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In the case of electrically conducting layers prepared on a glass substrate, sodium diffuses into the SnO2 film and deteriorates their electric properties. Sodium barrier diffusion properties of thin layers based on SiO2, and SiO2 modified by various contents of Al2O3, TiO2, ZrO2, CeO2, prepared by sol-gel, have been the subject of this study. Morphology and optical properties of the coatings have been analyzed. XPS technique has been used to evaluate the barrier properties of prepared coatings by measuring sodium 1s peak changes after thermal treatment of the coating. The best properties have been obtained for the coating based on SiO2-Al2O3 system and containing 0.08 mol of Al. It has been found that blocking properties of the coating are mainly connected with its microstructure. The role of added modifiers lies in changing the microstructure of formed gel.
Czasopismo
Rocznik
Tom
Strony
171--179
Opis fizyczny
Bibliogr. 13 poz.
Twórcy
autor
autor
autor
- AGH University of Science and Technology, Faculty of Materials Science and Ceramics, al. Mickiewicza 30, 30-059 Kraków, Poland
Bibliografia
- [1] BACH K., Thin Films on Glass, Springer, Berlin 1997.
- [2] ŻELAZOWSKA E.D., Powłoki refleksyjne na szkle otrzymywane przez pyrolizę acetyloacetonianów metali, Ph.D. Thesis, AGH – University of Science and Technology, Kraków 1994 (in Polish).
- [3] FUJITA Y., MIYAZAKI K., TATSUYAMA C., On the electrochromism of evaporated V2O5 films, Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes 24(8), 1985, pp. 1082–6.
- [4] DENEUVILLE A., GENARD P., BILLAT R., Principles and operation of an all solid state electrochromic display based on a-‘WO3’, Thin Solid Films 70(2), 1980, pp. 203–23.
- [5] ANDRUKAITIS E., JACOBS P.W.M., LORIMER J.W., Vanadium pentoxide electrodes. I. Formation of vanadium pentoxide from anodic electrodeposits, Solid State Ionics, Diffusion and Reactions 27(1–2), 1988, pp. 19–30.
- [6] NABAVI M., DOEUFF S., SANCHEZ C., LIVAGE J., Sol–gel synthesis of electrochromic films, Materiale Science and Engineering B 3(1–2), 1989, pp. 203–7.
- [7] MIZUHASHI M., Electrical properties of SnO2 films on various glass substrates, Journal of Non-Crystalline Solids 38–39, 1980, pp. 329–34.
- [8] FU GUANGHUI, DU JIAFENG, PAN DONGHUI, HE OULI, The migration of alkali ions from glass substratem coated with sol–gel barrier films, Journal of Non-Crystalline Solids 112(1–3), 1989, pp. 4547.
- [9] SARAIE J., ONO K., TAKEUCHI S., Effects of various atmospheres on the reduced-pressure CVD of Al2O3 thin films at low temperatures, Journal of the Electrochemical Society 136(10), 1989, pp. 3139–41.
- [10] SAWADA Y., TAGA Y., Application of indium tin oxide films to improved transparent IR shielding, Thin Solid Films 126(1–2), 1985, pp. 69–72.
- [11] NOCUŃ M., Characterisation of the tin oxide conducting film obtained by ultrasonic spray pyrolysis, Optica Applicata 33(1), 2003, pp. 183–90.
- [12] BRIGGS D., SEAH M.P. [Eds], Practical Surface Analysis, Vol. 1, 1990.
- [13] MANIFACIER J.C., GASIOT J., FILLARD J.P., A simple method for the determination of the optical constants n, k and the thickness of a weakly absorbing thin film, Journal of Physics E: Scientific Instruments 9(11), 1976, pp. 1002–4.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW9-0006-0042