Potencjalne metody zagospodarowania karbonizatów z opon samochodowych

• Autorzy: Stelmach S.

Warianty tytułu

EN

Potential methods for the utilisation of chars from used tyres

• Języki publikacji: PL

Abstrakty

PL

W publikacji przedstawiono problematykę związaną z zagospodarowaniem karbonizatów powstających podczas pirolizy zużytych opon samochodowych. Zużyte opony samochodowe stanowią wciąż poważny, nierozwiązany problem środowiskowy. W Polsce rocznie ilość wytwarzanych zużytych opon szacowana jest na ok. 160-170 tys. ton. Od wielu lat obserwowane jest rosnące zainteresowanie pirolityczną przeróbką zużytych opon samochodowych. Niestety stały produkt powstający w jej trakcie jest trudny do zagospodarowania, co w praktyce pogarsza ekonomikę procesu pirolizy. W publikacji dokonano prezentacji potencjalnych kierunków zagospodarowania karbonizatów z pirolizy zużytych opon samochodowych, opracowanej w oparciu o analizę literaturową, rozeznanie rynkowe oraz doświadczenia własne. Przeprowadzono również uproszczoną ocenę potencjalnych kierunków zagospodarowania tych materiałów.

EN

The paper presents problems connected with utilisation of chars obtained during pyrolysis of used tyres. Used tyres are still serious, unsolved environmental problem. In Poland, the annual amount of generated used tires is estimated at about 160-170 thousand tonnes. For many years, there is observed continuously growing interest in the pyrolytic processing of used tyres. Unfortunately, the solid product formed (char) is difficult to utilise, which in practice is deteriorating economics of the pyrolysis process. The publication describes potential directions of used tyres char utilisation, developed based on literature analysis, market insight and experience of its own. Simplified assessment of the potential directions of these materials utilisation is also carried out.

Słowa kluczowe

PL

opona samochodowa; utylizacja odpadów; piroliza; zagospodarowanie odpadów; recykling odpadów gumowych

EN

car tyre; waste utilization; pyrolysis; waste disposal; recycling of rubber waste

• Wydawca: Mastermedia sp. z o.o.
• Czasopismo: Archiwum Gospodarki Odpadami i Ochrony Środowiska
• Rocznik: 2011
• Tom: Vol. 13, nr 3
• Strony: 37--52
• Opis fizyczny: Bibliogr. 41 poz.

Twórcy

autor

Stelmach S.

• Instytut Chemicznej Przeróbki Węgla, ul. Zamkowa 1, Zabrze 41-803, tel. [phone], fax [phone],

Bibliografia

• [1] Rubber Manufacturers Association. http://www.rma.org.
• [2] Singh S., Nimmo W., Tayyeb Javed M., Williams P.T.: Co-combustion of pulverized coal with waste plastic and tire rubber powders. Energy & Fuels, 25 (2011) 108-118.
• [3] Statistical Information and Elaborations. Environment 2010. Central Statistical Office, Poland, Warsaw, 2010.
• [4] Galvagno S., Casu S., Martino M., Di Palma E., Portofino S.: Thermal and kinetic study of tyre waste pyrolysis via TG-FTIR-MS analysis. Journal of Thermal Analysis and Calorimetry, 88, 2 (2007) 507-514.
• [5] Shah J., Jan M.R., Mabood F.: Recovery of value-added products from the catalytic pyrolysis of waste tyre. Energy Conversion and Management, 50, 4 (2009) 991-994.
• [6] Boxiong S., Chunfei W., Cai L., Binbin G., Rui W.: Pyrolysis of waste tyres: The influence of USY catalyst/tyre ratio on products. Journal of Analytical and Applied Pyrolysis, 78, 2 (2007) 243-249.
• [7] Paradela F., Pinto F., Ramos A.M., Gulyurtlu I., Cabrita I.: Study of the slow batch pyrolysis of mixtures of plastics, tyres and forestry biomass wastes. Journal of Analytical and Applied Pyrolysis, 85, 1-2 (2009) 392-398.
• [8] Aylón E., Fernández-Colino A., Murillo R., Navarro M.V., García T., et. al.: Valorisation of waste tyre by pyrolysis in a moving bed reactor. Waste Management Volume, 30, 7 (2010) 1220-1224.
• [9] Boxiong S., Chunfei W., Binbin G., Rui W., Liangcai: Pyrolysis of waste tyres with zeolite USY and ZSM-5 catalysts. Applied Catalysis B, Environmental Volume, 73, 1-2 (2007) (150-157).
• [10] Aylón E., Fernández-Colino A., Murillo R., Grasa G., Navarro M.V., García T., et. al.: Waste tyre pyrolysis: Modelling of a moving bed reactor. Waste Management, 30, 12 (2010) 2530-2536.
• [11] López G., Olazar M., Aguado R., Bilbao J.: Continuous pyrolysis of waste tyres in a conical spouted bed reactor. Fuel, 89, 8 (2010) 1946-1952.
• [12] Helleur R., Popovic N., Ikura M., Staniciulescu M., Liu D.: Characterization and potential application of pyrolytic char from ablative pyrolysis of used tires. Journal of Analytical and Applied Pyrolysis, 58-59 (2001) 813-824.
• [13] http://www.rubber-compounding.com.
• [14] http://www.bpri.org/papers/chapman300102.pdf.
• [15] Atal A., Levendis Y.A.: Comparison of the combustion behaviour of pulverized waste tyres and coal. Fuel, 74, 11, 1570-1581, 1995.
• [16] Bilal Butt S., Innayat M., Riaz M., Mahmood A.: Activated carbon from scrap tires for water purification. 24th WEDC Conference SANITATION AND WATER FOR ALL, Islamabad, Pakistan, 1998.
• [17] Darmstadt H., Roy Ch., Kaliaguine S.: Characterization of pyrolytic carbon blacks from commercial tire pyrolysis plants. Carbon, 33, 1449÷1455, 1995.
• [18] Gonzalez J.F., Encinar J.M., Canito J.L., Rodriguez J.J.: Pyrolysis of automobile tyre waste. Influence of operating variables and kinetics study. Journal of Analytical and Applied Pyrolysis, 58-59, 667-683, 2001.
• [19] Napoli A., Soudais Y., Lecomte D., Castillo S.: Scrap tyres pyrolysis: Are the effluents valuable products? Journal of Analytical and Applied Pyrolysis, 40-41, 373-382, 1997.
• [20] 5 Program Ramowy Komisji Europejskiej, Projekt CRAFT nr CR-1999-70614 pt.: „Thermal treatment of scrap tyres to produce reusable carbon black”, akronim: SCRAPTREAT (sprawozdania IChPW - niepublikowane).
• [21] Roy C., Chaala A., Darmstadt H.: The vacuum pyrolysis of used tires. End-uses for oil and carbon black products. Journal of Analytical and Applied Pyrolysis, 51, 201-221, 1999.
• [22] Solisio C., Lodi A., Del Borghi M.: Treatment of effluent containing micropollutants by means of activated carbon. Waste Management, 21, 33-40, 2001.
• [23] Bratek W., Bratek K., Kułażyński M.: The utilization of waste ion exchange resin in environmental protection. Fuel Processing Technology, 77-78, 431-436, 2002.
• [24] Sainz-Diaz C.I., Griffiths A.J.: Activated carbon from solid wastes using a pilot-scale batch flaming pyrolyser. Fuel, 79, 1863-1871, 2000.
• [25] Oh G.H., Park Ch.R.: Preparation and characteristics of rice-straw-based porous carbons with high adsorption capacity. Fuel, 81, 327-336, 2002.
• [26] Razouk R.I., El-Inany G.A., Fahim R.B., Mikhail R.Sh.: The adsorptive properties of carbonised agricultural wastes. 1. Adsorption of some vapours on carbonised rice husks and rice stalks. J.Chem.U.A.R., 3, 11-22, 1960.
• [27] László K., Bóta A., Nagy L.G.: Characterization of activated carbons from waste materials by adsorption from aqueous solutions. Carbon, 35, 593-598, 1997.
• [28] Izquierdo M.T., Rubio B., Mayoral C., Andrés J.M.: Low cost coal-based carbons for combined SO2 and NO removal from exhaust gas. Fuel, 82, 147-151, 2003.
• [29] Lu G.Q., Do D.D.: Preparation of economical sorbents for SO2 and NOx removal using coal washery reject, Carbon, 29, 207-213, 1991.
• [30] Sainz-Diaz C.I., Griffiths A.J.: Activated carbon from solid wastes using a pilot-scale batch flaming pyrolyser. Fuel, 79, 1863-1871, 2000.
• [31] László K., Bóta A., Nagy L.G.: Characterization of activated carbons from waste materials by adsorption from aqueous solutions. Carbon, 35, 593÷598, 1997.
• [32] Streat M., Patric J.W., Camporro Perez M.J.: Sorption of phenol and para-chlorophenol from water using conventional and novel activated carbons. Water Research, 29, 467-472, 1995.
• [33] San Miguel G., Fowler G.D., Sollars Ch.J.: A study of the characteristics of activated carbons produced by steam and carbon dioxide activation of waste tyre rubber. Carbon, 41, 1009-1016, 2002.
• [34] Allen J.L., Gatz J.L., Eklund P.C.: Applications for activated carbons from used tires: butane working capacity. Carbon, 37, 9, 1485-1489, 1999.
• [35] Brady T.A., Rostam-Abadi M., Rood M.J.: Applications for activated carbons from waste tires: natural gas storage and air pollution control. Gas Separation and Purification, 10, 2, 97-102, 1996.
• [36] Ko D.C.K., Mui E.L.K., Lau K.S.T., McKay G.: Production of activated carbons from waste tire - process design and economical analysis. Waste Management, 24, 9, 875-888, 2004.
• [37] Jastrząb K., Stelmach S., Figa J.: Adsorbenty węglowe otrzymane ze zużytych opon przeznaczone do usuwania rtęci z gazów spalinowych. Praca zbiorowa pod redakcją Z. Dębowskiego pt. Węgiel aktywny w ochronie środowiska i przemyśle. Wydawnictwo Politechniki Częstochowskiej, 157-167, 2008.
• [38] Gallup J., Hutson N.: Getting Mercury Out of Coal Combustion Gases, EPA Region 5 Science Forum, October 6, 2004, Chicago.
• [39] Waszak D., Walkowiak M., Stelmach S.: Application of nanocrystalline carbons from recycled car tyres in lithium-based energy storage devices. ALISTORE Summer School on Syntesis of Nanostructured Materials for Polimer Batteries, 2005.
• [40] Lee W.H., Kim J.Y., Ko Y.K., Reucroft P.J., Zondlo J.W.: Surface analysis of carbon black waste materials from tire residues. Applied Surface Science, 141, 1-2, 107-113, 1999.
• [41] Development of a prototype system for processing inkjet dispersions from postpyrolysis tyre char. Project reference numer: 2003-6-53, 2004.