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Produkcja metanu z substratów bogatych w tłuszcze
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Waste materials containing a lot of fats seem to be an attractive substrate for production of methane through the fermentation process. Yet, due to a changing content of reagents and the high concentration of higher fatty acids, they must be stabilized along with other biodegradable wastes in the process of co-fermentation. This process results in a higher fermentation-grade and a greater volume of produced biogas. However, the methane fermentation of sewage sludges or sewage containing higher fatty acids may be problematical, and requires widespread studies in order to get a better understanding of this process.
Odpady zawierające wysoką zawartość tłuszczów wydają się najbardziej atrakcyjnym substratem do produkcji metanu w procesie fermentacji. Z uwagi na zmienny skład reagentów oraz znaczne stężenia wyższych kwasów tłuszczowych muszą być one stabilizowane z innymi biodegradowalnymi odpadami w procesie kofermentacji. W procesie kofermentacji dochodzi do rozcieńczenia substancji toksycznych oraz poprawy równowagi nutrientowej. Ponadto obserwuje się wyższy stopień przefermentowania osadów i większą produkcję biogazu. Podczas stabilizacji beztlenowej, tłuszcze w pierwszym etapie są hydrolizowane do wyższych kwasów tłuszczowych oraz glicerolu. W kolejnych fazach wyższe kwasy tłuszczowe oraz glicerol rozkładane są do kwasów lotnych, octanu i wodoru. Mimo, że hydroliza uważana jest za fazę limitującą jeden z etapów konwersji tłuszczy, niektórzy autorzy wskazują iż proces ten zależy od czasu zatrzymania osadu (SRT). Przy SRT poniżej 8 dni dochodzi do akumulacji wyższych kwasów tłuszczowych i inhibicji całego procesu fermentacji. Jednakże fermentacja metanowa osadów ściekowych lub ścieków zawierających tłuszcze na wysokim poziomie może być problematyczna. Główne problemy spowodowane przez tłuszcze podczas stabilizacji beztlenowej to pienienie, flotacja osadów, zapychanie się instalacji oraz nieprzyjemne odory. Tak więc kofermentacja odpadów z dużą zawartością tłuszczy może być problematyczna i wymaga dalszych badań mających na celu wyjaśnienie tego procesu.
Czasopismo
Rocznik
Tom
Strony
147--162
Opis fizyczny
Bibliogr. 58 poz., rys., tab.
Twórcy
autor
autor
autor
autor
- Czestochowa University of Technology, Faculty of Engineering and Environmental Protection, Institute of Environmental Engineering Brzeźnicka st. 60A, 42–200 Częstochowa, Poland, mworwag@is.pcz.czest.pl
Bibliografia
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Bibliografia
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bwmeta1.element.baztech-article-BPZ4-0021-0035