Transport cząstek koloidalnych z zaadsorbowanymi jonami arsenu przez mineralne złoże porowate

• Autorzy: Wróbel I. , Polowczyk I. , Sadowski Z.

Warianty tytułu

EN

Transport of colloidal particles with arsenic ions adsorbed on the colloidal surfaces through mineral porous bed

• Języki publikacji: PL

Abstrakty

PL

Obecność odpadów przemysłowych w środowisku naturalnym staje się coraz bardziej zauważalnym problemem w ochronie środowiska. Za główne źródło ich powstawania, uważa się przemysł wydobywczy i przetwórstwa kopalin. W wyniku prowadzenia procesów wzbogacania, bądź procesów hutniczych, powstają odpady deponowane na hałdach, które w znaczący sposób przyczyniają się do zanieczyszczeń wód gruntowych. Dzieje się tak w wyniku transportu trudno rozpuszczalnych zanieczyszczeń przez naturalny polimineralny ośrodek porowaty. Zjawisko to zostało zaliczone do głównych procesów mających istotny wpływ na zanieczyszczanie wód gruntowych.

EN

The storage of insecure industrial waste, descended from mining and metallurgical industry, has an influence on the pollution of a ground and groundwater. It is a result of migration of toxic substances into the bed of soli. The weathering processes and hydrodynamic changes in soil causes the colloidal particles formation, which are effective contaminations carriers through mineral porous media. In this paper transport of colloidal particles: synthetic hematite and natural kaolin has been investigated. The porous medias were waste from both Szklary and Złoty Stok heaps. The aim of this work is to inspect the influence of arsenate ions on the behaviour of colloidal particles in porous bed. The investigations were conducted in two ionic strengths: 5ź10-3 M KCl and 5ź10-4 M KCl, at pH 9.2-11.6. Results showed that transport of colloidal hematite was facilitated, when arsenic ions were adsorbed onto the colloid particles. Additionally, the increase of mobility of hematite was caused by a decrease of ionic strength. In the case of kaolin transport, the results showed an increase of kaolin particles migration without arsenic ions. These behaviour of colloidal kaolin particles into mineral bed isexplained by different surface property of kaolin particles. Results of examinations on colloidal particles of hematite and kaolin transport through column with mineral bed show, that examined mobility is conditioned with physico-chemical proprieties of colloidal particles and materials of porous bed. Studied colloids, can influence pollution of underground waters in the areas of storing of studied industrial wastes. Results of conducted measurements show, that the process of examined colloidal particles transport is influenced by presence of adsorbed arsenic ions. It is the most perceptible phenomenon in the case of the colloidal hematite, particularly for porous medium built from materials taken from the southern side of heap in Szklary and heap in Złot Stok. Additionally, influence of ion strength on quantity of transported colloidal particles through the layer of porous mineral medium was observed. When ion strength was decreasing, the thickness of the double electric layer increases on colloidal particles. It has impact on decrease of attracting interactions among particles of colloid, and also between colloidal particle and grain of mineral bed. The opposite case was noted during investigations on transportation of colloidal particles of kaolin. Adsorption of arsenic ions by particles of kaolin causes decrease of their mobility. This causes stopping of migration of arsenic ions to underground waters. The similar result is obtained when ion strength is enlarged.

Słowa kluczowe

PL

jony arsenu; złoża mineralne; cząstki koloidalne

EN

colloidal particles; arsenic ions; minerals

• Wydawca: Politechnika Koszalińska
• Czasopismo: Rocznik Ochrona Środowiska
• Rocznik: 2009
• Tom: Tom 11
• Strony: 1119--1130
• Opis fizyczny: bibliogr. 17 poz.

Twórcy

autor

Wróbel I.

autor

Polowczyk I.

autor

Sadowski Z.

• Politechnika Wrocławska

Bibliografia

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