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Abstrakty
EN
The paper presents a method for the preparation of sulfonated polysulfone in order to receive a matrix to immobilisation of biomolecules. Optimum conditions of the synthesis are described. The phase inversion method was used to prepare a sulfonated polysulfone membrane and then urease was immobilized on the surface of the prepared matrix. Comparison of activity of native urease and the immobilized urease is presented.
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autor
  • Nałęcz Institute of Biocybernetics and Biomedical Engineering, Polish Academy of Sciences, ul. Księcia Trojdena 4, 02-109 Warsaw, Poland, ewa.lukowska@ibib.waw.pl
Bibliografia
  • [1] Nagese Y., Naruse A., Matsui K.: Chemical modification of polysulphone: 1. Synthesis of polysulphone/polydimethylsiloxane graft copolymer. Polymer. 1989, 30, 1931-1937.
  • [2] Nagese Y., Naruse A., Matsui K.: Chemical modification of polysulphone: 2. Gas and liquid permeability of polysulphone/polydimethylsiloxane graft copolymer membranes. Polymer. 1990, 31, 121-125.
  • [3] Sheldon J.: The fine-structure of ultrafiltration membranes. I. Clean membranes. J. Membrane Sci. 1991, 62, 75-86.
  • [4] Sheldon J. M., Reed I. M., Hawes C. R.: The fine-structure of ultrafiltration membranes. II. Protein fouled membranes. J. Membrane Sci. 1992, 74, 87-102.
  • [5] Summers G. J., Ndawuni M. P., Summers C. A.: Dipyridyl functionalized polysulfones for membrane production. J. Membrane Sci. 2003, 226, 21-33.
  • [6] Summers G. J., Ndawuni M. P., Summers C. A.: Chemical modification of polysulfone: anionic synthesis of dipyridyl functionalized polysulfone. Polymer. 2001, 42(2), 397-402.
  • [7] Chen S-H., Liou R-M., Hsu C-S., Chang D-J., Yu K-C., Chang C-Y.: Pervaporation separation water/ethanol mixture through lithiated polysulfone membrane. J. Membrane Sci. 2001, 193(1),59-67.
  • [8] Karlsson L. E., Jannasch P.: Polysulfone ionomers for proton-conducting fuel cell membranes 2. Sulfophenylated polysulfones and polyphenylsulfones. Electrochimica Acta. 2005, 50, 1939-1946.
  • [9] Cozan V., Avram E.: Side chain thermotropic liquid crystalline polysulfone obtained from polysulfone udel by chemical modification. European Polymer Journal. 2003, 39(1), 107-114.
  • [10] Arad-Yellin R., Firer M., Kahana N., Green B. S.: Functionalized polysulfone as a novel and useful carrier for immunization and antibody detection. Reactive and Functional Polymers 2003, 54(1-3), 5-16.
  • [11] Avram E., Brebu M. A., Warshawsky A., Vasile C.: Polymers with pendent functional groups. V. Thermooxidative and thermal behavior of chloromethylated polysulfones. Polymer Degradation and Stability. 2000, 69(2), 175-181.
  • [12] Möckel D., Staude E., Guiver M. D.: Static protein adsorption, ultrafiltration behavior and cleanability of hydrophilized polysulfone membranes. J. Membrane Sci. 1999, 158(1-2), 63-75.
  • [13] Genova-Dimitrova P., Baradie B., Foscallo D., Poinsignon C., Sanchez J. Y.: Ionomeric membranes for proton exchange membrane fuel cell (PEMFC): sulfonated polysulfone associated with phosphatoantimonic acid. J. Membrane Sci. 2001, 185(1), 59-71.
  • [14] Matsumoto Y., Sudoh M., Suzuki Y.: Preparation of composite UF membranes of sulfonated polysulfone coated on ceramics. J. Membrane Sci. 1999, 158(1-2), 55-62.
  • [15] Zschocke P., Quellmalz D.: Novel ion exchange membranes based on an aromatic polyethersulfone. J. Membrane Sci. 1985, 22, 325-332.
  • [16] Rucka M., Poźniak G., Turkiewicz B., Trochimczuk W.: Ultrafiltration membranes from polysulfone/aminated polysulfone blends with proteolytic activity. Enzyme and Microbial Technology 1996, 18(7), 477-481.
  • [17] Guan R., Zou H., Lu D., Gong C. I., Liu Y.: Polyethersulfone sulfonated by chlorosulfonic acid and its membrane characteristics. European Polymer Journal 2005, 41, 1554-1560.
  • [18] Poźniak G., Krajewska B., Trochimczuk W.: Urease immobilized on modified polysulfone membrane: preparation and properties. Biomaterials 1995, 16, 129-134.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPZ6-0002-0023
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