The comparison of properties of terpoly(ester-b-ether-b-amide)s with aromatic/aliphatic and aliphatic ester blocks

• Autorzy: Kozłowska A. , Piątek M. , Ukielski R.
• Konferencja: Third International Conference on Engineering Rheology, ICER 2005
• Języki publikacji: EN

Abstrakty

EN

Two series of multiblock terpolymers, terpoly(ester-b-ether-b-amide) (TEEA) and terpoly(estersoft-b-ether-b-amide) (TEsEA), with the same type of oligoamide (oligolaurolactam (PA12)) hard block and oligoether (oligooxytetramethylene diol (PTMO) soft block were obtained. Oligo(butylene sebacate) was used as oligoester soft block in the first series and oligo(butylene terephthalate) hard block in the second one. The influence of changes in chemical composition of ester block on the structure and thermal and mechanical properties of the terpolymers have been determined by differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA) and other standard physical methods.

Słowa kluczowe

EN

terpoly(ester-b-ether-b-amides); multiblock terpolymers; phase structure; mutual solubility of soft and hard blocks

PL

materiałoznawstwo; struktura fazowa; terpolimery

• Wydawca: Oficyna Wydawnicza Uniwersytetu Zielonogórskiego
• Czasopismo: International Journal of Applied Mechanics and Engineering
• Rocznik: 2005
• Tom: Vol. 10, no spec
• Strony: 33--37
• Opis fizyczny: Bibliogr. 7 poz., tab., wykr.

Twórcy

autor

Kozłowska A.

• Polymer Institute, Szczecin University of Technology Pulaskiego 10, 70-322 Szczecin, POLAND

autor

Piątek M.

• Polymer Institute, Szczecin University of Technology Pulaskiego 10, 70-322 Szczecin, POLAND

autor

Ukielski R.

• Polymer Institute, Szczecin University of Technology Pulaskiego 10, 70-322 Szczecin, POLAND

Bibliografia

• [1] Bhowmick A.K. and Stephens H.L. (2001): Handbook of Elastomers - New York: Marcel Dekker Inc.
• [2] Folkes M.J. (1985): Processing, Structure and Properties of Błock Copolymers. - London: Elsevier.
• [3] Holden G. (1996): Thermoplastic Elastomers. In: Polymeric Materials Encyclopaedia (Salamone J.C., Ed.). - New York: CRC Press, vol.ll, pp.8343-8353.
• [4] Kozłowska A. and Ukielski R. (2004): New type of thermoplastic multiblock elastomers- poly(ester-block-amide)s- based on oligoamide 12 and oligoester prepared from dimerized fatty acid. - European Polymer Journal, vol.40, pp.2767-2772.
• [5]Ukielski R. (2000): New multiblock terpoly(ester-ether-amide)thermoplastic elastomers with various Chemical composition of ester błock. - Polymer, vol.41, pp.1893-1904.
• [6] Ukielski R. (1996): Synthesis of błock terpolymers ofthe poly(oxytetramethylene-block-(tetramethylene terephtalate)- block- laurolactam) type. - Polimery (Warsaw), vol. 41, pp.286-289.
• [7] Xie M. and Camberlin Y. (1986): Macromol. Chem. - vol.l87, No.383.