Kompleksy metali z jonami chinolino-2-karboksylanowym i 9,10-dihydro-9-okso-10-akrydynooctanowym - badania strukturalne, spektroskopowe i magnetyczne.

• Autorzy: Dobrzyńska D.

Warianty tytułu

EN

Structural, spectroscopic and magnetic studies of the metal complexes with quinoline-2-carboxylate and 9,10-dihydro-9-oxo-10-acridineacetate ions.

• Języki publikacji: PL

Abstrakty

PL

W pracy przedstawiono wyniki badań strukturalnych, spektroskopowych i magnetycznych dwóch grup kompleksów metali: pierwsza grupa zawiera związki z jonem chinolino-2-karboksylanowym, a druga zawiera związki z jonem 9,10-dihydro-9-okso-10-akrydynooctanowym. Otrzymano 21 nowych związków, a dla 16 przeprowadzono analizę rentgenostrukturalną. Kompleksy scharakteryzowano metodami spektroskopii oscylacyjnej, spektroskopii elektronowej, spektroskopii elektronowego rezonansu paramagnetycznego, spektroskopii Mossbauera oraz zbadano ich właściwości magnetyczne. Kompleksy z pierwszej grupy są monomerami i we wszystkich przypadkach jon chinolino-2-karboksylanowy jest ligandem chelatujacym, a grupa karboksylanowa koordynuje w formie monodentnej. W kryształach tych związków obserwuje się różnorodne struktury supramolekularne, których budowa zależy od geometrii sfery koordynacyjnej w kompleksie, rodzaju wspólliganda i związków współ-krystalizujących. Wyjątkowo efektywna kooperacja pomiędzy oddziaływaniami międzycząsteczkowymi (wiązania wodorowe, oddziaływania typu pi-pi i C-H-pi) występuje w kryształach kompleksów [Mn(quin-2-c)2(H20)2]. 2Ade i [Mn(quin-2-c)2(H20)2] 4CH3COOH. Oddziaływania międzyczą-steczkowe istotnie wpływają na charakterystykę oscylacyjną monodentnej grupy karboksyla-nowej, a także umożliwiają słabą wymianę magnetyczną między centrami paramagnetycznymi. W drugiej grupie związków ligand 9,10-dihydro-9-okso-10-akrydynooctanowy łączy się z jonami metali w różnorodny sposób, grupa karboksylanowa koordynuje jako monodentna, chelatująca lub mostkowa, otrzymane związki są monomerami lub polimerami. W kryształach tych związków występują struktury supramolekularne z dużym udziałem oddziaływań stackingowych i wiązań wodorowych. Analiza budowy kryształów obu grup związków dowodzi, że słabe oddziaływania typu pi-pi i C-H--pi-odgrywają ważna rolę w procesach samoskupiania związków koordynacyjnych.

EN

A large group of metal coordination compounds containing quinoline-2-carboxylate (quin-2-c") and 9,10-dihydro-9-oxo-10-acridineacetate (CMA~) ions was studied. Ancilliary ligands such as water, alcohols, imidazole and chloride ions have been incorporated in these complexes. Quinoline-2-carboxylic acid and 9,10-dihydro-9-oxo-10-acridineacetatic acid exhibit biological activity. The first compound is the tryptophan metabolite, whereas the second one is the powerful interferon inducer. Fifteen new complexes with quinoline-2-carboxylate ion and six new complexes with 9,10-dihydro-9-oxo- 10-acridineacetate ion were obtained and characterized by analytical, spectrosopic and magnetic methods. Sixteen compounds were obtained in the form suitable for single crystal X-ray analysis. The first group of complexes are molecular compounds in which the quin-2-c" ligand chelates the metal ions by the quinoline nitrogen atom and the oxygen atom from monodentate carboxylate group. The coordination sphere of the metal ions in these compounds mimics the structure of the metal centers in the corresponding mononuclear iron and manganese enzymes in regard to the coordination number, donor groups, geometry and the spin state. In the second group of complexes, the monomers, polymers and cluster were found. The CMA~ ion coordinates metal ions through the oxygen atoms from the carboxylate group in the various modes: monodentate, chelating or bridging. In the crystals of all compounds studied, the ID, 2D or 3D supramolecular structures generated by in-termolecular interactions of 0-H-O, N-H-O, N-H--N, C-H-O, C-Hxx and tv-k type have been found. The results of the structural analysis show that the coordination compound containing the groups essential for hydrogen bond's formation, located close to the coordination sphere, are efficient substrates in the selfassembly processes. The architecture of the crystals greatly depenas on the strong hydrogen bond systems, however the weak interactions between aromatic rings also play important role in the compounds studied. Very effective cooperation of various intermolecular interactions is found in the crystals of [Mn(quin-2-c)2(H20)2]-2Ade and [Mn(quin-2-c)2(H20)2]-4CH3COOH. The adenine ribbons of unique type have been found in the crystal of the first compound. Adenine molecules are connected by simuta-neas Watson-Crick and Hoogsteen hydrogen bonds. The second compound is a very interesting example of tetrasolvate which becomes amorphous when it looses the solvent and rebuilds the crystal structure after resolvation. This compound can be used as a safe and efficient store of acetic acid. The results of the spectroscopic and magnetic studies on the complexes with quin-2-c" and CMA" ions are presented. The magnetic properties of the compounds containing the Fe(II) high-spin ions testify the weak magnetic exchange taking place by the systems of strong hydrogen bonds. The EPR and UV-Vis spectroscopic data support the results of the X-ray studies. The detailed magnetic and spectroscopic investigations of [Ni(CMA)2(Him)2(MeOH)2] (UV-Vis, HFHFEPR and magnetic measurements) combined with the structural information provide reliable experimental data for determination of the electronic structure of nickel center in the bacterial enzyme Glioxalase I. The studies of the IR spectra have shown that the vibrational frequencies of the monodentate carboxylate group are considerably influenced by the hydrogen bonding involving this group. When the monodentate carboxylate group is involved in hydrogen bonding the A v = vas(COO) - vs(COO) value is several dozen cm"' smaller than that in the absence of hydrogen bonds. This observation shows that the determination of the type of coordination of the carboxylate group cannot be made solely on the basis of the IR spectra.

Słowa kluczowe

PL

właściwości spektroskopowe; właściwości magnetyczne; struktura molekularna; struktura supramolekularna

EN

spectroscopic properties; magnetic properties; molecular structure; supermolecular structure

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Prace Naukowe Wydziału Chemicznego Politechniki Wrocławskiej. Monografie
• Rocznik: 2007
• Tom: Nr 3, nr 3
• Strony: 5--80
• Opis fizyczny: Bibliogr. 146 poz.

Twórcy

autor

Dobrzyńska D.

• Zakład Chemii Nieorganicznej i Strukturalnej Wydziału Chemicznego Politechniki Wrocławskiej, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wrocław.

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