 1958, The mechanical properties of ice. I. The plaslic properties of ice, Adv. in Phys. 7, 26, 254-265.
• 14. Glockmann, H.P., 1969, Conduction anoalies and polarization in ice at low temperatures, Physics of ice, Plenum Press, N Y, 502-513.
• 15. Granicher, H., 1969a, Review on problems of the physics of ice. In: "Physics of Ice", Proc. Intern. Symp. Munich, Plenum Press, New York, 1-18.
• 16. Granicher, H., 1969b, Evaluation of dielectric dispersion data. In: "Physics of Ice", Proc. In tern. Symp. Munich, Plenum Press, New York, 527-533.
• 17. Homes, C.C., T. Vogt, S.M. Shapiro, S. Wakimoto and A.P. Ramirez, 2001, Optical response of high-dielectric-constant perovskite-relatedoxide, Science 293, 673-676.
• 18. Jones, S.J., and J.W. Glen, 1969, Impurity effects on the plasticity of ice and their explanation in terms of hydrogen reorientation. In: "Physics of ice", Proc. Intern. Symp. Munich, Plenum Press, N Y, 217-222.
• 19. Kittel, C., 1966, Introduction to Solid State Physics, John Wiley and Sons, New York.
• 20. Lieb, E.H., 1967a, Exact solution of the problem of the entropy of two-dimensional ice, Phys. Rev. Letters 18, 692-694.
• 21. Lieb, E.H., 1967b, Exact solution of the F model of an antiferroelectric, Phys. Rev. Letters 18, 1046-1048.
• 22. Mascarenhas, S., 1969, Charge and polarization storage in ice crystals. In: "Physics of ice", Proc. Intern. Symp. Munich, Plenum Press, New York, 483-491.
• 23. Onsager, L., 1967, Ferroelectricity of ice? In: E. Weller (ed.), "Ferroelectricity", Elsevier, Amsterdam.
• 24. Onsager, L., 1969, Protonic semiconductors. In: "Physics of Ice", Proc. Intern. Symp. Munich Plenum Press, New York, 363-368.
• 25. Owston, P.G., 1958, The structure of ice I, as determined by X-ray and neutron diffraction analysis, Advances in Physics (Phil. Mag. Suppl.) 7, 26, 171-188.
• 26. Ruepp, R., and M. Kass, 1969, Dielectric relaxation, bulk and surface conductivity of ice single crystals. In: "Physics of Ice", Proc. Intern. Symp. Munich, Plenum Press,'. York, 555-561.
• 27. Runnels, L.K., 1969, Diffusion and relaxation phenomena in ice. In: "Physics of Ice", Intern. Symp. Munich, Plenum Press, New York, 514-526.
• 28. Rusiniak, L., 2000, Dielectric properties and structure of water at room temperature. New experimental data in 5Hz- 13 MHz frequency range, Phys. Chem. Earth (A) 25,2,201- 207.
• 29. Smyth, C.P., and C.S. Hitchcock, 1932, Dipole rotation in crystalline solids, J. Am. Soc. 54,4631-4637.
• 30. Steineman, A., and H. Granicher, 1957a, Dielektrische eigenschafen von eiskristallen dynamisch theorie der dielektrizitatskonstante, Helv. Phys. Acta 30, 553-580.
• 31. Steineman, A., and H. Granicher, 1957b, Dielektrische untersuchungen au eiskristallen mit eingelagerten fremdatomen, Helv. Phys. Acta 30, 581-610.
• 32. Sutherland, B., 1967, Exact solution of the two-dimensional model for hydrogen-bonded crystals, Phys. Rev. Letters 19, 103-104.
• 33. Sutherland, B., C.N. Yang and C.P. Yang, 1967, Exact solution of the two-dimensional model for hydrogen-bonded crystals, Phys. Rev. Letters 19, 588-591.
• 34. Truby, F.K., 1955, Hexagonal microstructure of ice crystals, J. Appl. Phys. 26, 1416-1420.
• 35. Vaubel, G., 1963, Thesis, Lab. Technische Physik, Technische Hochschule, Munchen.
• 36. Workman, E., 1953, The cellular nature of ice crystals, Phys. Rev. 92,544-550.
• 37. Workman, E., and S. Reynolds, 1950, Electrical phenomena occuring during of the freezing of dilute aqueous solutions and their possible relationship to thunderstorm electricity, Phys. Rev. 78, 254-259.
• 38. Yang, C.P., 1967, Exact solution of a model of two-dimensional ferroelectrics in an arbitrary external electric field, Phys. Rev. Letters 19, 586-588.