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Thermodynamic analysis of cast irons solidification with various types of graphite

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The contribution summarises the results of oxygen activity determinations, which were measured and registered continuously in castings from cast irons with various types of graphite. The results were used to find the relationship between two variables: natural logarithm of oxygen activities and reverse value of thermodynamic temperature 1 /T. Obtained regression lines were used to calculate oxygen activity at different temperatures, to calculate Gibbs free energy \deltaG at the different temperatures and to calculate the single \deltaG value for significant temperature of the graphite solidification. The results were processed by a statistical analysis of data files for the different types of graphite with flake, vermicular and spheroidal graphite. Each material has its proper typical oxygen activities range and individual temperature function of Gibbs free energy for analysing and governing casting quality.
Rocznik
Strony
157--165
Opis fizyczny
Bibliogr. 15 poz., rys., tab., wykr.
Twórcy
autor
autor
  • VSB Technical University of Ostrava, Faculty of Metallurgy and Materials Engineering, 17. listopadu 15, 708 33 Ostrava-Poruba, Czech Republic, tomas.elbel@vsb.cz
Bibliografia
  • [1] J. C. Sturm, G. Busch, Cast Iron - a predictable material. China Foundry, l.8, (2011), 1, pp. 51-61.
  • [2] S. Lekakh, C. R. Loper, Jr., Improving inoculation of ductile iron. AFS Transactions, 111, (2003) pp.885-894.
  • [3] Oxygen and Sulphur-Metallurgical partners in cast iron melts. Foundry Trade Journal, 178), (2004), pp. 299-301.
  • [4] F. Mampaey, K. Beghym, Oxygen activity in cast iron measured induction furnace at variable temperature. AFS Transactions,.114, (2006), pp. 637-656.
  • [5] F. Mampaey, D. Habets, J. Plessers, F. Seutens, The use of oxygen activity measurement to determine optimal properties of ductile iron during production. Giessereiforschung-International Foundry Research 60,.(2008), 1, pp. 2-19.
  • [6] F. Mampaey, D. Habets, J. Plessers, F. Seutens, On-line oxygen activity measurements to determine optimal graphite form during compacted graphite iron production. International Journal of Metalcasting, (Spring 2010), pp. 25-40.
  • [7] J. Hampl, T. Elbel, Effect oxygen on graphite morphology and properties of modified cast iron, Archives of Foundry Engineering, 10, (2010), 4, pp.55-60.
  • [8] T. Elbel, J. Senberger,A. Zádera, J. Hampl : Behaviour of oxygen in cast irons. Archives of Materials Science and Engineering, 33, (2008), 2, pp.111-116.
  • [9] T. Elbel, J. Senberger, A. Zadera, L. Kocian, Study of the occurrence and suppression of metal reoxidation in ferrous castings . Proceedings of the 67th World Foundry Congress, Harrogate, ICME 2006, paper 94/1-94/10.
  • [10] A. Zadera, J. Senberger, T. Elbel, Reoxidation processes at casting ferrous alloys. Ceská slévárenská spolecnost. Brno, 2009, (in Czech).
  • [11] J. Senberger et al., Metallurgy of cast steel. Nakladatelství VUTIUM, Brno 2008, (in Czech).
  • [12] T. Myslivec, Basic of physical chemistry of steelmaking. SNTL, Praha, 1971, (in Czech).
  • [13] S. Katz, Principles of physical chemistry.ASM Handbook, vol.15, Casting, s. 50-64.
  • [14] J. P. Hrusovsky, J. F. Wallace, Effect of composition on solidification on compacted graphite iron. AFS Transactions. 93, (1985), pp .55-86.
  • [15] T. Elbel, J. Hampl, Influence of Al and Ti on microstructure and quality of compacted graphite iron castings. Metalurgija/Metallurgy, 48, (2009), 4, pp. 243-247.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPZ7-0006-0054
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