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Morphology of porous glasses. Colloid-chemical aspect

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EN
Abstrakty
EN
A summarizing of the results of complex study of pore morphology of porous glasses has been carried out taking into consideration the dissolved secondary silica state in the systems alkali borosilicate glass - a leaching solution. An influence of the composition and phase structure of an initial glass, and their leaching conditions, on the colloid-chemical characteristics of the porous glasses has been shown. The polymodal micro porous substructure and meso porous one, the size and a form of the pores and secondary silica particles as well as the fractal dimensions of their aggregates, the coefficients of structural resistance and tortuosity of the pores has been discussed.
Czasopismo
Rocznik
Strony
5--16
Opis fizyczny
Bibliogr. 29 poz.
Twórcy
autor
  • Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 24/2 Odoevskii Str., St. Petersburg, 199155, Russia
Bibliografia
  • [1] YAO S., SANTIAGO J.G., Porous glass electroosmotic pumps: theory, Journal of Colloid and Interface Science 268(1), 2003, pp. 133–42.
  • [2] YAO S., HERTZOG D.E., ZENG S., MIKKELSEN J.C., SANTIAGO J.G., Porous glass electroosmotic pumps: design and experiments, Journal of Colloid and Interface Science 268(1), 2003, pp. 143–53.
  • [3] EVSTRAPOV A.A., ESIKOVA N.A., ANTROPOVA T.V., Spectral characteristics and structure of porous glasses, Optica Applicata 35(4), 2005, pp. 753–9.
  • [4] ERMAKOVA L., SIDOROVA M., ANTROPOVA T., JURA N., LURIE S., Porous glass membranes as model disperse systems, Colloids and Surfaces A: Physicochemical and Engineering Aspects 282–283,2006, pp. 279–86.
  • [5] ZHDANOV S.P., Wissenschaftliche Zeitschrift der Friedrich-Schiller-Universitaet Jena, Vol. 36, 1987, p. 81.
  • [6] ANTROPOVA T.V., Physicochemical processes of creation of the porous glasses and high-silica materials based on the phase-separated alkali borosilicate systems, D.Sc. Thesis (Chem.), Saint Petersburg 2005, p. 588 (in Russian).
  • [7] TANAKA H., YAZAWA T., EGUCHI K., NAGASAWA H., MATSUDA H., EINISHI T., Precipitation of colloidal silica and pore size distribution in high silica porous glass, Journal of Non-Crystalline Solids 65(2–3), 1984, pp. 301–9.
  • [8] TANAKA K., Journal of the Ceramic Society of Japan 85(12), 1977, p. 587.
  • [9] VENZEL B.I., SVATOVSKAYA L.G., Fizika i Khimiya Stekla 14(6), 1988, p. 920 (in Russian).
  • [10] TSEKHOMSKAYA T.S., ANFIMOVA I.N., Soviet Journal of Glass Physics and Chemistry 18(2), 1992, p. 161.
  • [11] TSYGANOVA T.A., ANTROPOVA T.V., RAKHIMOVA O.V, DROZDOVA I.A., Features of leaching of phase separated alkali borosilicate glasses in acid salt solutions, Glass Technology 43C, 2002, p. 343.
  • [12] GREGG S.J., SING K.S.W., Adsorption, Surface area and Porosity, Academic, London 1967.
  • [13] KREISBERG V.A., RAKCHEEV V.P., ANTROPOVA T.V., Microporosity of porous glasses: New investigation techniques, Glass Physics and Chemistry 29(6), 2003, pp. 541–7.
  • [14] KREISBERG V.A., RAKCHEEV V.P., ANTROPOVA T.V., Microporous substructure of porous glasses: Dynamic and equilibrium approaches, Journal of Porous Materials 12(1), 2005, pp. 13–22.
  • [15] KREISBERG V.A., RAKCHEEV V.P., ANTROPOVA T.V., Influence of the acid concentration on the morphology of micropores and mesopores in porous glasses, Glass Physics and Chemistry 32(6), 2006, pp. 615–22.
  • [16] ANTROPOVA T.V., DROZDOVA I.A., Glass Physics and Chemistry 21(2), (1995), p. 131.
  • [17] DROZDOVA I., VASILEVSKAYA T., ANTROPOVA T., Structural transformation of secondary silica inside the porous glasses according to electron microscopy and small-angle X-ray scattering, European Journal of Glass Science and Technology Part B: Physics and Chemistry of Glasses 48(3), 2007, pp. 142–6.
  • [18] TSYGANOVA T.A., ANTROPOVA T.V., RAKHIMOVA O.V., Book of Abstracts ECS Topical Meeting “StructChem2006”, Saint-Petersburg, Russia 2006, p. 88.
  • [19] ANTROPOVA T.V., ANFIMOVA I.N., TSYGANOVA T.A., [In] Proceeding of the XXIst Intern. Congress on Glass, Extended Abstracts (CD-ROM), Strasbourg, France, 2007, Z7.
  • [20] ANTROPOVA T.V., DROZDOVA I.A., YASTREBOV S.G., EVSTRAPOV A.A., Porous glass: inhomogeneities and light transmission, Optica Applicata 30(4), 2000, pp. 553–68.
  • [21] ILER R.K., The Chemistry of Silica, Wiley, New York 1979.
  • [22] TSYGANOVA T.A., ANTROPOVA T.V., RAKHIMOVA O.V., KOSTYREVA T.G., Specific features of the formation of a porous structure in products of leaching of two-phase sodium borosilicate glasses in acid-salt solutions, Glass Physics and Chemistry 33(2), 2007, pp. 122–9.
  • [23] ANTROPOVA T.V., ERMAKOVA L.E., MEDVEDEVA S.V., SIDOROVA M.P., Glastechnische Berichte – Glass Science and Technology 77C, 2004, p. 193.
  • [24] MEDVEDEVA S.V., Production and electrosuperficial characteristics of the porous glass membranes of various compositions in the solutions of 1:1 – charge electrolytes, Ph.D. Thesis (Chem.), Saint Petersburg, 2004, p. 308 (in Russian).
  • [25] EXNAR P., Macroporous glass with P2O5 and fruorides content, [In] Proceeding of the 5th Conference of the European Society of Glass Science and Technology, Book of Abstracts, Czech Glass Society, Prague 1999, p. 184.
  • [26] KIPRIANOV A.A., KARPUKHINA N.G., Influence of fluoride additives on the electrical characteristics of alkali silicate electrode glasses, Glass Physics and Chemistry 27(1), 2001, pp. 74–9.
  • [27] ERMAKOVA L.E., MEDVEDEVA S.V., VOLKOVA A.V., SIDOROVA M.P., ANTROPOVA T.V., Structure and electrosurface properties of porous glasses with different compositions in KCl and NaCl solutions, Colloid Journal 67(3), 2005, pp. 304–12.
  • [28] JULIAN R., Comments on Modern Physics, Part B 13, 1987, p. 177.
  • [29] ZARZYCKI J., Structural aspects of sol-gel synthesis, Journal of Non-Crystalline Solids 121(1–3), 1990, pp. 110–8.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW9-0006-0023
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