PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

The flow of viscoelastic fluids in an opposed jets rheometer and a Fano flow rheometer

Autorzy
Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Konferencja
Second International Conference on Engineering Rheology ICER 2003
Języki publikacji
EN
Abstrakty
EN
The elongational rheometer used for this work is an opposed jet rheometer, which allows elongational flow measurements of highly dilute polymer solutions. The polymer concentrations can be lower than the critical concentration under steady state conditions and lower than the critical concentration in the case of flow conditions. A further experimental set up was used for characterising the viscoelastic fluids. The working method of this apparatus is the tubeless siphon or Fano flow, which can be understood approximately as the reverse fibre spinning process. The beginning of the fibre spinning process can be applied in order to determine the critical concentration . The experimental investigations undertaken here were carried out using a commercial, anionic polyacrylamide with a relatively high molar mass and hydrolysis factor. The polyacrylamide was dissolved in highly pure water. Sodium chloride with different concentrations was added to the solutions to control the partial neutralisation of negative charges at the ends of the polymer chains.
Rocznik
Strony
319--324
Opis fizyczny
Bibliogr. 16 poz., rys., wykr.
Twórcy
autor
  • Angewandte Mechanik, Universität Essen Schützenbahn 70, 45127 Essen, GERMANY
autor
  • Angewandte Mechanik, Universität Essen Schützenbahn 70, 45127 Essen, GERMANY
Bibliografia
  • [1] Bird R., Amstrong R. and Hassager O. (1987): Dynamics of Polymer Liquids, Volume 1: Fluid Mechanics. - New York: John Wiley & Sons, 2nd Fd.
  • [2] Crooks R. and Boger D. (2000): Influence of fluid elasticity on drops impacting on dry surfaces. - Journal of Rheology, vol.44, No.4, pp.973-996.
  • [3] de Gennes P. (1974): Coil-stretch transition of dilute flexible polymers under ultrahigh velocity gradients. - Journal of Chemical Physics, vol.60, No. 12, pp.5030-5042.
  • [4] Eich T. (1999): Elastische Eigenschaften hochverdiinnter Polymerlosungen. - Dissertation, Universitat Essen, Angewandte Mechanik.
  • [5] Frank F., Mackley M. and Wills H. (1976): Localized flow birefringence of polyethylene oxide Solutions in a two roli mili - Journal of Polymer Science, vol.l4, pp.l 121-1131.
  • [6] Gampert B. and Wilkes C. (2002a): Rheo-optical measurements of the elongational flow of aqueous polymer Solutions. Rheologica Acta, vol.41, No.4, pp.326-331.
  • [7] Gampert B. and Wilkes C. (2002b): Experimentelle untersuchungen des konzentrationseinflusses von polyacrylamidlosungen aufdas dehnstromungsverhalten. - Chemie Ingenieur Technik, vol.74, pp.l273-1276.
  • [8] Gampert B., Wilkes C. and Eich T. (1999): The viscosity of extremely low concentrated anionie polyelectrolyte Solutions. - Applied Rheology, vol.9, No.4, pp.l58-164.
  • [9] Hermansky C. and Boger D. (1995): Opposing-jet viscometry of fluids with viscosity approaching that of water. - Journal Non-Newtonian Fluid Mechanics, vol.56, pp.l-14.
  • [10] Hinch E. (1977): Mechanical models of dilute polymer Solutions in strong flows. - Physics of Fluids, vol.20, No. 10, pp.22-30.
  • [11] Keller A. and Odell J. (1985): The extensibility of macromolecules in solution; a new focusfor macromolecular science. Colloid and Polymer Science, vol.263, No.3, pp.l81-201.
  • [12] Lee E. and Muller S. (1999): Flow light scattering of polymer coil conformation in Solutions in extensional flow. - Macromolecules, vol.32, pp.3295-3305.
  • [13] Macosko C. (1994): Rheology Principles, Measurements and Applications. - New York: VCH, lst Ed..
  • [14] MacSporran W. (1981): On the suspended syphon elongational rheometer. - Journal of Non-Newtonian Fluid Mechanics, vol.8, pp.l 19-138.
  • [15] Rando M., Socias P., Muller A., Smitter L. and Saez A. (2000): The flow of mixture of poly(ethylene oxide) and hydrolyzed polyacrylamide Solutions through opposed jets. - Journal of Applied Polymer Science, vol.76, pp.1910-1919.
  • [16] Secor R., Schunk P., Hunter T., Stitt T., Macosko C. and Scriven L. (1989): Experimental uncertainties in extensional rheometry of liquids by fiber drawing. - Journal of Rheology, vol.33, No.8, pp.1329-1358.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPZ2-0005-0061
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.