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The effect of concentration of aqueous solutions of ethoxylated sorbitan esters on antiseizure properties

Wybrane pełne teksty z tego czasopisma
Identyfikatory
Warianty tytułu
Konferencja
Second International Tribology Conference
Języki publikacji
EN
Abstrakty
EN
Influence of compound's type and concentration of ethoxylated sorbitan ester (ESE) water solutions on their anti-seizure properties was investigated. Ethoxylated sorbitan monolaurate (ESML), ethoxylated sorbitan monostearate (ESMS) and ethoxylated sorbitan monooleate (ESMO) were used as lubricant additives. Tribological tests were performed on the four-ball machine, at linearly increasing load (409N/s) (tribosystem: steel-steel). Basing on the scuffing load (the load at the moment of rapid increment of friction torque) anti-seizure properties of the solutions were assessed. The other measured parameter was the seizure load, that is load at the moment when friction torque exceeded 10Nm. The limiting pressure of seizure was evaluated according to the formula: poz=0,52*Poz/d2 where Poz - seizure load, d - wear scar diameter. According to the results obtained one can say that addition of ESE to water significantly improves its anti-seizure properties. The measured tribological quantities strongly depend on concentration. 0.001%; 0.005%; 0.01%; 0.05%; 0.1%; 0.5% and 1% aqueous solutions were tested. The best anti-seizure properties were observed for ethoxylated sorbitan monostearate and monooleate. The results obtained can be interpreted as a consequence of a formed liquid crystalline structure near the surface. The presence of mesophases in water solutions of ethoxylated sorbitan esters was confirmed by observations in polarized light and characteristic changes of the viscosity.
Rocznik
Strony
189--195
Opis fizyczny
Bibliogr. 20 poz., rys., wykr.
Twórcy
autor
  • Technical University of Radom, 26-600 Radom, ul. Chrobrego 27, POLAND
  • Technical University of Radom, 26-600 Radom, ul. Chrobrego 27, POLAND
Bibliografia
  • [1] Bermudez M.D., Martinez-Nicolas G. and Carrion-Vilches F.J. (1997): Tribological properties of liquid crystals as lubricant additives – Wear, vol. 212, pp. 188-194.
  • [2] Biresaw G. and Zadnik D.A. (1990): Temperature effect on the tribological properties of thermotropic liquid crystals. - Tribology and the Liquid Crystalline State, American Chemical Society, Washington, DC, pp.83-90.
  • [3] Boschkova K., Elvesjo J. and Kronberg B. (2000): Frictional properties of lyotropic liquid crystalline mesophases at surface. - Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 166, pp.67-77.
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  • [5] Fischer T.E., Bhattacharya S., Sahler R., Lauer J.L. and Ahn Y.J. (1988): Lubrication by a smectic liquid crystal. - Tribology Transactions, vol.31, pp.442-448.
  • [6] Friberg S., Ward A., Gunsel S. and Lockwood F. (1990): Lyotropic liquid crystals in lubrications. - Tribology and the Liquid Crystalline State, American Chemical Society, Washington, DC, pp. 101-112.
  • [7] Kimura Y., Nakano K., Kato T. and Morishita S. (1994): Control of friction coefficient by applying electric fields across liquid crystal boundary films. - Wear, vol.175, pp.143-149.
  • [8] Kumar K. and Shah D.O. (1990): Effect of liquid-crystalline structures on lubrication of aluminium surfaces. - Tribology and the Liquid Crystalline State, American Chemical Society, Washington, DC, pp.91-100.
  • [9] KUpchinov B.I., Rodnenkov V.G., Ermakov S.F. and Parkalov V.P. (1991): A study of lubrication by liquid crystals. - Tribology International, vol.24, pp.25-28.
  • [10] Kupchinov B.I., Ermakov S.F., Rodnenkov V.G,Bobrysheva S.N. and Bolenko E,D. (1994): The effect of liquid crystals on join lubrication. - Wear, vol.171, pp.7-12.
  • [11] Mori S, and Iwata H. (1996): Relationship between tribological performance of liquid crystals and their molecular structure. - Tribology International, vol.29, pp.35-39.
  • [12] Morishita S., Nakano K. and Kimura Y. (1993): Electroviscous effect of nematic liquid crystals. - tribology International, vol.26, pp.399-403.
  • [13] Pikoszewski W., Szczerek M. and Tuszyński W. (2001): The action of lubricants under extreme pressure conditions in a modified four-ball tester. - Wear, vol.249, pp.188-193.
  • [14] Lockwood F.E., Benchaita M.T. and Friberg S.E. (1987): Study of lyotropic liquid crystals in viscometric flow and elastohydrodynamic contact. - ASLE Transactions, vol.30, pp.539-548.
  • [15] Sułek M.W. and Wasilewski T. (2001a): Role of smectic and nematic liquid crystals in lubrication. – Inżynieria Powierzchni, vol.4, pp.42-51(in Polish).
  • [16] Sułek M. W. and Wasilewski T. (2001b): Application of cholesteric liquid crystals as lubricant additives. - Tribologia, vol.4, No. 178, pp.797-819 (in Polish).
  • [17] Sułek M.W. and Wasilewski T. (2001c): The effect of temperature on tribological properties of liquid crystals applied as lubricant additives. - Tribologia, vol.5, No.179, pp.905-919 (in Polish).
  • [18] Sułek M.W. and Wasilewski T. (2001d): Influence of alkyl polyglycosides on lubricating properties of rand glycerin. - Inżynieria Powierzchni, vol.4, pp.52-58 (in Polish).
  • [19] Sułek M.W. and Wasilewski T. (2002): Influence of the structure of ethoxylated sodium lauryl sulfate water solutions on their tribological properties. - Zagadnienia Eksploatacji Maszyn, vol.l, No.129, pp. 35-47 (in Polish).
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPZ2-0002-0027
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