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Sol-gel materials may found plenty of applications, e.g., as carriers for various substances, which can be exploited for sensing purposes or as drug releasing carriers. In this work, the fluorescence properties of two photosensitizers immobilized in silica based sol-gel materials were examined. The sol-gel materials were produced from silica precursor TEOS and 96% ethyl alcohol as solvent. Materials with various ratios R (solvent to precursor molar ratio) 5, 15, 20, 32, 40, and 50, were prepared. Photolon and protoporphyrine PPIX were used as dopants in concentrations 0.001%, 0.005%, 0.01% and 0.05%. The excitation wavelength from a blue laser was 415 nm. The highest luminescence was observed for the material prepared with R = 20, whereas for R = 5 it was the lowest one. The fluorescence quenching for highest photosensitizer concentration was observed, as well.
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Tom
Strony
49--56
Opis fizyczny
Bibliogr. 12 poz.
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autor
autor
autor
autor
autor
autor
- Bio-Optics Group, Institute of Biomedical Engineering and Instrumentation, Wrocław University of Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
Bibliografia
- [1] GARCÍA SÁNCHEZ M.A., TELLO S S.R., SOSA F R., CAMPERO A., Fluorescent porphyrins trapped in monolithic SiO2 gels, Journal of Sol–Gel Science and Technology 37(2), 2006, pp. 93–7.
- [2] SANTOS S.F., SANTOS M.L., ALMEIDA L.E., JR. COSTA N.B., GIMENEZ I.F., ARAKI K., MAYER I., ENGELMANN F.M., TOMA H.E., BARRETO L.S., Fluorescent tetraruthenated porphyrins embedded in monolithic SiO2 gels by the sol–gel process, Journal of Colloid and Interface Science 305(2), 2007, pp. 264 –9.
- [3] DE LA LUZ V., GARCIA-SANCHEZ M.A., CAMPERO A., Luminescent porphyrinosilica obtained by the sol–gel metod, Journal of Non-Crystalline Solids 353(22–23), 2007, pp. 2143–9.
- [4] DELMARRE D., MEALLET R., BIED-CHARRETON C., PANSU R.B., Heavy metal ions detection in solution, in sol–gel and with grafted porphyrin monolayers, Journal of Photochemistry and Photobiology A: Chemistry 124(1–2), 1999, pp. 23–8.
- [5] PURRELLO R., GURRIERI S., LAUCERI R., Porphyrin assemblies as chemical sensors, Coordination Chemistry Reviews 190–192, 1999, pp. 683–706.
- [6] DARGIEWICZ-NOWICKA, RADZKI S., Porphyrins as chemical and biochemical optical sensors, Acta Bio-Optica et Informatica Medica 8, 2002, pp. 119–31 (in Polish).
- [7] DARGIEWICZ J., MAKARSKA M., RADZKI S., Spectroscopic characterization of water-soluble cationic porphyrins in sol–gel silica matrices and coatings, Colloids and Surfaces A: Physicochemical and Engineering Aspects 208(1–3), 2002, pp. 159–65.
- [8] DARGIEWICZ-NOWICKA J., MAKARSKA M., VILLEGAS M.A., LEGENDZIEWICZ J., RADZKI S., Photophysics of the porphyrins; unusual fluorescence of europium porphyrin complex entrapped in sol–gel silica matrix, Journal of Alloys and Compounds 380(1–2), 2004, pp. 380–8.
- [9] PODBIELSKA H., ULATOWSKA-JARŻA A., MÜLLER G. HOLOWACZ I., BAUER J., BINDIG U., Silica sol–gel matrix doped with Photolon molecules for sensing and medical therapy purposes, Biomolecular Engineering 24(5), 2007, pp. 425–33, doi: 10.1016/j.bioeng.2007.07.005.
- [10] ULATOWSKA-JARŻA A., ZYCHOWICZ J., HOŁOWACZ I., BAUER J., RAZIK J., WIELICZKO A., PODBIELSKA H., MÜLLER G., STRĘK W., BINDIG U., Antimicrobial PDT with chlorophyll-derived photosensitizer and semiconductor laser, Medical Laser Application 21(3), 2006, pp. 177–83.
- [11] GRENOBLE S., GOUTERMAN M., KHALIL G., CALLIS J., DALTON L., Pressure-sensitive paint (PSP): concentration quenching of platinum and magnesium porphyrin dyes in polymeric films, Journal of Luminescence 113(1–2), 2005, pp. 33–44.
- [12] ULATOWSKA-JARŻA A., BINDIG U., PODBIELSKA H., HOŁOWACZ I., STRĘK W., MÜLLER G., EICHLER H.J., Spectroscopic properties of chlorophyll-based photosensitive dye entrapped in sol–gel fiber-optic applicators, Materials Science (Poland) 23(1), 2005, pp. 111–22.
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BPW9-0006-0028