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Analysis of carbon diffusion during bainite transformation in ADI

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The paper presents an investigation of the time required for the diffusion of carbon out of supersaturated sub-units of ferrite into the retained austenite. The analytical model estimates the decarburisation time of the sub-units of supersaturated bainitic ferrite. The purpose of the present paper is to demonstrate how a thermodynamic method can be used for solving a problem of the decarburisation of bainite subunits and carbon diffusion distances in the matrix of ADI. This should in principle enable to examine the partitioning of carbon from supersaturated ferrite plates into adjacent austenite and the carbon content in retained austenite using analytical method. The diffusion coefficient of carbon in austenite is very sensitive to the carbon concentration and this has to be taken into account in treating the large concentration gradients that develop in the austenite. The results are discussed in the context of displacive mechanism of bainite transformation. Experimental measurements of volume fraction of bainitic ferrite and volume of the untransformed austenite indicate that there is a necessity of carbides precipitation from austenite. The necessary carbon diffusion distance in austenite also illustrates that the estimated time is not capable of decarburising the ferrite subunits during the period of austempering. A consequence of the precipitation of cementite from austenite during austempering is that the growth of bainitic ferrite can continue to larger extent and that the resulting microstructure is not an ausferrite but is a mixture of bainitic ferrite, retained austenite and carbides.
Rocznik
Strony
87--92
Opis fizyczny
Bibliogr. 19 poz., rys., tab.
Twórcy
autor
  • University of Technology and Life Sciences, Mechanical Engineering Faculty, al. Kaliskiego 7, 85-796 Bydgoszcz, Poland, lawry@utp.edu.pl
Bibliografia
  • [1] L.C. Chang, Carbon content of austenite in austempered ductile iron, Scripta Materialia, Vol.39, No 1, (1998) 35-38.
  • [2] S. Pietrowski, Nodular cast iron of bainitic ferrite structure with austenite or bainitic structure, Archives of Materials Science, vol. 18, No.4 (1997) 253-273. (in Polish).
  • [3] S.E. Guzik, Austempered cast iron as a modern constructional material, Inżynieria Materiałowa, nr 6 (2003) 677-680. (in Polish).
  • [4] H.K.D.H. Bhadeshia, D.V. Edmonds, Bainite in silicon steels: new composition-property approach, Metal Science Vol. 17 (1983) 420-425.
  • [5] O. Eric at al., The austempering study of alloyed ductile iron, Materials & Design, vol. 27 (2006) 617-622.
  • [6] Z. Ławrynowicz, S. Dymski, Mechanism of bainite transformation in ductile iron ADI, Archives of Foundry Engineering, PAN, Vol.6, No 19, (2006) 171-176. (in Polish).
  • [7] Z. Ławrynowicz, Transition from upper to lower bainite in Fe-C-Cr steel, Materials Science and Technology, Vol.20 (2004) 1447-1454.
  • [8] Z. Ławrynowicz, S. Dymski, Application of the mechanism of bainite transformation to modelling of processing window in ductile iron ADI, Archives of Foundry Engineering, PAN, Vol.6, No 19, (2006) 177-182. (in Polish).
  • [9] H.K.D.H. Bhadeshia, Bainite in Steels, Institute of Materials, London, 1-458, 1992.
  • [10] K.R. Kinsman, H.I. Aaronson, The transformation and hardenability in steels, Climax Molybdenum Company, Ann Arbor, MI, p.39, 1967.
  • [11] G.J. Shiflet, R.E. Hackenberg, Partitioning and the growth of bainite, Scripta Materialia, Vol.47 (2002) 163-167.
  • [12] A. Kutsov at al., Formation of bainite in ductile iron, Materials Sci. and Engineering A273-275 (1999) 480-484.
  • [13] H.K.D.H. Bhadeshia, J.W. Christian, Bainite in Steels, Metallurgical Transactions A, 21A (1990) 767-797.
  • [14] H.K.D.H. Bhadeshia, Diffusion of carbon in austenite, Metal Science, Vol.15 (1981) 477-479.
  • [15] R.H. Siller, R.B. McLelan, The Application of First Order Mixing Statistics to the Variation of the Diffusivity of Carbon in Austenite, Metallurgical Transactions Vol.1 (1970) 985-988.
  • [16] Z. Ławrynowicz, Criticism of selected methods for diffusivity estimation of carbon in austenite, Zeszyty Naukowe ATR nr 216, Mechanika 43, (1998) 283-287. (in Polish).
  • [17] Z. Ławrynowicz, Bainitic transformation: estimation of carbon diffusivity in austenite on the basis of measured austenite film thickness, Zeszyty Naukowe ATR nr 216, Mechanika 43, (1998) 289-297. (in Polish).
  • [18] Z. Ławrynowicz, A discussion on the mechanism of bainite transformation in steels, Technology and Materials, Gdańsk, Politechnika Gdańska, No 4, (2006) 149-155. (in Polish).
  • [19] Z. Ławrynowicz, Observation of interphase boundary: bainite-non-pearlitic eutectoid in Cr-Mo-C alloy by TEM, Technology and Materials, Gdańsk, Politechnika Gdańska, No 4, (2006) 156-160. (in Polish).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPZ3-0032-0018
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