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Relationship between the dispersed droplet diameter and the mean power input for emulsification in several types of motionless mixers

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Języki publikacji
EN
Abstrakty
EN
Continuous emulsification of low-viscosity liquids was investigated with three different types of motionless mixers, i.e., Needle Jetting Mixer (NJM), Kenics Static Mixer ® (KSM) and Ramond Supermixer ® (RSM). Kerosene and n-heptane were used as the continuous phase, in which nonionic surfactant (Span80) was dissolved, and deionized water was the dispersed phase. The size distributions of water droplets in emulsions were normalized by the Sauter mean diameter (d32), and then they obeyed a log-normal distribution function with an upper-limit. The correlations of d32 with the mean power input per unit mass of the media within the region where the drop dispersion mainly occurred (PM) were derived. The PM levels of these motionless mixers were the same as these of agitation vessel. The slopes of the correlation lines on the log (d32) - log (PM) correlation chart took almost the same value of -0.4, which agreed with the value derived from isotropic turbulence law in low-viscosity liquids. As the line for RSM was located below those for NJM and KSM, RSM may be the most energy-efficient device of the three.
Rocznik
Strony
5--21
Opis fizyczny
Bibliogr. 22 poz.
Twórcy
autor
autor
autor
  • Department of Life Sciences and Bioengineering, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyamashi, Toyama 930-8555, Japan., yamamoto@eng.u-toyama.ac.jp
Bibliografia
  • [1] AL-MAAMARI R.S., SHIGEMOTO N., HIRAYAMA A., SUEYOSHI M.N., Combustion Properties of Emulsion Fuel Prepared from Heavy Crude Oil in Oman, J. Chem. Eng. Japan, 2007, 40, 105–107.
  • [2] HUSNAWAN M., MASJUKI H.H., MAHLIA T.M.I., SAIFULLAH M.G., Thermal Analysis of Cylinder Head Carbon Deposits from Single Cylinder Diesel Engine Fuelled by Palm Oil–Diesel Fuel Emulsions, Applied Energy, 2009, 86, 2107–2113.
  • [3] BASHA S.A., GOPAL K.R., JEBARAJ S., A Review on Biodiesel Production, Combustion, Emissions and Performance, Renewable and Sustainable Energy Reviews, 2009, 13, 1628–1634.
  • [4] YAMAMOTO T., KUMAZAWA H., Emulsification of Low-Viscosity Liquids with Three Different Types of Motionless Mixer, Proceedings of the 8th APCChE Congress, Seoul, Korea, 1999, 2153–2156.
  • [5] YAMAMOTO T., NISHII K., KAWASAKI H., TANAKA H., Formation of W/O Emulsions by Twin-Needle Jet Disperser, Kagaku Kogaku Ronbunshu (Collected Papers of Chemical Engineering, Japanese document), 1995, 21, 944–947.
  • [6] YAMAMOTO T., KAWASAKI H., KUMAZAWA H., Relationship between the Dispersed Droplet Diameter and the Mean Power Input for Emulsification in Three Different Types of Motionless Mixer, J. Chem. Eng. Japan, 2007, 40, 673–678.
  • [7] DAVIES J.T., Drop Sizes of Emulsions Related to Turbulent Energy Dissipation Rates, Chem. Eng. Sci., 1985, 40, 839–842.
  • [8] DAVIES J.T., A Physical Interpretation of Drop Sizes in Homogenizers and Agitated Tanks, Including the Dispersion of Viscous Oils, Chem. Eng. Sci., 1987, 42, 1671–1676.
  • [9] GRIFFIN W.C., Calculation of HLB Values of Non-Ionic Surfactants, J. Soc. Cosmet. Chem., 1954, 5, 249–256.
  • [10] PASQUALI R.C. et al., Some Considerations about the Hydrophilic–Lipophilic Balance System, International Journal of Pharmaceutics, 2008, 356, 44–51.
  • [11] TAKAHASHI K., TAKEUCHI H., Copper Extraction by LIX65N in Liquid–Liquid Dispersion System, Kagaku Kogaku Ronbunshu (Collected Papers of Chemical Engineering, Japanese document), 1985, 11, 349–352.
  • [12] YAMAMOTO T., NISHII K., KAWASAKI H., YAMAGUCHI S., Characteristics of a Small Sized Continuous Disperser with Needle Jet (in Case of Using Two Parallel Needles), Atomization (J. ILASS–Japan, Japanese document), 1996, 5, 64–70.
  • [13] YAMAMOTO T., KAWASAKI H., KUMAZAWA H., Generalized Characteristics of Emulsification with Two Different Types of Motionless Mixer, Atomization (J. ILASS–Japan, Japanese document), 1999, 8, 59–65.
  • [14] BERKAMN P.D., CALABRESE R.V., Drop Sizes Produced by Static Mixers, AIChE Annual Meeting, paper 27e, Chicago, USA, 1985.
  • [15] BERKMAN P.D., CALABRESE R.V., Dispersion of Viscous Liquids by Turbulent Flow in a Static Mixer, AIChE J., 1988, 34, 602–609.
  • [16] YAMAMOTO T., KUMAZAWA H., Emulsification of Water–Kerosene Systems with Ramond Supermixer, Proceedings of the 10th APCChE Congress, 1P-09-018, Kitakyushu, Japan, 2004
  • [17] MIDDLEMAN S., Drop Size Distributions Produced by Turbulent Pipe Flow of Immiscible Fluids through a Static Mixer, Ind. Eng. Chem. Process Des. Dev., 1974, 13, 78–83.
  • [18] MCMANAMEY W.J., Sauter Mean and Maximum Drop Diameters of Liquid–Liquid Dispersions in Turbulent Agitated Vessels at Low Dispersed Phase Hold-Up, Chem. Eng. Sci., 1979, 34, 432–434.
  • [19] RAJARATNUM N., Turbulent Jets, Developments in Water Science, Vol. 5, Chapt. 2, Elsevier Science, 1976/06.
  • [20] SATO K., Mixing Process in a Jet Mixing Vessel, Kagaku Kogaku (Memoir of the Society of Chemical Engineers, Japan, Japanese document), 1968, 32, 588–594.
  • [21] Chemineer Inc., Drop Formation of Low-Viscosity Fluids in the Kenics Mixer, Kenics Static Mixers KTEK Series, KTEK-5, Dayton, USA, 1988.
  • [22] YAMAMOTO T., TANAKA M., KAWASAKI H., Effects of Surfactant Concentration on Drop Sizes in O/W and W/O/W Emulsions, J. Chem. Eng. Japan, 2003, 36, 963–970.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW8-0013-0047
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