Pliensbachian – lowermost Toarcian chemostratigraphy (elemental and TOC) of the Peniche section (Lusitanian Basin, Portugal)

• Autorzy: Veiga de Oliveira L. , Duarte L. , Rodrigues R.
• Konferencja: International Congress on the Jurassic System (7 ; 06-18.09.2006 ; Kraków, Poland]
• Języki publikacji: EN

Abstrakty

EN

In Portugal, the Peniche section constitutes one of the most continuous series of Lower Jurassic. This study is based on a detailed chemostratigraphic analysis of the Pliensbachian - lowermost Toarcian marly limestones, belonging to the Vale das Fontes, Lemede and Cabo Carvoeiro formations. 196 samples of limestones and marls were analyzed in terms of minor and major elements (Fig. 1). Total organic carbon (TOC) was determined in 233 samples. Besides the stratigraphic distribution of these geochemical parameters, the aim of this work is to perform a discussion about biogenic influx and aluminosilicate phasefluxes. The Al concentrations are a good indicator of detrital flux and good correlations between them signify aluminosilicate affiliation. In Peniche, K (0.98), Si (0.96) and Ti (0.98) show, in all section, excellent correlation with Al2O3. Mg (0.82), Ba (0.80), Cr (0.78), Li (0.80), Na (0.74), Sc (0.80), V (0.81) and Zr (0.86) correlate well with Al2O3 but other secondary factors, beyond the detrital flux, affect the resultant concentrations. The Pearson's coefficients between Al2O3 and CaO is strongly negative (-0.98), suggesting divergent behaviours for this elements. Al2O3 and Fe2O3 correlate moderately (0.61). However, the correlation coefficients calculated for each stratigraphic unit show variable values. Lemede Formation and the Members Marls and Limestones with Uptonia and Pentacrinus (MLUP), Lumpy Marls and Limestones (LML), to the Vale das Fontes Formation, and CC1, to the Cabo Carvoeiro Formation, show high correlation coefficients between Al2O3 and Fe2O3 (0.87, 0.91, 0.88 and 0.97, respectively). On the other hand, the Member CC2 has moderate correlation (0.67) and the Member Marls and Limestones with Bituminous Shales (MLBF) has weak correlation (0.20). These variations suggest that the elemental inputs change during the Pliensbachian - lowermost Toarcian, in the Peniche area. Ba enrichment is considered an indicator of high flux of biogenic material and high surface-water productivity. But, in the studied section, correlation between Al2O3 and Ba is high (0.80) and Ba lacks any correlation with TOC (0.17). Thus, in the Peniche region, the distribution of Ba is dominated by the original detrital flux and transported to the basin, mainly, as a constituent of clays. The mainly TOC values in the Pliensbachian - lowermost Toarcian of the Peniche section are below 2. But the MLBF (Ibex to Margaritatus zones) represents a high TOC interval with concentrations up to 15%, correlated with the 2nd order flooding interval, well know in the Lusitanian Basin.

Słowa kluczowe

EN

chemostratigraphy; Pliensbachian; Toarcian; Lusitanian Basin; Peniche; Portugal

• Wydawca: Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy
• Czasopismo: Volumina Jurassica
• Rocznik: 2006
• Tom: Vol. 4, no. 1
• Strony: 217--218

Twórcy

autor

Veiga de Oliveira L.

autor

Duarte L.

autor

Rodrigues R.

• Petrobras/Cenpes, Cidade Universitária, Ilha Fundao, 21941-598, Rio de Janeiro, Brasil,