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The subject of the research was the influence of N2O on propane combustion in a fluidized bed reactor with active and chemically inert beds. It was determined that CaO has a significant influence on shifting the area in which the reaction is most intensive deeper into the bed and on the combustion result. It was also observed that adding nitrous oxide causes a decrease in VOC and CO concentration in exhaust gas. It was established that N2O, when added, is the determining factor of NOx creation, which takes place in a similar manner as via the prompt mechanism.
Czasopismo
Rocznik
Tom
Strony
15--32
Opis fizyczny
bibliogr. 26 poz.
Twórcy
autor
autor
autor
autor
- Faculty of Chemical Engineering and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155 Kraków, pczukows@pk.edu.pl
Bibliografia
- [1] National Greenhouse Accounts (NGA) Factors 2009, Department of Climate Change, Australian Government, Commonwealth Copyright Administration, Canberra, 2009.
- [2] LE TREUT H., SOMERVILLE R., CUBASCH U., DING Y., MAURITZEN C., MOKSSIT A., PETERSON T., PRATHER M., Historical Overview of Climate Change, Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (Solomon S., Qin D., Manning M., Chen Z., Marquis M., Averyt K.B., Tignor M., Miller H.L. (eds.)), Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 2007.
- [3] Ochrona Środowiska 2008, Informacje i opracowania statystyczne, Główny Urząd Statystyczny, Warszawa, 2008, the publication is available on a CD and on the Internet: www.stat.gov.pl.
- [4] ZELDOVICH Y.B., The oxidation of nitrogen combustion and explosions, Acta Physicochemica, 1946, 21, 577–625.
- [5] TSANG W., HERRON J.T., Chemical Kinetic Data Base for Propellant Combustion. I. Reactions In- volving NO, NO2, HNO, HNO2, HCN, and N2O, 1991, Vol. 20, No. 4, 609–663.
- [6] KONNOV A.A., Development and Validation of a Detailed Reaction Mechanism for the Combustion of Small Hydrocarbons, 28-th Symposium (Int.) on Combustion, Edinburgh, Abstr. Symp. Pap., 2000, 317.
- [7] KONNOV A.A., Detailed Reaction Mechanism for Small Hydrocarbons Combustion, Release 0.5, 2000, available at http://homepages.vub.ac.be/~akonnov/, available as electronic supplementary material to Coppens F.H.V., De Ruyck J., Konnov A.A., Flame 149, 2007, 409–417.
- [8] SUTTON J.A., FLEMING J.W., Towards accurate kinetic modelling of prompt NO formation in hydro- carbon flames via the NCN pathway, Combustion and Flame, 2008, 154, 630–636.
- [9] FENIMORE C.P., Formation of Nitric Oxide in Premixed Hydrocarbon Flames, Symposium (Int.) on Combustion, 1971, Vol. 13, Issue 1, 373–380.
- [10] KONNOV A.A., DYAKOV I.V., Nitrous Oxide Conversion in Laminar Premixed Flames of CH4+O2+Ar, Proceedings of the Combustion Institute, 2009, 32, 319–326.
- [11] BONN B., PELZ G., BAUMANN H., Formation and decomposition of N2O in fluidized bed boilers, Fuel, 1995, 74, 163–171.
- [12] ARMESTO L., BOERRIGTER H, BAHILLO A., OTERO J., N2O emission from fluidised bed combustion. The effect of fuel characteristic and operating conditions, Fuel, 2003, 82, 1845–1850.
- [13] SVOBODA K., BAXTER D., MARTINEC J., Nitrous oxide emission from waste incineration, Chem. Pap., 2006, 60, 78–90.
- [14] SHIMIZU T., FUJITA D., ISHIZU K., KOBAYASHI S., INAGAKI M., Effect of Limestone Feed on Emissions of NOx and N2O from a Circulating Fluidized Bed Combustor, Proc. of 12th Int. Conf. on Fluidized Bed Combustion, 1993, 611–617.
- [15] ŻUKOWSKI, W., A simple model for explosive combustion of premixed natural gas with air in a bubbling fluidized bed of inert sand, Combustion and Flame, 2003, Vol. 134, 399–409.
- [16] ŻUKOWSKI W., Methane and Ethane Combustion in an Inert Fluidized Bed, Proceedings of 18th International Conference on Fluidized Bed Combustion, ASME, Toronto, Ontario, Canada, (FBC2005-78100), 2005, 1–9.
- [17] BARON J., BULEWICZ E.M., KANDEFER S., PILAWSKA M., ŻUKOWSKI W., HAYHURST A.N., Combustion of hydrogen in a bubbling fluidized bed, Combustion and Flame, 2009, 156, Issue 5, 975–984.
- [18] ŻUKOWSKI W., Acoustic effects during the combustion of gaseous fuels in a bubbling fluidized bed, Combustion and Flame, 1999, 117, 629–635.
- [19] ŻUKOWSKI W., An acoustic method of studying sequential explosions during gas combustion in bubbling fluidized beds, Combustion and Flame, 2001, 125, 3, 1075–1082.
- [20] ŻUKOWSKI W., The pressure pulses generated by the combustion of natural gas in bubbling fluidized beds, Combustion and Flame, 2002, 130, 15–26.
- [21] ŻUKOWSKI W., Badania procesu spalania paliw gazowych w reaktorze z inertnym złożem fluidalnym, Monografia 306, 132, Seria Inżynieria Środowiska, Politechnika Krakowska, Kraków, 2004.
- [22] ŻUKOWSKI W., ENGLOT S., BARON J., KANDEFER S., OLEK M., Reduction of carbon dioxide emission through sorption in situ using a fluidised bed reactor, Polish Journal of Chemical Technology, 2008, 10, 4, 45–48.
- [23] ŻUKOWSKI W., BARON J., BŁASZCZYK-PASTECZKA A., KANDEFER S., OLEK M., Efekty spalania propanu w inertnym i aktywnym chemicznie złożu reaktora fluidyzacyjnego, Przemysł Chemiczny, 2008, 87(2), 214–218.
- [24] HAYHURST A.N., LAWRENCE A.D., The effect of solid CaO on the production of NO and N2O in fluidized bed combustors, studies using pyridine as a prototypical nitrogenous fuel, Comb. Flame, 1996, 105, 511–527.
- [25] HANSEN P.F.B., DAM-JOHANSEN K., JOHNSSON J.E., HULGAARD T., Catalytic reduction of NO and N2O on limestone during sulphur capture under fluidized bed combustion conditions, Chemical Engineering Science, 1992, 47(9–11), 2419–2424.
- [26] SKALSKA K., MILLER J., LEDAKOWICZ S., NO removal from flue gases by ozonation, Environment Protection Engineering, 2009, 35, 3, 207–214.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW8-0012-0013