Ocena procesów biologicznego usuwania azotanów (V) i fosforanów w komorze SBR z zewnętrznym źródłem węgla

• Autorzy: Janczukowicz W. , Rodziewicz J. , Filipkowska U.

Warianty tytułu

EN

Evaluation of process of biological nitrate and phosphate removal in SBR type reactor with external carbon source

• Języki publikacji: PL

Abstrakty

PL

Celem pracy jest określenie wpływu lotnych kwasów tłuszczowych na szybkość uwalniania i wiązania fosforanów w reaktorze SBR oczyszczającym ścieki charakteryzujące się porównywalnymi stężeniami fosforanów i azotanów (V). Celem pracy jest także ustalenie, czy na przebieg i sprawność procesów defosfatacji i denitryfikacji ma wpływ obecność w biomasie osadu czynnego mikroorganizmów zaadaptowanych wcześniej do określonych źródeł węgla. Zakres pracy obejmował określenie: szybkości uwalniania i wiązania fosforanów w obecności kwasów octowego, propionowego, masłowego, walerianowego, izowalerianowego i kapronowego, wpływu rodzaju kwasu na efektywność usuwania fosforanów szybkości procesu denitryfikacji w fazie mieszania i napowietrzania oraz sprawności procesu denitryfikacji w zależności o rodzaju kwasu z grupy LKT.

EN

Determinations were made for the effect of volatile fatty acids (VFA) on the rate of release and absorption of phosphates and on the rate of nitrates removal in the stirring and aeration phases in an SBR type reactor. The effectiveness of phosphates and nitrates removal, influenced by the fatty acid applied, was determined as well. The experiment was conducted in SBR type reactors in one working cycle (stirring - 3 h, aeration - 4 h and sedimentation - 1 h) in the presence of acetic, propionic, butyric, isobutyric, valeric, isovaleric and caproic acids. The initial concentrations of phosphates and nitrates were: 13.4 mg PPO4?dm-3 and 15.2 mg NNO3?dm-3, respectively. The study demonstrated that phosphates were released with the highest rate in the reactors containing acetic acid (3.35 mg PPO4?dm-3?h-1), whereas with the lowest rate - in these containing butyric acid (1.25 mg PPO4?dm-3?h-1). Also the process of phosphates absorption proceeded with the highest rate in the reactor with acetic acid (4.19 mg PPO4?dm-3?h-1), and with the lowest rate - in the presence of isobutyric acid (2.13 mg PPO4?dm-3?h-1). In the case of acetic acid, the highest rates of both processes corresponded with the most effective dephosphatation process (50.0%). Such an explicit dependency was not, however, noted in the case of other fatty acids. In the stirring phase, the denitrification process proceeded with the highest rate (3.95 mg NNO3?dm-3?h-1) in the reactor containing caproic acid, and with the lowest rate - in the presence of isobutyric acid (3.42 mg NNO3?dm-3? h-1). During aeration, the rate of nitrates concentration decrease was the highest in the presence of butyric acid (0.91 mg NNO3?dm-3?h-1) and the lowest - in the presence of caproic acid (0.52 mg NNO3?dm-3?h-1). The highest rates of denitrification recorded in both phases in the reactor with caproic acid were not tantamount to the highest effectiveness of nitrates removal. It was the acetic acid that turned out to be the most effective source of carbon in the denitrification process (92.6%) The highest efficiency of both examined processes was observed in the presence of acetic acid. Negligibly lower efficiencies were noted in the reactor with butyric acid. In view of the fact that propionic acid was only slightly less effective both in the denitrification as well as dephosphatation process, it may be speculated that the presence of microorganisms, adapted earlier to specified carbon sources, in the biomass of activated sludge is likely to affect the course and effectiveness of both processes in reactors with an external source of carbon.

Słowa kluczowe

PL

azotany; fosforany; węgiel; lotne kwasy tłuszczowe

EN

nitrates; phosphates; coal; volatile fatty acids

• Wydawca: Politechnika Koszalińska
• Czasopismo: Rocznik Ochrona Środowiska
• Rocznik: 2011
• Tom: Tom 13
• Strony: 453--468
• Opis fizyczny: Bibliogr. 19 poz.

Twórcy

autor

Janczukowicz W.

autor

Rodziewicz J.

autor

Filipkowska U.

• Uniwersytet Warmińsko-Mazurski, Olsztyn

Bibliografia

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